﻿{"id":10,"date":"2020-08-20T09:00:12","date_gmt":"2020-08-20T09:00:12","guid":{"rendered":"https:\/\/www2.hu-berlin.de\/chemie\/braun\/?page_id=10"},"modified":"2026-02-24T10:58:12","modified_gmt":"2026-02-24T10:58:12","slug":"publikationen","status":"publish","type":"page","link":"https:\/\/www2.hu-berlin.de\/chemie\/braun\/publikationen\/","title":{"rendered":"Publications"},"content":{"rendered":"\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<h1 class=\"wp-block-heading\" id=\"publications\">Publications<\/h1>\n\n\n\n<p><\/p>\n\n\n\n<figure class=\"wp-block-table\"><table style=\"\u201cborder:none;\u201c\"><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">195.<\/td><td style=\"vertical-align: top; border: none;\"> S. Mollasalehi, J. Borel, T. Braun, <em> Eur. J. Inorg. Chem. <\/em> <strong>2025<\/strong>, <em>29<\/em>, e202500509.<br><em><a href=\" https:\/\/doi.org\/10.1002\/ejic.202500509\"_blank\" rel=\"noreferrer noopener\"><em>&#8222;Activation and Derivatization of Perfluoro(methyl Vinyl Ether) by a Rh(I) Germyl Complex&#8220;<\/em><\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n<div class=\"wp-block-image\">\n<figure class=\"aligncenter size-full is-resized\"><img loading=\"lazy\" decoding=\"async\" width=\"1092\" height=\"733\" src=\"https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2025\/12\/Soodeh_TOC.png\" alt=\"\" class=\"wp-image-2390\" style=\"width:456px;height:auto\" srcset=\"https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2025\/12\/Soodeh_TOC.png 1092w, https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2025\/12\/Soodeh_TOC-300x201.png 300w, https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2025\/12\/Soodeh_TOC-1024x687.png 1024w, https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2025\/12\/Soodeh_TOC-768x516.png 768w\" sizes=\"auto, (max-width: 1092px) 100vw, 1092px\" \/><\/figure>\n<\/div>\n\n\n<hr class=\"wp-block-separator has-alpha-channel-opacity\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table style=\"\u201cborder:none;\u201c\"><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">194.<\/td><td style=\"vertical-align: top; border: none;\"> L. M. Richter, O. He, T. Braun, <em> Z. Anorg. Allg. Chem. <\/em> <strong>2025<\/strong>, <em>652<\/em>, e202500210.<br><em><a href=\" https:\/\/doi.org\/10.1002\/zaac.202500210\" target=\"_blank\" rel=\"noreferrer noopener\"><em>&#8222;C\u2013F and C\u2013H Bond Activation Reactions of Fluorinated Molecules at Rhodium Pincer Complexes&#8220;<\/em><\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n<div class=\"wp-block-image\">\n<figure class=\"aligncenter size-full is-resized\"><img loading=\"lazy\" decoding=\"async\" width=\"643\" height=\"493\" src=\"https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2025\/11\/Liza_TOC_2-1.png\" alt=\"\" class=\"wp-image-2385\" style=\"width:456px;height:auto\" srcset=\"https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2025\/11\/Liza_TOC_2-1.png 643w, https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2025\/11\/Liza_TOC_2-1-300x230.png 300w\" sizes=\"auto, (max-width: 643px) 100vw, 643px\" \/><\/figure>\n<\/div>\n\n\n<hr class=\"wp-block-separator has-alpha-channel-opacity\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table style=\"\u201cborder:none;\u201c\"><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">193.<\/td><td style=\"vertical-align: top; border: none;\"> A. Abdolrahimi, P. Woite, K. Kretschmar, O. He, M. Roemelt, T. Braun, <em> Chem. Sci. <\/em> <strong>2025<\/strong>, <em>16<\/em>, 19414\u201319422.<br><em><a href=\" https:\/\/doi.org\/10.1039\/D5SC03892H\" target=\"_blank\" rel=\"noreferrer noopener\"><em>&#8222;Sequential one-pot N-alkylation and aminocarbonylation of primary amines catalyzed by heterobimetallic Ir\/Pd complexes&#8220;<\/em><\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n<div class=\"wp-block-image\">\n<figure class=\"aligncenter size-full is-resized\"><img loading=\"lazy\" decoding=\"async\" width=\"1191\" height=\"944\" src=\"https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2025\/10\/Amin_TOC-1.jpg\" alt=\"\" class=\"wp-image-2368\" style=\"width:456px;height:auto\" srcset=\"https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2025\/10\/Amin_TOC-1.jpg 1191w, https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2025\/10\/Amin_TOC-1-300x238.jpg 300w, https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2025\/10\/Amin_TOC-1-1024x812.jpg 1024w, https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2025\/10\/Amin_TOC-1-768x609.jpg 768w\" sizes=\"auto, (max-width: 1191px) 100vw, 1191px\" \/><\/figure>\n<\/div>\n\n\n<hr class=\"wp-block-separator has-alpha-channel-opacity\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table style=\"\u201cborder:none;\u201c\"><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">192.<\/td><td style=\"vertical-align: top; border: none;\"> M. Bui, C. Heinekamp, E. Fuhry, S. Weidner, J. Radnik, M. Ahrens, K. Scheurell, K. Balasubramanian, F. Emmerling, T. Braun, <em> Chem. Sci. <\/em> <strong>2025<\/strong>, <em>16<\/em>, 18903-18910.<br><em><a href=\" https:\/\/doi.org\/10.1039\/D5SC05783C\" target=\"_blank\" rel=\"noreferrer noopener\"><em>&#8222;Lewis-acid induced mechanochemical degradation of polyvinylidene fluoride: transformation into valuable products&#8220;<\/em><\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n<div class=\"wp-block-image\">\n<figure class=\"aligncenter size-full is-resized\"><img loading=\"lazy\" decoding=\"async\" width=\"1418\" height=\"945\" src=\"https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2025\/10\/Minh_TOC.jpg\" alt=\"\" class=\"wp-image-2365\" style=\"width:480px;height:auto\" srcset=\"https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2025\/10\/Minh_TOC.jpg 1418w, https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2025\/10\/Minh_TOC-300x200.jpg 300w, https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2025\/10\/Minh_TOC-1024x682.jpg 1024w, https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2025\/10\/Minh_TOC-768x512.jpg 768w, https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2025\/10\/Minh_TOC-930x620.jpg 930w\" sizes=\"auto, (max-width: 1418px) 100vw, 1418px\" \/><\/figure>\n<\/div>\n\n\n<hr class=\"wp-block-separator has-alpha-channel-opacity\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table style=\"\u201cborder:none;\u201c\"><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">191.<\/td><td style=\"vertical-align: top; border: none;\">L. M. Richter, O. He, M. Ahrens, T. Braun, <em> ChemistryEurope <\/em> <strong>2025<\/strong>, <em>3<\/em>, e202500146.<br><em><a href=\" https:\/\/doi.org\/10.1002\/ceur.202500146\" target=\"_blank\" rel=\"noreferrer noopener\"><em>&#8222;Activation of SOF<sub>2<\/sub> at Rh Pincer Complexes: Ligand Backbone Versus Metal Centred Reactivity&#8220;<\/em><\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n<div class=\"wp-block-image\">\n<figure class=\"aligncenter size-full is-resized\"><img loading=\"lazy\" decoding=\"async\" width=\"1307\" height=\"202\" src=\"https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2025\/08\/LIza_TOC-1.png\" alt=\"\" class=\"wp-image-2323\" style=\"width:720px;height:auto\" srcset=\"https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2025\/08\/LIza_TOC-1.png 1307w, https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2025\/08\/LIza_TOC-1-300x46.png 300w, https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2025\/08\/LIza_TOC-1-1024x158.png 1024w, https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2025\/08\/LIza_TOC-1-768x119.png 768w\" sizes=\"auto, (max-width: 1307px) 100vw, 1307px\" \/><\/figure>\n<\/div>\n\n\n<hr class=\"wp-block-separator has-alpha-channel-opacity\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table style=\"\u201cborder:none;\u201c\"><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">190.<\/td><td style=\"vertical-align: top; border: none;\">O. He, F. Jameel, H. Flammang, S. S. Babu, M. Kaupp, T. Braun, <em> Angew. Chem. Int. Ed. <\/em> <strong>2025<\/strong>, <em>64<\/em>, e202512181.<br><em><a href=\"https:\/\/doi.org\/10.1002\/anie.202512181\" target=\"_blank\" rel=\"noreferrer noopener\"><em>&#8222;Platinum-Catalysed Hydrofluorination of Alkynes at Room Temperature Promoted by a Fluoride Shuttle&#8220;<\/em><\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n<div class=\"wp-block-image\">\n<figure class=\"aligncenter size-full is-resized\"><img loading=\"lazy\" decoding=\"async\" width=\"649\" height=\"531\" src=\"https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2025\/08\/TOCS.jpg\" alt=\"\" class=\"wp-image-2344\" style=\"width:491px;height:auto\" srcset=\"https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2025\/08\/TOCS.jpg 649w, https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2025\/08\/TOCS-300x245.jpg 300w\" sizes=\"auto, (max-width: 649px) 100vw, 649px\" \/><\/figure>\n<\/div>\n\n\n<hr class=\"wp-block-separator has-alpha-channel-opacity\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table style=\"\u201cborder:none;\u201c\"><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">189.<\/td><td style=\"vertical-align: top; border: none;\">S. Mollasalehi, M. Ahrens, T. Braun, <em> Chem. Sci. <\/em> <strong>2025<\/strong>, <em>16<\/em>, 10928\u201310934.<br><em><a href=\"https:\/\/doi.org\/10.1039\/D5SC02056E \" target=\"_blank\" rel=\"noreferrer noopener\"><em>&#8222;Activation of perfluoro(methyl vinyl ether) at Rh(I) complexes: metal-centered versus phosphine-mediated decarbonylation&#8220;<\/em><\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n<div class=\"wp-block-image\">\n<figure class=\"aligncenter size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"627\" height=\"286\" src=\"https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2025\/06\/TOC-Soodeh-1.png\" alt=\"\" class=\"wp-image-2299\" srcset=\"https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2025\/06\/TOC-Soodeh-1.png 627w, https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2025\/06\/TOC-Soodeh-1-300x137.png 300w\" sizes=\"auto, (max-width: 627px) 100vw, 627px\" \/><\/figure>\n<\/div>\n\n\n<hr class=\"wp-block-separator has-alpha-channel-opacity\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table style=\"\u201cborder:none;\u201c\"><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">188.<\/td><td style=\"vertical-align: top; border: none;\">C. Heinekamp, A. Roy, S. Karafiludis, S. Kumar, A. G. Buzanich, T. M. Stawski, A. Mili\u016bt\u0117, M. v. d. Au, M. Ahrens, T. Braun, F. Emmerling,<br><em> J. Mater. Chem. A <\/em> <strong>2025<\/strong>, <em>13<\/em>, 20383\u201320393.<br><em><a href=\"https:\/\/doi.org\/10.1039\/D4TA08664C\" target=\"_blank\" rel=\"noreferrer noopener\"><em>&#8222;Zirconium fluoride-supported high-entropy fluoride: a catalyst for enhanced oxygen evolution reaction&#8220;<\/em><\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n<div class=\"wp-block-image\">\n<figure class=\"aligncenter size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"417\" height=\"229\" src=\"https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2025\/07\/TOC__Chris.png\" alt=\"\" class=\"wp-image-2305\" srcset=\"https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2025\/07\/TOC__Chris.png 417w, https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2025\/07\/TOC__Chris-300x165.png 300w\" sizes=\"auto, (max-width: 417px) 100vw, 417px\" \/><\/figure>\n<\/div>\n\n\n<hr class=\"wp-block-separator has-alpha-channel-opacity\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table style=\"\u201cborder:none;\u201c\"><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">187.<\/td><td style=\"vertical-align: top; border: none;\">R. Jaeger, O. He, D. Dirican, S. Sander, M. Ahrens, T. Braun, <em> Angew. Chem. Int. Ed. <\/em> <strong>2025<\/strong>, <em>64<\/em>, e202503153.<br><em><a href=\"https:\/\/doi.org\/10.1002\/anie.202503153 \" target=\"_blank\" rel=\"noreferrer noopener\"><em>&#8222;Routes to Pt Derivatives of High-Valent Sulfur Oxofluorides\nS(=O)<sub>2<\/sub>F, S(=O)F<sub>2<\/sub> and S(=O)F<sub>3<\/sub> by Fluorination and Oxygenation&#8220;<\/em><\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n<div class=\"wp-block-image\">\n<figure class=\"aligncenter size-large\"><img loading=\"lazy\" decoding=\"async\" width=\"1024\" height=\"242\" src=\"https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2025\/04\/Routes-to-Pt-Derivatives-of-High-Valent-Sulfur-Oxofluorides-SO2F-SOF2-and-SOF3-by-Fluorination-and-Oxygenation-1024x242.jpg\" alt=\"\" class=\"wp-image-2223\" srcset=\"https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2025\/04\/Routes-to-Pt-Derivatives-of-High-Valent-Sulfur-Oxofluorides-SO2F-SOF2-and-SOF3-by-Fluorination-and-Oxygenation-1024x242.jpg 1024w, https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2025\/04\/Routes-to-Pt-Derivatives-of-High-Valent-Sulfur-Oxofluorides-SO2F-SOF2-and-SOF3-by-Fluorination-and-Oxygenation-300x71.jpg 300w, https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2025\/04\/Routes-to-Pt-Derivatives-of-High-Valent-Sulfur-Oxofluorides-SO2F-SOF2-and-SOF3-by-Fluorination-and-Oxygenation-768x181.jpg 768w, https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2025\/04\/Routes-to-Pt-Derivatives-of-High-Valent-Sulfur-Oxofluorides-SO2F-SOF2-and-SOF3-by-Fluorination-and-Oxygenation-1536x363.jpg 1536w, https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2025\/04\/Routes-to-Pt-Derivatives-of-High-Valent-Sulfur-Oxofluorides-SO2F-SOF2-and-SOF3-by-Fluorination-and-Oxygenation-2048x484.jpg 2048w\" sizes=\"auto, (max-width: 1024px) 100vw, 1024px\" \/><\/figure>\n<\/div>\n\n\n<hr class=\"wp-block-separator has-alpha-channel-opacity\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table style=\"\u201cborder:none;\u201c\"><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">186.<\/td><td style=\"vertical-align: top; border: none;\">M. Talavera, S. Mollasalehi ,T. Braun, <em>Chem. Sci.<\/em> <strong>2024<\/strong>, <em>15<\/em>, 8472\u20138477.<br><em><a href=\"https:\/\/doi.org\/10.1039\/D4SC00951G \" target=\"_blank\" rel=\"noreferrer noopener\"><em>&#8222;C\u2013H and C\u2013F bond activation of fluorinated\npropenes at Rh: enabling cross-coupling reactions with outer-sphere C\u2013C coupling&#8220;<\/em><\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n<div class=\"wp-block-image\">\n<figure class=\"aligncenter size-full is-resized\"><img loading=\"lazy\" decoding=\"async\" width=\"1038\" height=\"282\" src=\"https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2024\/06\/C\u2013H-and-C\u2013F-bond-activation-of-fluorinated-propenes-at-Rh-enabling-cross-coupling-reactions-with-outer-sphere-C\u2013C-coupling.png\" alt=\"\" class=\"wp-image-2143\" style=\"width:auto;height:133px\" srcset=\"https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2024\/06\/C\u2013H-and-C\u2013F-bond-activation-of-fluorinated-propenes-at-Rh-enabling-cross-coupling-reactions-with-outer-sphere-C\u2013C-coupling.png 1038w, https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2024\/06\/C\u2013H-and-C\u2013F-bond-activation-of-fluorinated-propenes-at-Rh-enabling-cross-coupling-reactions-with-outer-sphere-C\u2013C-coupling-300x82.png 300w, https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2024\/06\/C\u2013H-and-C\u2013F-bond-activation-of-fluorinated-propenes-at-Rh-enabling-cross-coupling-reactions-with-outer-sphere-C\u2013C-coupling-1024x278.png 1024w, https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2024\/06\/C\u2013H-and-C\u2013F-bond-activation-of-fluorinated-propenes-at-Rh-enabling-cross-coupling-reactions-with-outer-sphere-C\u2013C-coupling-768x209.png 768w\" sizes=\"auto, (max-width: 1038px) 100vw, 1038px\" \/><\/figure>\n<\/div>\n\n\n<hr class=\"wp-block-separator has-alpha-channel-opacity\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table style=\"\u201cborder:none;\u201c\"><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">185.<\/td><td style=\"vertical-align: top; border: none;\">J. Cardozo, O. He, W. Ma, K. Ray, T. Braun, <em>Z. anorg. allg. Chem.<\/em> <strong>2024<\/strong>, <em>650<\/em>, e202400028.<br><em><a href=\"https:\/\/doi.org\/10.1002\/zaac.202400028\" target=\"_blank\" rel=\"noreferrer noopener\"><em>&#8222;An Iminophosphinite Pincer Iridium Complex: Synthesis and\nCatalytic Tool for Alkane Transfer Dehydrogenations&#8220;<\/em><\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n<div class=\"wp-block-image\">\n<figure class=\"aligncenter size-large is-resized\"><img loading=\"lazy\" decoding=\"async\" width=\"1024\" height=\"536\" src=\"https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2024\/06\/An-Iminophosphinite-Pincer-Iridium-Complex-Synthesis-and-1-1024x536.png\" alt=\"\" class=\"wp-image-2130\" style=\"width:400px\" srcset=\"https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2024\/06\/An-Iminophosphinite-Pincer-Iridium-Complex-Synthesis-and-1-1024x536.png 1024w, https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2024\/06\/An-Iminophosphinite-Pincer-Iridium-Complex-Synthesis-and-1-300x157.png 300w, https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2024\/06\/An-Iminophosphinite-Pincer-Iridium-Complex-Synthesis-and-1-768x402.png 768w, https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2024\/06\/An-Iminophosphinite-Pincer-Iridium-Complex-Synthesis-and-1-1536x804.png 1536w, https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2024\/06\/An-Iminophosphinite-Pincer-Iridium-Complex-Synthesis-and-1-2048x1071.png 2048w\" sizes=\"auto, (max-width: 1024px) 100vw, 1024px\" \/><\/figure>\n<\/div>\n\n\n<hr class=\"wp-block-separator has-alpha-channel-opacity\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table style=\"\u201cborder:none;\u201c\"><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">184.<\/td><td style=\"vertical-align: top; border: none;\">R. Jaeger, S. Rachor, M. Ahrens, T. Braun, <em>Chem. Eur. J.<\/em> <strong>2024<\/strong>, <em>30<\/em>, e202401571.<br><em><a href=\"https:\/\/doi.org\/10.1002\/chem.202401571\" target=\"_blank\" rel=\"noreferrer noopener\"><em>&#8222;Activation of SO<sub>2<\/sub>F<sub>2<\/sub> at a Rhodium PNP Pincer Complex: Ligand Supported S-F Bond Cleavage to Generate NSO<sub>2<\/sub>F Derivatives&#8220;<\/em><\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n<div class=\"wp-block-image\">\n<figure class=\"aligncenter size-full is-resized\"><img loading=\"lazy\" decoding=\"async\" width=\"1022\" height=\"309\" src=\"https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2024\/05\/Activation-of-SO2F2-at-a-Rhodium-PNP-Pincer-Complex-Ligand-Supported-S-F-Bond-Cleavage-to-Generate-NSO2F-Derivatives.png\" alt=\"\" class=\"wp-image-2110\" style=\"width:700px\" srcset=\"https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2024\/05\/Activation-of-SO2F2-at-a-Rhodium-PNP-Pincer-Complex-Ligand-Supported-S-F-Bond-Cleavage-to-Generate-NSO2F-Derivatives.png 1022w, https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2024\/05\/Activation-of-SO2F2-at-a-Rhodium-PNP-Pincer-Complex-Ligand-Supported-S-F-Bond-Cleavage-to-Generate-NSO2F-Derivatives-300x91.png 300w, https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2024\/05\/Activation-of-SO2F2-at-a-Rhodium-PNP-Pincer-Complex-Ligand-Supported-S-F-Bond-Cleavage-to-Generate-NSO2F-Derivatives-768x232.png 768w\" sizes=\"auto, (max-width: 1022px) 100vw, 1022px\" \/><\/figure>\n<\/div>\n\n\n<hr class=\"wp-block-separator has-alpha-channel-opacity\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table style=\"\u201cborder:none;\u201c\"><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">183.<\/td><td style=\"vertical-align: top; border: none;\">C. Heinekamp, S. Kneiske, A. G. Buzanich, M. Ahrens, T. Braun, F. Emmerling, <em>Cat. Sci. Technol.<\/em> <strong>2024<\/strong>, <em>14<\/em>, 673-680.<br><em><a href=\"https:\/\/doi.org\/10.1039\/D3CY01439H\" target=\"_blank\" rel=\"noreferrer noopener\"><em>&#8222;A fluorolytic sol\u2013gel route to access an amorphous Zr fluoride catalyst: a useful tool for C\u2013F bond activation&#8220;<\/em><\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n<div class=\"wp-block-image\">\n<figure class=\"aligncenter size-full is-resized\"><img loading=\"lazy\" decoding=\"async\" width=\"378\" height=\"122\" src=\"https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2024\/01\/A-fluorolytic-solgel-route-to-access-an-amorphous-Zr-fluoride-catalyst-a-useful-tool-for-CF-bond-activation.gif\" alt=\"\" class=\"wp-image-2068\" style=\"aspect-ratio:3.098360655737705;width:394px;height:auto\"\/><\/figure>\n<\/div>\n\n\n<hr class=\"wp-block-separator has-alpha-channel-opacity\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table style=\"\u201cborder:none;\u201c\"><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">182.<\/td><td style=\"vertical-align: top; border: none;\">C. Heinekamp, A. G. Buzanich, M. Ahrens, T. Braun, F. Emmerling, <em>Chem. Commun.<\/em> <strong>2023<\/strong>, <em>59<\/em>, 11224.<br><em><a href=\"https:\/\/doi.org\/10.1039\/D3CC03164K \" target=\"_blank\" rel=\"noreferrer noopener\"><em>&#8222;An amorphous Lewis-acidic zirconium chlorofluoride as HF shuttle: C\u2013F bond activation and formation&#8220;<\/em><\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n<div class=\"wp-block-image\">\n<figure class=\"aligncenter size-full is-resized\"><img loading=\"lazy\" decoding=\"async\" width=\"945\" height=\"262\" src=\"https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2023\/09\/graphical-abstract.png\" alt=\"\" class=\"wp-image-2051\" style=\"width:453px;height:126px\" srcset=\"https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2023\/09\/graphical-abstract.png 945w, https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2023\/09\/graphical-abstract-300x83.png 300w, https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2023\/09\/graphical-abstract-768x213.png 768w\" sizes=\"auto, (max-width: 945px) 100vw, 945px\" \/><\/figure>\n<\/div>\n\n\n<hr class=\"wp-block-separator has-alpha-channel-opacity\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table style=\"\u201cborder:none;\u201c\"><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">181.<\/td><td style=\"vertical-align: top; border: none;\">D. Herbstritt, P. Tomar, T. Braun, <em>Molecules<\/em> <strong>2023<\/strong>, <em>28<\/em>, 6693.<br><em><a href=\"https:\/\/doi.org\/10.3390\/molecules28186693\" target=\"_blank\" rel=\"noreferrer noopener\"><em>&#8222;Activation of SF<sub>5<\/sub>CF<sub>3<\/sub> by the N-Heterocyclic Carbene SIMes &#8222;<\/em><\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n<div class=\"wp-block-image\">\n<figure class=\"aligncenter size-large is-resized\"><img loading=\"lazy\" decoding=\"async\" width=\"1024\" height=\"295\" src=\"https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2023\/09\/TOC_SF5CF3aktivierung-an-SIMES_Domi_1-1024x295.png\" alt=\"\" class=\"wp-image-2038\" style=\"width:648px;height:186px\" srcset=\"https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2023\/09\/TOC_SF5CF3aktivierung-an-SIMES_Domi_1-1024x295.png 1024w, https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2023\/09\/TOC_SF5CF3aktivierung-an-SIMES_Domi_1-300x86.png 300w, https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2023\/09\/TOC_SF5CF3aktivierung-an-SIMES_Domi_1-768x221.png 768w, https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2023\/09\/TOC_SF5CF3aktivierung-an-SIMES_Domi_1-1536x442.png 1536w, https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2023\/09\/TOC_SF5CF3aktivierung-an-SIMES_Domi_1-2048x590.png 2048w\" sizes=\"auto, (max-width: 1024px) 100vw, 1024px\" \/><\/figure>\n<\/div>\n\n\n<hr class=\"wp-block-separator has-alpha-channel-opacity\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table style=\"\u201cborder:none;\u201c\"><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">180.<\/td><td style=\"vertical-align: top; border: none;\">D. Herbstritt, P. Tomar, R. M\u00fcller, M, Kaupp, T. Braun, <em>Eur. J. Chem.<\/em> <strong>2023<\/strong>, <em>29<\/em>, e202301556.<br><em><a href=\"https:\/\/doi.org\/10.1002\/chem.202301556\" target=\"_blank\" rel=\"noreferrer noopener\"><em>&#8222;A 2,2-Difluoroimidazolidine Derivative for Deoxyfluorination Reactions: Mechanistic Insights by Experimental and Computational Studies&#8220;<\/em><\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n<div class=\"wp-block-image\">\n<figure class=\"aligncenter size-large is-resized\"><img loading=\"lazy\" decoding=\"async\" width=\"1024\" height=\"169\" src=\"https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2023\/06\/A-22-Difluoroimidazolidine-Derivative-for-Deoxyfluorination-Reactions-Mechanistic-Insights-by-Experimental-and-Computational-Studies-1024x169.png\" alt=\"\" class=\"wp-image-1972\" style=\"width:600px;height:99px\" srcset=\"https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2023\/06\/A-22-Difluoroimidazolidine-Derivative-for-Deoxyfluorination-Reactions-Mechanistic-Insights-by-Experimental-and-Computational-Studies-1024x169.png 1024w, https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2023\/06\/A-22-Difluoroimidazolidine-Derivative-for-Deoxyfluorination-Reactions-Mechanistic-Insights-by-Experimental-and-Computational-Studies-300x50.png 300w, https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2023\/06\/A-22-Difluoroimidazolidine-Derivative-for-Deoxyfluorination-Reactions-Mechanistic-Insights-by-Experimental-and-Computational-Studies-768x127.png 768w, https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2023\/06\/A-22-Difluoroimidazolidine-Derivative-for-Deoxyfluorination-Reactions-Mechanistic-Insights-by-Experimental-and-Computational-Studies.png 1040w\" sizes=\"auto, (max-width: 1024px) 100vw, 1024px\" \/><\/figure>\n<\/div>\n\n\n<hr class=\"wp-block-separator has-alpha-channel-opacity\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table style=\"\u201cborder:none;\u201c\"><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">179.<\/td><td style=\"vertical-align: top; border: none;\">X. Pan, M. Talavera, T. Braun, <em>J. Fluorine Chem.<\/em> <strong>2023<\/strong>, <em>267<\/em>, 110116.<br><em><a href=\"https:\/\/doi.org\/10.1016\/j.jfluchem.2023.110116\" target=\"_blank\" rel=\"noreferrer noopener\"><em>&#8222;Efficient hydrostannation of fluorinated alkenes&#8220;<\/em><\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n<div class=\"wp-block-image\">\n<figure class=\"aligncenter size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"496\" height=\"200\" src=\"https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2023\/04\/1-s2.0-S0022113923000313-ga1.jpg\" alt=\"\" class=\"wp-image-1962\" srcset=\"https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2023\/04\/1-s2.0-S0022113923000313-ga1.jpg 496w, https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2023\/04\/1-s2.0-S0022113923000313-ga1-300x121.jpg 300w\" sizes=\"auto, (max-width: 496px) 100vw, 496px\" \/><\/figure>\n<\/div>\n\n\n<hr class=\"wp-block-separator has-alpha-channel-opacity\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table style=\"\u201cborder:none;\u201c\"><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">178.<\/td><td style=\"vertical-align: top; border: none;\">D. Herbstritt, T. Braun, <em>Chem. Commun.<\/em> <strong>2023<\/strong>, <em>59<\/em>, 3850-3853.<br><em><a href=\"http:\/\/dx.doi.org\/10.1039\/D3CC00495C\" target=\"_blank\" rel=\"noreferrer noopener\"><em>&#8222;Reduction of SF<sub>5<\/sub>CF<sub>3<\/sub> <em>via<\/em> iridium catalysis: radical trifluoromethylation of aromatics&#8220;<\/em><\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n<div class=\"wp-block-image\">\n<figure class=\"aligncenter size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"332\" height=\"189\" src=\"https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2023\/03\/Get.gif\" alt=\"\" class=\"wp-image-1955\"\/><\/figure>\n<\/div>\n\n\n<hr class=\"wp-block-separator has-alpha-channel-opacity\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table style=\"\u201cborder:none;\u201c\"><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">177.<\/td><td style=\"vertical-align: top; border: none;\">M. Bui, K. F. Hoffmann, T. Braun, S. Riedel, C. Heinekamp, K. Scheurell, G. Scholz, T. M. Stawski, F. Emmerling, <em>ChemCatChem<\/em>, <em>15<\/em>, <strong>2023<\/strong>, e202300350.<br><em><a href=\"https:\/\/doi.org\/10.1002\/cctc.202300350\" target=\"_blank\" rel=\"noreferrer noopener\"><em>&#8222;An Amorphous Teflate Doped Aluminium Chlorofluoride: A Solid Lewis-Superacid for the Dehydrofluorination of Fluoroalkanes&#8220;<\/em><\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n<div class=\"wp-block-image\">\n<figure class=\"aligncenter size-full is-resized\"><img loading=\"lazy\" decoding=\"async\" width=\"500\" height=\"464\" src=\"https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2023\/03\/cctc202300350-toc-0001-m.webp\" alt=\"\" class=\"wp-image-1947\" style=\"width:329px;height:315px\" srcset=\"https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2023\/03\/cctc202300350-toc-0001-m.webp 500w, https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2023\/03\/cctc202300350-toc-0001-m-300x278.webp 300w\" sizes=\"auto, (max-width: 500px) 100vw, 500px\" \/><\/figure>\n<\/div>\n\n\n<hr class=\"wp-block-separator has-alpha-channel-opacity\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table style=\"\u201cborder:none;\u201c\"><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">176.<\/td><td style=\"vertical-align: top; border: none;\">K. Kretschmar, V. Pelmenschikov, M. Kaupp, T. Braun, P. Wittwer, S. Rachor, J. Cardozo, <em>Eur. J. Inorg. Chem.<\/em> <strong>2023<\/strong>, <em>26<\/em>, e202300099.<br><em><a href=\"https:\/\/doi.org\/10.1002\/ejic.202300099\" target=\"_blank\" rel=\"noreferrer noopener\"><em>&#8222;Bimetallic Carbonyl Complexes Based on Iridium and Rhodium: Useful Tools for Hydrodefluorination Reactions&#8220;<\/em><\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n<div class=\"wp-block-image\">\n<figure class=\"aligncenter size-large is-resized\"><img loading=\"lazy\" decoding=\"async\" width=\"1024\" height=\"670\" src=\"https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2023\/03\/ejic202300099-toc-0001-m-1024x670.webp\" alt=\"\" class=\"wp-image-1944\" style=\"width:379px;height:248px\" srcset=\"https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2023\/03\/ejic202300099-toc-0001-m-1024x670.webp 1024w, https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2023\/03\/ejic202300099-toc-0001-m-300x196.webp 300w, https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2023\/03\/ejic202300099-toc-0001-m-768x502.webp 768w, https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2023\/03\/ejic202300099-toc-0001-m-1536x1005.webp 1536w, https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2023\/03\/ejic202300099-toc-0001-m.webp 1712w\" sizes=\"auto, (max-width: 1024px) 100vw, 1024px\" \/><\/figure>\n<\/div>\n\n\n<hr class=\"wp-block-separator has-alpha-channel-opacity\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table style=\"\u201cborder:none;\u201c\"><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">175.<\/td><td style=\"vertical-align: top; border: none;\">D. Kass, S. Yao, K. B. Krause, T. Corona, L. Richter, T. Braun, S. Mebs, M. Haumann, H. Dau, T. Lohmiller, C. Limberg, M. Drie\u00df, K. Ray, <em>Angew. Chem. Int. Ed. <\/em> <strong>2023<\/strong>, <em>62<\/em>, e202209437.<br><em><a href=\"https:\/\/doi.org\/10.1002\/anie.202209437\" target=\"_blank\" rel=\"noreferrer noopener\"><em>&#8222;Spectroscopic Properties of a Biologically Relevant [Fe<sub>2<\/sub>(\u03bc-O)<sub>2<\/sub>] Diamond Core Motif with a Short Iron-Iron Distance&#8220;<\/em><\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n<div class=\"wp-block-image\">\n<figure class=\"aligncenter size-large is-resized\"><img loading=\"lazy\" decoding=\"async\" width=\"1024\" height=\"920\" src=\"https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2023\/02\/Fe-Paper-Ray-Braun-1024x920.webp\" alt=\"\" class=\"wp-image-1866\" style=\"width:256px;height:230px\" srcset=\"https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2023\/02\/Fe-Paper-Ray-Braun-1024x920.webp 1024w, https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2023\/02\/Fe-Paper-Ray-Braun-300x269.webp 300w, https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2023\/02\/Fe-Paper-Ray-Braun-768x690.webp 768w, https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2023\/02\/Fe-Paper-Ray-Braun.webp 1176w\" sizes=\"auto, (max-width: 1024px) 100vw, 1024px\" \/><\/figure>\n<\/div>\n\n\n<hr class=\"wp-block-separator has-alpha-channel-opacity is-style-default\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table style=\"\u201cborder:none;\u201c\"><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">174.<\/td><td style=\"vertical-align: top; border: none;\">O. He, B. Cula, T. Braun, <em>Helv. Chim. Acta<\/em> <strong>2023<\/strong>, <em>106<\/em>, e202200156.<br><em><a href=\"https:\/\/doi.org\/10.1002\/hlca.202200156\" target=\"_blank\" rel=\"noreferrer noopener\"><em>&#8222;Indolyl Phosphine Nickel(II) Fluorido Complexes: Synthesis and Intermediates in Suzuki-Miyaura Cross-Coupling Reactions&#8220;<\/em><\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n<div class=\"wp-block-image\">\n<figure class=\"aligncenter size-large is-resized\"><img loading=\"lazy\" decoding=\"async\" width=\"1903\" height=\"645\" src=\"https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2023\/01\/Indolyl-Phosphine-NickelII-Fluorido-Complexes-Synthesis-and-Intermediates-in-Suzuki-Miyaura-Cross-Coupling-Reactions-aus-ppt-1.svg\" alt=\"\" class=\"wp-image-1833\" style=\"width:536px;height:181px\"\/><\/figure>\n<\/div>\n\n\n<hr class=\"wp-block-separator has-alpha-channel-opacity is-style-default\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table style=\"\u201cborder:none;\u201c\"><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">173.<\/td><td style=\"vertical-align: top; border: none;\">A. Loges, G. Scholz, N. de Sousa Amadeu, J. Shao, D. Schultze, J. Fuller, B. Paulus, F. Emmerling, T. Braun, T. John, <em>Eur. J. Mineral.<\/em> <strong>2022<\/strong>, <em>34<\/em>, 507-521.<br><em><a href=\"https:\/\/doi.org\/10.5194\/ejm-34-507-2022\" target=\"_blank\" rel=\"noreferrer noopener\"><em>&#8222;Studies on the local structure of the F\u2009\u2215\u2009OH site in topaz by magic angle spinning nuclear magnetic resonance and Raman spectroscopy&#8220;<\/em><\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n<div class=\"wp-block-image\">\n<figure class=\"aligncenter size-full is-resized\"><img loading=\"lazy\" decoding=\"async\" width=\"600\" height=\"337\" src=\"https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2022\/12\/Studies-on-the-local-structure-of-the-F\u2009\u2215\u2009OH-site-in-topaz-by-magic-angle-spinning-nuclear-magnetic-resonance-and-Raman-spectroscopy.png\" alt=\"\" class=\"wp-image-1823\" style=\"width:450px;height:253px\" srcset=\"https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2022\/12\/Studies-on-the-local-structure-of-the-F\u2009\u2215\u2009OH-site-in-topaz-by-magic-angle-spinning-nuclear-magnetic-resonance-and-Raman-spectroscopy.png 600w, https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2022\/12\/Studies-on-the-local-structure-of-the-F\u2009\u2215\u2009OH-site-in-topaz-by-magic-angle-spinning-nuclear-magnetic-resonance-and-Raman-spectroscopy-300x169.png 300w\" sizes=\"auto, (max-width: 600px) 100vw, 600px\" \/><\/figure>\n<\/div>\n\n\n<hr class=\"wp-block-separator has-alpha-channel-opacity is-style-default\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table style=\"\u201cborder:none;\u201c\"><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">172.<\/td><td style=\"vertical-align: top; border: none;\">S. Sander, E. J. Cosgrove, R. M\u00fcller, M. Kaupp, T. Braun, <em>Chem. Eur. J.<\/em> <strong>2023<\/strong>, <em>29<\/em>,  e202202768.<br><em><a href=\"https:\/\/doi.org\/10.1002\/chem.202202768\" target=\"_blank\" rel=\"noreferrer noopener\"><em>&#8222;Hydrogen Bonding in Platinum Indolylphosphine Polyfluorido and Fluorido Complexes&#8220;<\/em><\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n<div class=\"wp-block-image\">\n<figure class=\"aligncenter size-large\"><img loading=\"lazy\" decoding=\"async\" width=\"559\" height=\"216\" src=\"https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2022\/12\/Hydrogen-Bonding-in-Platinum-Indolylphosphine-Polyfluorido-and-Fluorido-Complexes-3.svg\" alt=\"\" class=\"wp-image-1817\"\/><\/figure>\n<\/div>\n\n\n<hr class=\"wp-block-separator has-alpha-channel-opacity is-style-default\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table style=\"\u201cborder:none;\u201c\"><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">171.<\/td><td style=\"vertical-align: top; border: none;\">S. G. Rachor, R. M\u00fcller, M. Kaupp, T. Braun, <em>Eur. J. Inorg. Chem.<\/em> <strong>2023<\/strong>, <em>26<\/em>, e202200668.<br><em><a href=\"https:\/\/doi.org\/10.1002\/ejic.202200668\" target=\"_blank\" rel=\"noreferrer noopener\"><em>&#8222;Hydrogen and Halogen Bonding to Au(I) Fluorido Complexes&#8220;<\/em><\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n<div class=\"wp-block-image\">\n<figure class=\"aligncenter size-large\"><img loading=\"lazy\" decoding=\"async\" width=\"708\" height=\"254\" src=\"https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2022\/11\/Hydrogen-and-Halogen-Bonding-to-AuI-Fluorido-Complexes.svg\" alt=\"\" class=\"wp-image-1800\"\/><\/figure>\n<\/div>\n\n\n<hr class=\"wp-block-separator has-alpha-channel-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table style=\"\u201cborder:none;\u201c\"><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">170.<\/td><td style=\"vertical-align: top; border: none;\">S. G. Rachor, M. Ahrens, T. Braun, <em>Angew. Chem. Int. Ed.<\/em> <strong>2022<\/strong>, <em>61<\/em>, e202212858.<br><em><a href=\"https:\/\/doi.org\/10.1002\/anie.202212858\" target=\"_blank\" rel=\"noreferrer noopener\"><em>&#8222;Conversion of a Au<sup>I<\/sup> Fluorido Complex into an N-Fluoroamido Derivative: N\u2212F versus Au\u2212N Reactivity&#8220;<\/em><\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n<div class=\"wp-block-image\">\n<figure class=\"aligncenter size-large\"><img loading=\"lazy\" decoding=\"async\" width=\"709\" height=\"268\" src=\"https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2022\/11\/Conversion-of-a-AuI-Fluorido-Complex-into-an-N-Fluoroamido-Derivative-N\u2212F-versus-Au\u2212N-Reactivity.svg\" alt=\"\" class=\"wp-image-1775\"\/><\/figure>\n<\/div>\n\n\n<hr class=\"wp-block-separator aligncenter has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table style=\"\u201cborder:none;\u201c\"><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">169.<\/td><td style=\"vertical-align: top; border: none;\">X. Pan, M. Talavera, T. Braun, <em>J. Fluorine Chem.<\/em> <strong>2022<\/strong>, <em>263<\/em>, 110046.<br><em><a href=\"https:\/\/doi.org\/10.1016\/j.jfluchem.2022.110046\" target=\"_blank\" rel=\"noreferrer noopener\"><em>&#8222;Dehydrofluorination reactions at Lewis acidic ACF in the presence of HSnBu<sub>3<\/sub>&#8222;<\/em><\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n<div class=\"wp-block-image\">\n<figure class=\"aligncenter size-large is-resized\"><img loading=\"lazy\" decoding=\"async\" width=\"519\" height=\"88\" src=\"https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2022\/10\/Dehydrofluorination-reactions-at-Lewis-acidic-ACF-in-the-presence-of-HSnBu3.svg\" alt=\"\" class=\"wp-image-1750\" style=\"width:752px;height:193px\"\/><\/figure>\n<\/div>\n\n\n<hr class=\"wp-block-separator aligncenter has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table style=\"\u201cborder:none;\u201c\"><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">168.<\/td><td style=\"vertical-align: top; border: none;\">S. Sander, T. Braun, <em>Angew. Chem. Int. Ed.<\/em> <strong>2022<\/strong>, <em>61<\/em>, e202204678.<br><em><a href=\"https:\/\/doi.org\/10.1002\/anie.202204678\" target=\"_blank\" rel=\"noreferrer noopener\"><em>&#8222;Platinum-Catalyzed Hydrofluorination of Alkynes: Hydrogen Bonding to Indolylphosphine Ligands to Provide Fluoride Reactivity&#8220;<\/em><\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n<div class=\"wp-block-image\">\n<figure class=\"aligncenter size-large is-resized\"><img loading=\"lazy\" decoding=\"async\" width=\"495\" height=\"204\" src=\"https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2022\/06\/Platinum-Catalyzed-Hydrofluorination-of-Alkynes-Hydrogen-Bonding-to-Indolylphosphine-Ligands-to-Provide-Fluoride-Reactivity.svg\" alt=\"\" class=\"wp-image-1707\" style=\"width:700px;height:undefinedpx\"\/><\/figure>\n<\/div>\n\n\n<hr class=\"wp-block-separator aligncenter has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table style=\"\u201cborder:none;\u201c\"><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">167.<\/td><td style=\"vertical-align: top; border: none;\">S. G. Rachor, R. Jaeger, T. Braun,  <em>Eur. J. Inorg. Chem.<\/em> <strong>2022<\/strong>, <em>2022<\/em>, e202200158.<br><em><a href=\"https:\/\/doi.org\/10.1002\/ejic.202200158\" target=\"_blank\" rel=\"noreferrer noopener\"><em>&#8222;Au(I) Fluorido Phosphine Complexes: Tools for the Hydrofluorination of Alkynes&#8220;<\/em><\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n<div class=\"wp-block-image\">\n<figure class=\"aligncenter size-large is-resized\"><img loading=\"lazy\" decoding=\"async\" width=\"567\" height=\"91\" src=\"https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2022\/06\/AuI-Fluorido-Phosphine-Complexes-Tools-for-the-Hydrofluorination-of-Alkynes.svg\" alt=\"\" class=\"wp-image-1700\" style=\"width:800px;height:150px\"\/><\/figure>\n<\/div>\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table style=\"\u201cborder:none;\u201c\"><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">166.<\/td><td style=\"vertical-align: top; border: none;\">M. Wozniak, S. Sander, B. Cula, M. Ahrens, T. Braun, <em>Chem. Eur. J.<\/em> <strong>2022<\/strong>, <em>28<\/em>, e202200626.<br><em><a href=\"https:\/\/doi.org\/10.1002\/chem.202200626\" target=\"_blank\" rel=\"noreferrer noopener\"><em>&#8222;Reactivity of Xantphos-Type Rhodium Complexes Towards SF<sub>4<\/sub>: SF<sub>3<\/sub> Versus SF<sub>2<\/sub> Complex Generation&#8220;<\/em><\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n<div class=\"wp-block-image\">\n<figure class=\"aligncenter size-large is-resized\"><img loading=\"lazy\" decoding=\"async\" width=\"309\" height=\"85\" src=\"https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2022\/06\/Reactivity-of-Xantphos-Type-Rhodium-Complexes-Towards-SF4-SF3-Versus-SF2-Complex-Generation.svg\" alt=\"\" class=\"wp-image-1697\" style=\"width:500px;height:undefinedpx\"\/><\/figure>\n<\/div>\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table style=\"\u201cborder:none;\u201c\"><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">165.<\/td><td style=\"vertical-align: top; border: none;\">X. Pan, M. Talavera, G. Scholz, T. Braun, <em>ChemCatChem<\/em> <strong>2022<\/strong>, <em>14<\/em>, e202200029.<br><em><a href=\"https:\/\/doi.org\/10.1002\/cctc.202200029\" target=\"_blank\" rel=\"noreferrer noopener\"><em>&#8222;Chlorodefluorination of Fluoromethanes and Fluoroolefins at a Lewis Acidic Aluminum Fluoride&#8220;<\/em><\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n<div class=\"wp-block-image\">\n<figure class=\"aligncenter size-large is-resized\"><img loading=\"lazy\" decoding=\"async\" width=\"478\" height=\"114\" src=\"https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2022\/06\/Chlorodefluorination-of-Fluoromethanes-and-Fluoroolefins-at-a-Lewis-Acidic-Aluminum-Fluoride.svg\" alt=\"\" class=\"wp-image-1681\" style=\"width:858px;height:129px\"\/><\/figure>\n<\/div>\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table style=\"\u201cborder:none;\u201c\"><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">164.<\/td><td style=\"vertical-align: top; border: none;\">M. Talavera, T. Braun, <em>Chem. Sci.<\/em> <strong>2022<\/strong>, <em>13<\/em>, 1130-1135.<br><em><a href=\"https:\/\/doi.org\/10.1039\/D1SC06713C\" target=\"_blank\" rel=\"noreferrer noopener\"><em>&#8222;Competing C\u2013H and C\u2013F bond activation reactions of a fluorinated olefin at Rh: a fluorido vinylidene complex as an intermediate in an unprecedented dehydrofluorination step&#8220;<\/em><\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n<div class=\"wp-block-image\">\n<figure class=\"aligncenter size-large is-resized\"><img loading=\"lazy\" decoding=\"async\" width=\"724\" height=\"157\" src=\"https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2022\/01\/Competing-C\u2013H-and-C\u2013F-bond-activation-fluorinated-olefin-at-Rh.svg\" alt=\"\" class=\"wp-image-1656\" style=\"width:850px;height:270px\"\/><\/figure>\n<\/div>\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table style=\"\u201cborder:none;\u201c\"><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">163.<\/td><td style=\"vertical-align: top; border: none;\">S. G. Rachor, R. M\u00fcller, P. Wittwer, M. Kaupp, T. Braun, <em>Inorg. Chem.<\/em> <strong>2022<\/strong>, <em>61<\/em>, 357-367.<br><em><a href=\"https:\/\/doi.org\/10.1021\/acs.inorgchem.1c02959\" target=\"_blank\" rel=\"noreferrer noopener\"><em>&#8222;Synthesis, Reactivity, and Bonding of Gold(I) Fluorido-Phosphine Complexes&#8220;<\/em><\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n<div class=\"wp-block-image\">\n<figure class=\"aligncenter size-large is-resized\"><img loading=\"lazy\" decoding=\"async\" width=\"590\" height=\"222\" src=\"https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2022\/01\/GoldI-Fluorido-Phosphine-Complexes.svg\" alt=\"\" class=\"wp-image-1635\" style=\"width:750px;height:270px\"\/><\/figure>\n<\/div>\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table style=\"\u201cborder:none;\u201c\"><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">162.<\/td><td style=\"vertical-align: top; border: none;\">D. Dirican, M. Talavera, T. Braun, <em>Chem. Eur. J.<\/em> <strong>2021<\/strong>, <em>27<\/em>, 17707-17712.<br><em><a href=\"https:\/\/doi.org\/10.1002\/chem.202103311\" target=\"_blank\" rel=\"noreferrer noopener\"><em>&#8222;Fluorination Reactions at a Platinum Carbene Complex: Reaction Routes to SF<sub>3<\/sub>, S(=O)F and Fluorido Complexes&#8220;<\/em><\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n<div class=\"wp-block-image\">\n<figure class=\"aligncenter size-large is-resized\"><img loading=\"lazy\" decoding=\"async\" width=\"579\" height=\"131\" src=\"https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2021\/12\/Fluorination-Reactions-at-a-Platinum-Carbene-Complex-Reaction-Routes-to-SF3-SOF-and-Fluorido-Complexes-1.svg\" alt=\"\" class=\"wp-image-1602\" style=\"width:700px;height:undefinedpx\"\/><\/figure>\n<\/div>\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table style=\"\u201cborder:none;\u201c\"><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">161.<\/td><td style=\"vertical-align: top; border: none;\">S. Sander, R. M\u00fcller, M. Ahrens, M. Kaupp, T. Braun, <em>Chem. Eur. J.<\/em> <strong>2021<\/strong>, <em>27<\/em>, 14287-14298.<br><em><a href=\"https:\/\/doi.org\/10.1002\/chem.202102451\" target=\"_blank\" rel=\"noreferrer noopener\"><em>&#8222;Platinum Indolylphosphine Fluorido and Polyfluorido Complexes: An Interplay between Cyclometallation, Fluoride Migration, and Hydrogen Bonding&#8220;<\/em><\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n<div class=\"wp-block-image\">\n<figure class=\"aligncenter size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"501\" height=\"527\" src=\"https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2021\/11\/Platinum-indolylphosphine-fluorido-and-polyfluorido-complexes-1.png\" alt=\"\" class=\"wp-image-1581\" srcset=\"https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2021\/11\/Platinum-indolylphosphine-fluorido-and-polyfluorido-complexes-1.png 501w, https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2021\/11\/Platinum-indolylphosphine-fluorido-and-polyfluorido-complexes-1-285x300.png 285w\" sizes=\"auto, (max-width: 501px) 100vw, 501px\" \/><\/figure>\n<\/div>\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table style=\"\u201cborder:none;\u201c\"><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">160.<\/td><td style=\"vertical-align: top; border: none;\">M. Talavera, T. Braun, <em>Chem. Eur. J.<\/em> <strong>2021<\/strong>, <em>27<\/em>, 11926-11934.<br><em><a href=\"https:\/\/doi.org\/10.1002\/chem.202101508\" target=\"_blank\" rel=\"noreferrer noopener\"><em>&#8222;Versatile Reaction Pathways of 1,1,3,3,3-Pentafluoropropene at Rh(I) Complexes [Rh(E)(PEt<sub>3<\/sub>)<sub>3<\/sub> (E=H, GePh<sub>3<\/sub>, Si(OEt)<sub>3<\/sub>, F, Cl): C-F versus C-H Bond Activation Steps&#8220;<\/em><\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n<div class=\"wp-block-image\">\n<figure class=\"aligncenter size-large is-resized\"><img loading=\"lazy\" decoding=\"async\" width=\"628\" height=\"217\" src=\"https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2021\/08\/Versatile-Reaction-Pathways-of-1_1_3_3_3-Pentafluoropropene-at-Rh_I_-Complexes-_Rh_E__PEt3_3-_E_H_-G.svg\" alt=\"Reaction scheme for activation of 1,1,3,3,3-Pentafluoropropene\" class=\"wp-image-1533\" style=\"width:700px;height:undefinedpx\"\/><\/figure>\n<\/div>\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table style=\"\u201cborder:none;\u201c\"><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">159.<\/td><td style=\"vertical-align: top; border: none;\">R. Jaeger, M. Talavera, T. Braun, <em>J. Fluorine Chem.<\/em> <strong>2021<\/strong>, <em>247<\/em>, 109803.<br><em><a href=\"https:\/\/doi.org\/10.1016\/j.jfluchem.2021.109803\" target=\"_blank\" rel=\"noreferrer noopener\"><em>&#8222;Studies on the reactivity of Rh(I) complexes towards SF<sub>5<\/sub>Cl&#8220;<\/em><\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n<div class=\"wp-block-image\">\n<figure class=\"aligncenter size-large is-resized\"><img loading=\"lazy\" decoding=\"async\" width=\"619\" height=\"150\" src=\"https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2021\/05\/SF5Cl-activation-at-RhI-1.svg\" alt=\"\" class=\"wp-image-1473\" style=\"width:700px;height:undefinedpx\"\/><\/figure>\n<\/div>\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table style=\"\u201cborder:none;\u201c\"><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">158.<\/td><td style=\"vertical-align: top; border: none;\">C. Becker, T. Braun, B. Paulus, <em>Catalysts<\/em> <strong>2021<\/strong>, <em>11<\/em>,&nbsp;565.<br><em><a href=\"https:\/\/doi.org\/10.3390\/catal11050565\" target=\"_blank\" rel=\"noreferrer noopener\"><em>&#8222;Theoretical Study on the Lewis Acidity of the Pristine AlF<sub>3<\/sub> and Cl-Doped \u03b1-AlF<sub>3<\/sub> Surfaces&#8220;<\/em><\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table style=\"\u201cborder:none;\u201c\"><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">157.<\/td><td style=\"vertical-align: top; border: none;\"> M.-C. Kervarec, T. Braun, M. Ahrens, E. Kemnitz,<em> Beilstein J. Org. Chem.<\/em> <strong>2020<\/strong>, <em>16<\/em>,&nbsp;2623-2635.<br><em><a href=\"https:\/\/doi.org\/10.3762\/bjoc.16.213\" target=\"_blank\" rel=\"noreferrer noopener\"><em>&#8222;Activation of pentafluoropropane isomers at a nanoscopic aluminum chlorofluoride: hydrodefluorination versus dehydrofluorination&#8220;<\/em><\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n<div class=\"wp-block-image is-style-default\">\n<figure class=\"aligncenter size-large is-resized\"><img loading=\"lazy\" decoding=\"async\" width=\"559\" height=\"154\" src=\"https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2020\/12\/publication157-1.svg\" alt=\"\" class=\"wp-image-1117\" style=\"width:650px;height:undefinedpx\"\/><\/figure>\n<\/div>\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table style=\"\u201cborder:none;\u201c\"><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">156.<\/td><td style=\"vertical-align: top; border: none;\"> M. Talavera, T. Braun,<em> Synlett<\/em> <strong>2020<\/strong>, <em>31<\/em>,&nbsp;1760-1774.<br><em><a href=\"https:\/\/doi.org\/10.1055\/s-0040-1707156\" target=\"_blank\" rel=\"noreferrer noopener\"><em>&#8222;Rhodium(I) Complexes as Useful Tools for the Activation of Fluoroolefins&#8220;<\/em><\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n<div class=\"wp-block-image\">\n<figure class=\"aligncenter size-large is-resized\"><img loading=\"lazy\" decoding=\"async\" width=\"360\" height=\"296\" src=\"https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2020\/12\/Publication156.svg\" alt=\"\" class=\"wp-image-1113\" style=\"width:450px;height:undefinedpx\"\/><\/figure>\n<\/div>\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<div style=\"height:20px\" aria-hidden=\"true\" class=\"wp-block-spacer\"><\/div>\n\n\n\n<figure class=\"wp-block-table\"><table style=\"\u201cborder:none;\u201c\"><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">155.<\/td><td style=\"vertical-align: top; border: none;\">M. Talavera, S. Hinze, T. Braun, R. Laubenstein, R. Herrmann,<em> Molecules<\/em> <strong>2020<\/strong>, <em>25<\/em>,&nbsp;3977.<br><em><a href=\"https:\/\/doi.org\/10.3390\/molecules25173977\" target=\"_blank\" rel=\"noreferrer noopener\"><em>&#8222;A SF<sub>5<\/sub> Derivative of Triphenylphosphine as an Electron-Poor Ligand Precursor for Rh and Ir Complexes&#8220;<\/em><\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n<div class=\"wp-block-image is-style-default\">\n<figure class=\"aligncenter size-large is-resized\"><img loading=\"lazy\" decoding=\"async\" width=\"162\" height=\"80\" src=\"https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2020\/12\/Publication155.svg\" alt=\"\" class=\"wp-image-1110\" style=\"width:213px;height:undefinedpx\"\/><\/figure>\n<\/div>\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table style=\"\u201cborder:none;\u201c\"><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">154.<\/td><td style=\"vertical-align: top; border: none;\">N. Pfister, M. Bui, T. Braun, P. Wittwer, M. Ahrens,<em> Z. Anorg. Allg. Chem.<\/em> <strong>2020<\/strong>, <em>646<\/em>,&nbsp;808-815.<br><em><a href=\"https:\/\/doi.org\/10.1002\/zaac.202000026\" target=\"_blank\" rel=\"noreferrer noopener\"><em>&#8222;Synthesis and Reactivity of Iridium(I) Fluorido Complexes: Oxidative Addition of SF<sub>4<\/sub> at trans-[Ir(F)(CO)(PEt<sub>3<\/sub>)<sub>2<\/sub>]&#8220;<\/em><\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n<div class=\"wp-block-image is-style-default\">\n<figure class=\"aligncenter size-large is-resized\"><img loading=\"lazy\" decoding=\"async\" width=\"915\" height=\"328\" src=\"https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2020\/08\/Publikation154.svg\" alt=\"\" class=\"wp-image-438\" style=\"width:650px;height:260px\"\/><\/figure>\n<\/div>\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">153.<\/td><td style=\"vertical-align: top; border: none;\">M.-C. Kervarec, E. Kemnitz, G. Scholz, S. Rudi\u0107, T. Braun, C. J\u00e4ger, A. A. L. Michalchuk, F. Emmerling,<em> Chem. Eur. J.<\/em> <strong>2020<\/strong>, <em>26<\/em>,&nbsp;7314-7322.<br><em><a href=\"https:\/\/doi.org\/10.1002\/chem.202001627\" target=\"_blank\" rel=\"noreferrer noopener\"><em>&#8222;A HF Loaded Lewis-Acidic Aluminium Chlorofluoride for Hydrofluorination Reactions&#8220;<\/em><\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n<div class=\"wp-block-image\">\n<figure class=\"aligncenter size-large is-resized\"><img loading=\"lazy\" decoding=\"async\" width=\"389\" height=\"107\" src=\"https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2020\/12\/Publication153-3.svg\" alt=\"\" class=\"wp-image-1101\" style=\"width:450px;height:undefinedpx\"\/><\/figure>\n<\/div>\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">152.<\/td><td style=\"vertical-align: top; border: none;\">D. Dirican, N. Pfister, M. Wozniak, T. Braun,<em> Chem. Eur. J.<\/em> <strong>2020<\/strong>, <em>26<\/em>,&nbsp;6945-6963.<br><em><a href=\"https:\/\/doi.org\/10.1002\/chem.201904493\" target=\"_blank\" rel=\"noreferrer noopener\">&#8222;Reactivity of Binary and Ternary Sulfur Halides towards Transition-Metal Compounds&#8220;<\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n<div class=\"wp-block-image\">\n<figure class=\"aligncenter size-large is-resized\"><img loading=\"lazy\" decoding=\"async\" width=\"382\" height=\"339\" src=\"https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2020\/12\/Publication152.svg\" alt=\"\" class=\"wp-image-1104\" style=\"width:480px;height:undefinedpx\"\/><\/figure>\n<\/div>\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">151.<\/td><td style=\"vertical-align: top; border: none;\">M. Talavera, G. Mei\u00dfner, S. G. Rachor, T. Braun,<em> Chem. Commun.<\/em> <strong>2020<\/strong>, <em>56<\/em>,&nbsp;4452-4455.<br><em><a href=\"https:\/\/doi.org\/10.1039\/D0CC01420F\" target=\"_blank\" rel=\"noreferrer noopener\"><em>&#8222;C-F activation reactions at germylium ions: dehydrofluorination of fluoralkanes&#8220;<\/em><\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n<div class=\"wp-block-image is-style-default\">\n<figure class=\"aligncenter size-large is-resized\"><img loading=\"lazy\" decoding=\"async\" width=\"253\" height=\"135\" src=\"https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2020\/12\/Publikation151.svg\" alt=\"\" class=\"wp-image-1090\" style=\"width:300px;height:0px\"\/><\/figure>\n<\/div>\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">150.<\/td><td style=\"vertical-align: top; border: none;\">C. P. Marshall, G. Scholz, T. Braun, E. Kemnitz,<em> Catal. Sci. Technol.<\/em> <strong>2020<\/strong>, <em>10<\/em>,&nbsp;391-402.<br><em><em><a href=\"https:\/\/pubs.rsc.org\/en\/content\/articlelanding\/2020\/CY\/C9CY01585J#!divAbstract\" target=\"_blank\" rel=\"noreferrer noopener\">&#8222;Strong Lewis acidic catalysts for C-F bond activation by fluorination of activated \u03b3-Al<sub>2<\/sub>O<sub>3<\/sub>&#8222;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">149.<\/td><td style=\"vertical-align: top; border: none;\">P. Tomar, T. Braun, E. Kemnitz,<em> Eur. J. Inorg. Chem.<\/em> <strong>2019<\/strong>, <em>44<\/em>,&nbsp;4735-4739.<br><em><em><a rel=\"noreferrer noopener\" href=\"https:\/\/doi.org\/10.1002\/ejic.201900921\" target=\"_blank\"><em>&#8222;Preparation of NHC Stabilized Al(III)fluorides: Fluorination of [(SIMes)AlMe<sub>3<\/sub>] with SF<sub>4<\/sub> or Me<sub>3<\/sub>SnF&#8220;<\/em><\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n<div class=\"wp-block-image\">\n<figure class=\"aligncenter size-large is-resized\"><img loading=\"lazy\" decoding=\"async\" width=\"346\" height=\"95\" src=\"https:\/\/www2.hu-berlin.de\/chemie\/braun\/wp-content\/uploads\/2020\/12\/Publication149.svg\" alt=\"\" class=\"wp-image-1107\" style=\"width:400px;height:undefinedpx\"\/><\/figure>\n<\/div>\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">148.<\/td><td style=\"vertical-align: top; border: none;\">M. Talavera, R. M\u00fcller, T. Ahrens, C. N. von Hahmann, B. Braun-Cula, M. Kaupp, T. Braun,<em> Faraday Discuss.<\/em> <strong>2019<\/strong>, <em>220<\/em>,&nbsp;328-349.<br><em><em><a rel=\"noreferrer noopener\" href=\"https:\/\/doi.org\/10.1039\/C9FD00059C\" target=\"_blank\"><em>&#8222;Activation of tetrafluoropropenes by rhodium(I) germyl and silyl complexes&#8220;<\/em><\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">147.<\/td><td style=\"vertical-align: top; border: none;\">C. Xu, M. Talavera, S. Sander, T. Braun,<em> Dalton Trans.<\/em> <strong>2019<\/strong>, <em>48<\/em>,&nbsp;16258-16267.<br><em><em><a rel=\"noreferrer noopener\" href=\"https:\/\/doi.org\/10.1039\/c9dt03371h\" target=\"_blank\">&#8222;C-H and C-F bond activation reactions of pentafluorostyrene at rhodium complexes&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">146.<\/td><td style=\"vertical-align: top; border: none;\">M. Talavera, C. N. von Hahmann, R. M\u00fcller, M. Ahrens, M. Kaupp, T. Braun,<em> Angew. Chem. Int. Ed.<\/em> <strong>2019<\/strong>, <em>58<\/em>,&nbsp;10688-10692; M. Talavera, C. N. von Hahmann, R. M\u00fcller, M. Ahrens, M. Kaupp, T. Braun,<em> Angew. Chem.<\/em> <strong>2019<\/strong>, <em>131<\/em>,&nbsp;10798-10802.<br><em><em><a rel=\"noreferrer noopener\" href=\"https:\/\/doi.org\/10.1002\/ange.201902872\" target=\"_blank\">&#8222;C-H and C-F bond activation reactions of fluorinated propenes at rhodium: Distinctive reactivity of the refrigerant HFO-1234yf&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">145.<\/td><td style=\"vertical-align: top; border: none;\">C. P. Marshall, G. Scholz, T. Braun, E. Kemnitz,<em> Dalton Trans.<\/em> <strong>2019<\/strong>, <em>48<\/em>,&nbsp;6834-6845.<br><em><em><a rel=\"noreferrer noopener\" href=\"https:\/\/doi.org\/10.1039\/C9DT00831D\" target=\"_blank\">&#8222;Nb-doped variants of high surface aluminium fluoride: a very strong bi-acidic solid catalyst&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">144.<\/td><td style=\"vertical-align: top; border: none;\">\u00d2. Torres, N. Pfister, T. Braun, P. Wittwer,<em> Dalton Trans.<\/em> <strong>2019<\/strong>, <em>48<\/em>,&nbsp;6153-6161.<br><em><em><a rel=\"noreferrer noopener\" href=\"https:\/\/doi.org\/10.1039\/C9DT00780F\" target=\"_blank\">&#8222;C\u2013F activation of perfluorophenazine at nickel: selectivity and mechanistic investigations&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">143.<\/td><td style=\"vertical-align: top; border: none;\">M. Kervarec, C. P.\nMarshall, T. Braun, E. Kemnitz,<span style=\"font-style: italic;\">\nJ.\nFluorine Chem. <\/span> <b>2019<\/b>, <i>221<\/i>,\n61-65.<br><em><em><a rel=\"noreferrer noopener\" href=\"https:\/\/doi.org\/10.1016\/j.jfluchem.2019.04.001\" target=\"_blank\">&#8222;Selective\ndehydrofluorination of 2-chloro-1,1,1,2-tetrafluoropropane (HCFC-244bb)\nto 2-chloro-3,3,3-trifluoropropene (HFO-1233xf) using nanoscopic\naluminium fluoride catalysts at mild conditions&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">142.<\/td><td style=\"vertical-align: top; border: none;\">P. Roesch, R.\nM\u00fcller, A. Dallmann, G. Scholz, M. Kaupp, T. Braun, B.\nBraun-Cula, P. Wittwer, <span style=\"font-style: italic;\">Chem.\nEur. J. <\/span> <b>2019<\/b>, <i>25<\/i>,\n4678-4682.<br><em><em><a rel=\"noreferrer noopener\" href=\"https:\/\/doi.org\/10.1002\/chem.201900481\" target=\"_blank\">&#8222;A Silylene-Boran Lewis\nPair as a Tool for Trapping Water Molecule: Silanol Formation and\nDehydrogenation&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">141.<\/td><td style=\"vertical-align: top; border: none;\">B. Calvo, C. P.\nMarshall, T. Krahl, J. Kr\u00f6hnert, A. Trunschke, G. Scholz, T.\nBraun, E. Kemnitz, <span style=\"font-style: italic;\">Dalton\nTrans. <\/span> <b>2018<\/b>, <i>47<\/i>,\n16461-16473. <br><em><em><a rel=\"noreferrer noopener\" href=\"https:\/\/doi.org\/10.1039\/C8DT03279C\" target=\"_blank\">&#8222;Comparative study of\nthe strongest Lewis acids known: ACF and <i>HS<\/i>-AlF<sub>3<\/sub><\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">140.<\/td><td style=\"vertical-align: top; border: none;\">H. Baumgarth, G.\nMeier, C. N. von Hahmann, T. Braun, <span style=\"font-style: italic;\">Dalton\nTrans. <\/span> <b>2018<\/b>, <i>47<\/i>,\n16299-16304. <br><em><em><a rel=\"noreferrer noopener\" href=\"https:\/\/doi.org\/10.1039\/C8DT03853H\" target=\"_blank\">&#8222;Reactivity of rhodium\nand iridium peroxido complexes towards hydrogen in the presence of B(C<sub>6<\/sub>F<sub>5<\/sub>)<sub>3<\/sub>\nor [H(OEt<sub>2<\/sub>)<sub>2<\/sub>][B{3,5-(CF<sub>3<\/sub>)<sub>2<\/sub>C<sub>6<\/sub>H<sub>3<\/sub>}<sub>4<\/sub>]<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">139.<\/td><td style=\"vertical-align: top; border: none;\">N. Pfister, T.\nBraun, P. Wittwer, M. Ahrens, <span style=\"font-style: italic;\">Z.\nAnorg. Allg. Chem.<\/span> <b>2018<\/b>, <i>644<\/i>,\n1064-1070. <br><em><em><a rel=\"noreferrer noopener\" href=\"https:\/\/doi.org\/10.1002\/zaac.201800323\" target=\"_blank\">&#8222;Selective Formation and\nCharacterization of a Rh<sup>III<\/sup> \u03bb<sup>4<\/sup>-Trifluorosulfanyl\nComplex<\/span>&#8222;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">138.<\/td><td style=\"vertical-align: top; border: none;\">P. Tomar, T. Braun,\nE. Kemnitz, <span style=\"font-style: italic;\">Chem.\nCommun.<\/span> <b>2018<\/b>, <i>54<\/i>,\n9753-9756.<br><em><em><a rel=\"noreferrer noopener\" href=\"https:\/\/doi.org\/10.1039\/c8cc05494k\" target=\"_blank\">&#8222;Photochemical\nactivation of SF<sub>6<\/sub> by N-heterocyclic carbenes to\nprovide a deoxyfluorinating reagent&#8220; <\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">137.<\/td><td style=\"vertical-align: top; border: none;\">S. Mebs, S. I.\nKall\u00e4ne, T. Braun, <span style=\"font-style: italic;\">Z.\nKristallog. \u2013 Cryst. Mater.<\/span> <b>2018<\/b>, <i>233<\/i>,\n615-626.<br><em><em><a rel=\"noreferrer noopener\" href=\"https:\/\/doi.org\/10.1515\/zkri-2017-2141\" target=\"_blank\">&#8222;Hapticity of asymmetric\nrhodium-allyl compounds in the light of real-space bonding indicators&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">136.<\/td><td style=\"vertical-align: top; border: none;\">M. A. Ellwanger, C.\nvon Randow, S. Steinhauer, Y. Zhou, A. Wiesner, H. Beckers, T. Braun,\nS. Riedel, <span style=\"font-style: italic;\">Chem. Commun.<\/span> <b>2018<\/b>,\n<i>54<\/i>,\n9301-9304.<br><em><em><a rel=\"noreferrer noopener\" href=\"https:\/\/doi.org\/10.1039\/C8CC05233F\" target=\"_blank\">&#8222;Tuning the Lewis\nacidity of difluorido gold(III) complexes: the synthesis of [AuClF<sub>2<\/sub>(SIMes)]\nand [AuF<sub>2<\/sub>(OTeF<sub>5<\/sub>)(SIMes)]&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">135.<\/td><td style=\"vertical-align: top; border: none;\">A. L. Raza, M. F.\nKuehnel, M. Talavera, M. Teltewskoi, M. Ahrens, P. Kl\u00e4ring, T.\nBraun, D. Lentz, <span style=\"font-style: italic;\">J.\nFluorine Chem.<\/span> <b>2018<\/b>, <i>214<\/i>,\n80-85.<br><em><em><a rel=\"noreferrer noopener\" href=\"https:\/\/doi.org\/10.1016\/j.jfluchem.2018.08.002\" target=\"_blank\">&#8222;Reactivity of rhodium\nhydrido and silyl complexes towards 1,1-difluoroallene&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">134.<\/td><td style=\"vertical-align: top; border: none;\">P. Wittwer, A.\nStelzer, T. Braun, <span style=\"font-style: italic;\">Eur.\nJ. Inorg. Chem.<\/span> <b>2018<\/b>, <i>27<\/i>,\n3187-3194.<br><em><em><a rel=\"noreferrer noopener\" href=\"https:\/\/doi.org\/10.1002\/ejic.201800564\" target=\"_blank\">&#8222;Reactivity of Cp*Al\ntowards Silanols: Formation and Hydrolysis of Alumosiloxanes&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">133.<\/td><td style=\"vertical-align: top; border: none;\">M. A.\nEllwanger, S. Steinhauer, P. Golz, T. Braun,\nS. Riedel, <span style=\"font-style: italic;\">Angew.\nChem.<\/span> <b>2018<\/b>, <i>130<\/i>,\n7328-7332; <span style=\"font-style: italic;\">Angew.\nChem. Int. Ed.<\/span> <b>2018<\/b>, <i>57<\/i>,\n7210-7214.<br><em><em><a rel=\"noreferrer noopener\" href=\"https:\/\/doi.org\/10.1002\/anie.201802952\" target=\"_blank\">&#8222;Stabilization of Lewis\nAcidic AuF<sub>3<\/sub>\nas an N-Heterocyclic Carbene Complex: Preparation and Characterization\nof [AuF<sub>3<\/sub>(SIMes)]&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">132.<\/td><td style=\"vertical-align: top; border: none;\">C. N. von Hahnmann,\nM. Talavera, C. Xu, T. Braun, <span style=\"font-style: italic;\">Chem.\nEur. J.<\/span> <b>2018<\/b>, <i>24<\/i>,\n11131-11138.<br><em><em><a rel=\"noreferrer noopener\" href=\"https:\/\/doi.org\/10.1002\/chem.201801662\" target=\"_blank\">&#8222;Reactivity of\n3,3,3-Trifluoropropyne at Rhodium Complexes: Development of\nHydroboration Reactions&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">131.<\/td><td style=\"vertical-align: top; border: none;\">C. P. Marshall, T.\nBraun, E. Kemnitz, <span style=\"font-style: italic;\">Catal.\nSci. Technol.<\/span> <b>2018<\/b>, <i>8<\/i>,\n3151-3159.<br><em><em><a rel=\"noreferrer noopener\" href=\"https:\/\/doi.org\/10.1039\/C8CY00502H\" target=\"_blank\">&#8222;Modifying the\nreactivity of a solid Lewis acid: niobium and antimony doped nanoscopic\naluminum fluoride&#8220; <\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">130.<\/td><td style=\"vertical-align: top; border: none;\">C. Berg, N.\nPfister, T. Braun, B. Braun-Cula, <span style=\"font-style: italic;\">Chem.\nEur. J.<\/span> <b>2018<\/b>, <i>24<\/i>,\n7985-7990.<br><em><em><a rel=\"noreferrer noopener\" href=\"https:\/\/doi.org\/10.1002\/chem.201800503\" target=\"_blank\">&#8222;Diverse Reactivity of\nPlatinum SF<sub>3<\/sub> and SF<sub>2<\/sub>\nComplexes towards EtOH and Me<sub>3<\/sub>SiOEt&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">129.<\/td><td style=\"vertical-align: top; border: none;\">M.\nWozniak, T. Braun, M. Ahrens, B. Braun-Cula, P. Wittwer, R. Herrmann,\nR. Laubenstein, <span style=\"font-style: italic;\">Organometallics<\/span>\n<b>2018<\/b>, <i>37<\/i>,\n821-828.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1021\/acs.organomet.7b00858\" target=\"_blank\">&#8222;Activation\nof SF<sub>6<\/sub>\nat a Xantphos-Type Rhodium Complex&#8220; <\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">128.<\/td><td style=\"vertical-align: top; border: none;\">B.\nCalvo, T. Braun, E. Kemnitz, <span style=\"font-style: italic;\">ChemCatChem<\/span>\n<b>2018<\/b>, <i>10<\/i>,\n403-406.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1002\/cctc.201701327\" target=\"_blank\">&#8222;Hydrogen\/Deuterium-Exchange\nReactions of Methane with Aromatics and Cyclohexane Catalyzed by a\nNanoscopic Aluminium Chlorofluoride&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">127.<\/td><td style=\"vertical-align: top; border: none;\">G.\nMei\u00dfner, K. Kretschmar, T. Braun, E. Kemnitz, <span style=\"font-style: italic;\">Angew.\nChem.<\/span> <b>2017<\/b>, <i>129<\/i>,\n16556-16559; Angew. Chem. Int. Ed. <b>2017<\/b>, <i>56<\/i>,\n16338-16341.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1002\/anie.201707759\" target=\"_blank\">&#8222;Consecutive\nTransformations of Tetrafluoropropenes: Hydrogermylation and Catalytic\nC\u2212F Activation Steps at a Lewis Acidic Aluminum Fluoride&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">126.<\/td><td style=\"vertical-align: top; border: none;\">R.\nLaubenstein, M. Ahrens, T.\nBraun, <span style=\"font-style: italic;\">Z.\nAnorg. Allg. Chem. <\/span><b>2017<\/b>, <i>643<\/i>,\n1723-1729.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1002\/zaac.201700276\" target=\"_blank\">&#8222;Synthesis\nand Structures of\nGallium-\u03b2-Diketiminate Complexes: Isolation of a Dinuclear\nGallium(II) Complex&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">125.<\/td><td style=\"vertical-align: top; border: none;\">J.\nKohlmann, T. Braun, <span style=\"font-style: italic;\">J.\nFluorine\nChem. <\/span><b>2017<\/b>, <i>203<\/i>,\n140-145.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1016\/j.jfluchem.2017.08.003\" target=\"_blank\">&#8222;Synthesis\nand reactivity of a cationic palladium complex as possible intermediate\nin a Suzuki-Miyaura cross-coupling reaction&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">124.<\/td><td style=\"vertical-align: top; border: none;\">K.\nS. Lokare, P. Wittwer, B. Braun-Cula, N. Frank, S. Hoof, T. Braun, C.\nLimberg, <span style=\"font-style: italic;\">Z.\nAnorg. Allg. Chem. <\/span><b>2017<\/b>, <i>643<\/i>,\n1581-1588.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1002\/zaac.201700295\" target=\"_blank\">&#8222;Mimicking\nBase Ineraction with Acidic Sites [Si-O(H)-Al]\nof Zeolites in Molecular\nModels&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">123.<\/td><td style=\"vertical-align: top; border: none;\">P.\nRoesch, U. Warzok, M. Enke, R. M\u00fcller, C. Schattenberg, C. A.\nSchalley, M. Kaupp, T. Braun, P. Wittwer, <span style=\"font-style: italic;\">Chem. Eur. J.<\/span> <b>2017<\/b>, <i>23<\/i>,\n13964-13972.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1002\/chem.201702393\" target=\"_blank\">&#8222;Reactivity\nof the Sterically Demanding Siloxanediol Mes<sub>2<\/sub>Si(OH)-(\u03bc-O)Si(OH)Mes<sub>2<\/sub>\nTowards Water and Ether Molecules&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">122.<\/td><td style=\"vertical-align: top; border: none;\">M.\nA. Ellwanger, S. Steinhauer, P. Golz, H. Beckers, A. Wiesner, B.\nBraun-Cula, T. Braun, S. Riedel, <span style=\"font-style: italic;\">Chem.\nEur. J. <\/span><b>2017<\/b>, <i>23<\/i>,\n13501-12509.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1002\/chem.201702663\" target=\"_blank\">&#8222;Taming\nthe High Reactivity of Gold(III) Fluoride: Fluorido Gold(III) Complexes\nwith N-Based Ligands&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">121.<\/td><td style=\"vertical-align: top; border: none;\">G.\nMei\u00dfner, M. Feist, T. Braun, E. Kemnitz, <span style=\"font-style: italic;\">J. Organomet. Chem.<\/span> <b>2017<\/b>, <i>847<\/i>,\n234-241.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1016\/j.jorganchem.2017.04.030\" target=\"_blank\">&#8222;Selecive\nreduction of a C-Cl bond in halomethanes with Et<sub>3<\/sub>GeH\nat nanoscopic Lewis acidic Aluminium fluoride\nFormation of Fluorovinyl and Fluorido Complexes&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">120.<\/td><td style=\"vertical-align: top; border: none;\">J.\nKohlmann, T. Braun, R. Laubenstein, R. Herrmann, <span style=\"font-style: italic;\">Chem. Eur. J.<\/span> <b>2017<\/b>, <i>23<\/i>,\n12218-12232.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1002\/chem.201700549\" target=\"_blank\">&#8222;Suzuki-Miyaura\nCross-Coupling Reactions of Highly Fluorinated Arylboronic Esters:\nCatalytic Studies and Stoichiometric Model Reactions on the\nTransmetallation Step&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">119.<\/td><td style=\"vertical-align: top; border: none;\">G.\nMei\u00dfner, D. Dirican, C. J\u00e4ger, T. Braun, E. Kemnitz, <span style=\"font-style: italic;\">Catal.\nSci. Technol. <\/span><b>2017<\/b>, <i>7<\/i>,\n3348-3354.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1039\/C7CY00845G\" target=\"_blank\">&#8222;Et<sub>3<\/sub>GeH\nversus Et<sub>3<\/sub>SiH:\ncontrolling reaction pathways in catalytic C-F bond activations at a\nnanoscopic aluminium chlorofluoride&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">118.<\/td><td style=\"vertical-align: top; border: none;\">J.\nBerger, T. Braun, T. Ahrens, P. Kl\u00e4ring, R. Laubenstein, B.\nBraun-Cula, <span style=\"font-style: italic;\">Chem. Eur.\nJ.<\/span> <b>2017<\/b>, <i>23<\/i>,\n8886-8900.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1002\/chem.201700403\" target=\"_blank\">&#8222;The\nVersatile Behavior of Platinum Alkyne Complexes towards XeF<sub>2<\/sub>:\nFormation of Fluorovinyl and Fluorido Complexes&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">117.<\/td><td style=\"vertical-align: top; border: none;\">C.\nBerg, T. Braun, M. Ahrens, P. Wittwer, R. Herrmann, <span style=\"font-style: italic;\">Angew.\nChem.<\/span> <b>2017<\/b>, <i>129<\/i>,\n4364-4368; <span style=\"font-style: italic;\">Angew.\nChem. Int. Ed.<\/span> <b>2017<\/b>, <i>56<\/i>,\n4300-4304.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1002\/anie.201612417\" target=\"_blank\">&#8222;Activation\nof SF<sub>6<\/sub>\nat Platinum Complexes: Formation of SF<sub>3<\/sub>\nDerivatives and Their\nApplication in Deoxyfluorination Reactions&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">116.<\/td><td style=\"vertical-align: top; border: none;\">A.\nK. Siwek, M. Ahrens, M.\nFeist, T. Braun, E. Kemnitz, <span style=\"font-style: italic;\">ChemCatChem<\/span>\n<b>2017<\/b>, <i>9<\/i>,\n839-845.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1002\/cctc.201601238\" target=\"_blank\">&#8222;Activation\nof Chlorinated Methanes\nat the Surface of Nanoscopic Lewis Acidic Aluminum Fluorides&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">115.<\/td><td style=\"vertical-align: top; border: none;\">T.\nAhrens, B. Schmiedecke, T. Braun, R. Herrmann, R. Laubenstein, <span style=\"font-style: italic;\">Eur. J. Inorg. Chem.<\/span> <b>2017<\/b>, <i>3<\/i>,\n713-722.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1002\/ejic.201601122\" target=\"_blank\">&#8222;Activation\nof CS<sub>2<\/sub>\nand COS at a Rhodium(I) Germyl Complex: Generation of CS and\nCarbido Complexes&#8220; <\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">114.<\/td><td style=\"vertical-align: top; border: none;\">T.\nAhrens, M. Teltewskoi, M.\nAhrens, T. Braun, R. Laubenstein, <span style=\"font-style: italic;\">Dalton\nTrans.<\/span> <b>2016<\/b>, <i>45<\/i>,\n17495-17507.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1039\/C6DT03027K\" target=\"_blank\">&#8222;Competing\nreaction pathways of\n3,3,3-trifluoropropene at rhodium hydrido, silyl and germyl complexes:\nC-F bond activation versus hydrogermylation&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">113.<\/td><td style=\"vertical-align: top; border: none;\">R. Herrmann, P. Wittwer, T. Braun,<em> Eur. J. Inorg. Chem.<\/em> <strong>2016<\/strong>, 4898-4905.<br><em><em><a rel=\"noreferrer noopener\" href=\"https:\/\/doi.org\/10.1002\/ejic.201600652\" target=\"_blank\">&#8222;Platinum Complexes Bearing a tripodal Germyl Ligand&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">112.<\/td><td style=\"vertical-align: top; border: none;\">H.\nBaumgarth, G. Meier, T. Braun,\nB. Braun-Cula, <span style=\"font-style: italic;\">Eur. J.\nInorg. Chem.<\/span> <b>2016<\/b>,\n4565-4572.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1002\/ejic.201600682\" target=\"_blank\">&#8222;Rhodium\nand Iridium Fluorido and\nBifluorido Complexes Derived from Peroxido Precursors&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">111.<\/td><td style=\"vertical-align: top; border: none;\">L.\nZ\u00e1mostn\u00e1, T. Braun, <span style=\"font-style: italic;\">Nachrichten\naus der Chemie<\/span> <b>2016<\/b>, <i>64<\/i>,\n829-835.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1002\/nadc.20164046690\" target=\"_blank\">&#8222;Inertes\nSchwefelhexafluorid aktivieren&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">110.<\/td><td style=\"vertical-align: top; border: none;\">B.\nCalvo, J. Wuttke, T. Braun,\nE. Kemnitz, <span style=\"font-style: italic;\">ChemCatChem.<\/span> <b>2016<\/b>,\n<i>8<\/i>,\n1945-1950.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1002\/cctc.201600257\" target=\"_blank\">&#8222;Heterogeneous\nCatalytic\nHydroarylation of Olefins at a Nanoscopic Aluminium Chlorofluoride&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">109.<\/td><td style=\"vertical-align: top; border: none;\">A.\nC. Stelzer, P. Hrob\u00e1rik, T. Braun, M. Kaupp, B. Braun-Cula, <span style=\"font-style: italic;\">Inorg. Chem.<\/span> <b>2016<\/b>, <i>55<\/i>,\n4915-4923.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1021\/acs.inorgchem.6b00462\" target=\"_blank\">&#8222;Completing\nthe Heterocubane Family [Cp*AlE]<sub>4<\/sub>\n(E = O, S, Se, and Te) by\nSelective\nOxygenation and Sulfuration of [Cp*Al]<sub>4<\/sub>:\nDensity Functional\nTheory\nCalculations of [Cp*AlE]<sub>4<\/sub>\nand Reactivity of [Cp*AlO]<sub>4<\/sub>\ntoward\nHydrolysis&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">108.<\/td><td style=\"vertical-align: top; border: none;\">C.\nMitzenheim, T. Braun, R. Laubenstein, B. Braun, R. Herrmann, <span style=\"font-style: italic;\">Datlton Trans.<\/span> <b>2016<\/b>, <i>45<\/i>,\n6394-6404.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1039\/C5DT04923G\" target=\"_blank\">&#8222;Hydrodealkoxylation\nreactions of silyl ligands at platinum: reactivity of SIH<sub>3<\/sub>\nand SiH<sub>2<\/sub>Me\ncomplexes&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">107.<\/td><td style=\"vertical-align: top; border: none;\">C.\nBerg, R.\nLaubenstein, T. Braun, B. Braun, <span style=\"font-style: italic;\">Chem.\nCommun.<\/span> <b>2016<\/b>, <i>52<\/i>,\n3931-3934.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1039\/C5CC10219G\" target=\"_blank\">&#8222;Palladium-mediated\nborylation of pentafluorosulfanyl functionalized compounds: the crucial\nrole of metal fluorido complexes&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">106.<\/td><td style=\"vertical-align: top; border: none;\">T.\nAhrens, T. Braun, B. Braun, R. Herrmann, <span style=\"font-style: italic;\">Dalton Trans.<\/span> <b>2016<\/b>, <i>45<\/i>,\n4716-4728.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1039\/C5DT04845A\" target=\"_blank\">&#8222;Synthesis\nof a rhodium(I) germyl complex: a useful tool for C-H and C-F bond\nactivation reactions&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">105.<\/td><td style=\"vertical-align: top; border: none;\">S.\nI. Kall\u00e4ne, R.\nLaubenstein, T. Braun, M. Dietrich, <span style=\"font-style: italic;\">Eur.\nJ. Inorg. Chem.<\/span> <b>2016<\/b>,\n530-537.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1002\/ejic.201501210\" target=\"_blank\">&#8222;Activation\nof Si-Si and Si-H Bonds\nat a Platinum Bis(diphenylphosphanyl)ferrocene (dppf) Complex: Key\nSteps for the Catalytic Hydrogenolysis of Disilanes&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">104.<\/td><td style=\"vertical-align: top; border: none;\">R.\nLaubenstein, M.-D. Serb, U. Englert, G. Raabe, T. Braun, B. Braun, <span style=\"font-style: italic;\">Chem. Commun.<\/span> <b>2016<\/b>, <i>52<\/i>,\n1214-1217.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1039\/C5CC08992A\" target=\"_blank\">&#8222;Is\nit all in the hinge? A kryptoracemate and three of its alternative\nracemic polymorphs of an aminonitrile&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">103.<\/td><td style=\"vertical-align: top; border: none;\">F.\nLiebau, T. Braun, B. Braun, <span style=\"font-style: italic;\">J.\nFluorine Chem.<\/span> <b>2015<\/b>, <i>180<\/i>,\n192-200.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1016\/j.jfluchem.2015.09.014\" target=\"_blank\">&#8222;Dehydrogenation\nof cycloalkanes at rhodium complexes bearing fluorinated\ncyclopentadienyl ligands&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">102.<\/td><td style=\"vertical-align: top; border: none;\">J.\nBerger, T. Braun, R. Herrmann, B. Braun, <span style=\"font-style: italic;\">Dalton Trans.<\/span> <b>2015<\/b>, <i>44<\/i>,\n19553-19565.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1039\/C5DT02306H\" target=\"_blank\">&#8222;Reactivity of platinum alkyne complexes towards\nN-fluorobenzenesulfonimide: formaiton of platinum compounds bearing a\n\u03b2-fluorovinyl ligand&#8220; <\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">101.<\/td><td style=\"vertical-align: top; border: none;\">S.\nI. Kall\u00e4ne, T. Braun, M. Teltewskoi, B. Braun, R. Herrmann, R.\nLaubenstein, <span style=\"font-style: italic;\">Chem.\nCommun.<\/span> <b>2015<\/b>, <i>51<\/i>,\n14613-14616.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1039\/C5CC05606C\" target=\"_blank\">&#8222;Remarkable\nreactivity of a rhodium(I) boryl complex towards CO<sub>2<\/sub>\nand CS<sub>2<\/sub>:\nisolation of a carbido complex&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">100.<\/td><td style=\"vertical-align: top; border: none;\">L.\nZ\u00e1mostn\u00e1, T.\nBraun, <span style=\"font-style: italic;\">Angew.\nChem.<\/span> <b>2015<\/b>, <i>127<\/i>,\n10798-10802; <span style=\"font-style: italic;\">Angew.\nChem. Int. Ed.<\/span> <b>2015<\/b>, <i>54<\/i>,\n10652-10656.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1002\/anie.201505462\" target=\"_blank\">&#8222;Catalytic\nDegradation of Sulfur Hexafluoride by Rhodium Complexes&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">99.<\/td><td style=\"vertical-align: top; border: none;\">A.\nBittner, T. Braun, R. Herrmann, S. Mebs, <span style=\"font-style: italic;\">Chem. Eur. J.<\/span> <b>2015<\/b>, <i>21<\/i>,\n12299-12302.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1002\/chem.201502481\" target=\"_blank\">&#8222;Rhodium-Mediated\nOxygenation of\nNitriles with Dioxygen: Isolation of Rhodium Derivatives of\nPeroxyimidic Acids&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">98.<\/td><td style=\"vertical-align: top; border: none;\">H.\nBaumgarth, T. Braun, B. Braun, R. Laubenstein, R. Herrmann, <span style=\"font-style: italic;\">Eur. J. Inorg. Chem.<\/span> <b>2015<\/b>, <i>2015<\/i>,\n3157-3168.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1002\/ejic.201500384\" target=\"_blank\">&#8222;Synthesis\nof an iridium Peroxido Complex and its Reactivity Towards\nBr\u00f8nsted Acids&#8220; <\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">97.<\/td><td style=\"vertical-align: top; border: none;\">M.\nFeist, M. Ahrens, A. Siwek,\nT. Braun, E. Kemnitz, <span style=\"font-style: italic;\">J.\nTherm.\nAnal. Calorim.<\/span> <b>2015<\/b>, <i>121<\/i>,\n929-935.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1007\/s10973-015-4479-2\" target=\"_blank\">&#8222;Triethylsilane-loaded\naluminium\nchlorofluoride&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">96.<\/td><td style=\"vertical-align: top; border: none;\">A.\nL. Raza, T. Braun, <span style=\"font-style: italic;\">Chem.\nSci.<\/span> <b>2015<\/b>, <i>6<\/i>,\n4255-4260.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1039\/C5SC00877H\" target=\"_blank\">&#8222;Consecutive\nC-F bond activation and C-F bond formation of\nheteroaromatics at rhodium: the peculiar role of FSi(OEt)<sub>3<\/sub>&#8222;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">95.<\/td><td style=\"vertical-align: top; border: none;\">L.\nZ\u00e1mostn\u00e1, S. Sander, T. Braun, R. Laubenstein, B.\nBraun, R. Herrmann, P. Kl\u00e4ring, <span style=\"font-style: italic;\">Dalton\nTrans.<\/span> <b>2015<\/b>, <i>44<\/i>,\n9450-9469.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1039\/C5DT00819K\" target=\"_blank\">&#8222;Synthesis\nand structure of\nrhodium(I) silyl carbonyl complexes:\nphotochemical C-F and C-H bond activation of\nfluorinated aromatic compounds&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">94.<\/td><td style=\"vertical-align: top; border: none;\">S.\nI. Kall\u00e4ne, M. Teltewskoi, T. Braun, B. Braun, <span style=\"font-style: italic;\">Organometallics<\/span> <b>2015<\/b>, <i>34<\/i>,\n1156-1169.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1021\/om500952x\" target=\"_blank\">&#8222;C-H\nand C-F Bond Activations at a Rhodium(I) Boryl Complex: Reaction Steps\nfor the Catalytic Borylation of Fluorinated Aromatics&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">93.<\/td><td style=\"vertical-align: top; border: none;\">M.\nA. Chilleck, L. Hartenstein, T. Braun, P. W. Roesky, B. Braun, <span style=\"font-style: italic;\">Chem. Eur. J.<\/span> <b>2015<\/b>, <i>21<\/i>,\n2594-2602.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1002\/chem.201405662\" target=\"_blank\">&#8222;Cationic\nZinc Organyls as Precatalysts for Hydroamination Reactions&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">92.<\/td><td style=\"vertical-align: top; border: none;\">T.\nAhrens, J. Kohlmann, M. Ahrens, T. Braun, <span style=\"font-style: italic;\">Chem. Rev.<\/span> <b>2015<\/b>, <i>115<\/i>,\n931-972.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1021\/cr500257c\" target=\"_blank\">&#8222;Functionalization\nof Fluorinated Molecules by Transition-Metal-Mediated C-F Bond\nActivation to Access Fluorinated Building Blocks&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">91.<\/td><td style=\"vertical-align: top; border: none;\">R.\nHerrmann, T. Braun, S. Mebs, <span style=\"font-style: italic;\">Eur.\nJ.\nInorg. Chem.<\/span> <b>2014<\/b>, <i>28<\/i>,\n4826-4835.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1002\/ejic.201402256\" target=\"_blank\">&#8222;[Ge(H)(2-C<sub>6<\/sub>H<sub>4<\/sub>PPh<sub>2<\/sub>)<sub>3<\/sub>]\nas Ligand precursor at Ruthenium: Formation and Reactivity of\n[Ru(Cl){Ge(2-C<sub>6<\/sub>H<sub>4<\/sub>PPh<sub>2<\/sub>)<sub>3<\/sub>)}]&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">90.<\/td><td style=\"vertical-align: top; border: none;\">S.\nI.\nKall\u00e4ne, T. Braun, <span style=\"font-style: italic;\">Angew.\nChem.<\/span> <b>2014<\/b>, <i>126<\/i>,\n9465-9469; <span style=\"font-style: italic;\">Angew.\nChem. Int. Ed.<\/span> <b>2014<\/b>, <i>53<\/i>,\n9311-9315.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1002\/anie.201406424\" target=\"_blank\">&#8222;Catalytic\nBorylation of SCF<sub>3<\/sub>-Functionalized\nArenes by Rhodium(I) Boryl Complexes:\nRegioselective C-H Activation at the ortho-Position&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">89.<\/td><td style=\"vertical-align: top; border: none;\">G.\nMeier, V. Steck, B. Braun, A. Ei\u00dfler, R. Herrmann, M. Ahrens,\nR. Laubenstein, T. Braun, <span style=\"font-style: italic;\">Eur.\nJ.\nInorg. Chem.<\/span> <b>2014<\/b>,\n2793-2808.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1002\/ejic.201402087\" target=\"_blank\">&#8222;Synthesis\nand Structures of Fluorinated (\u03b2-Diketiminato)rhodium\nComplexes: Si-H Activation of Silanes at a Carbonyl Complex&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">88.<\/td><td style=\"vertical-align: top; border: none;\">S.\nI.\nKall\u00e4ne, T. Braun, B. Braun, S. Mebs, <span style=\"font-style: italic;\">Dalton\nTrans.<\/span> <b>2014<\/b>, <i>43<\/i>,\n6786-6801.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1039\/C4DT00080C\" target=\"_blank\">&#8222;Versatile\nreactivity of a rhodium(I) boryl complex towards ketones and\nimines&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">87.<\/td><td style=\"vertical-align: top; border: none;\">L.\nZ\u00e1mostn\u00e1, T. Braun, B. Braun, <span style=\"font-style: italic;\">Angew.\nChem.<\/span> <b>2014<\/b>, <i>126<\/i>,\n2783-2787; <span style=\"font-style: italic;\">Angew.\nChem. Int. Ed.<\/span> <b>2014<\/b>, <i>53<\/i>,\n2745-2749.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1002\/anie.201308254\" target=\"_blank\">&#8222;S-F\nand S-C Activation of SF<sub>6<\/sub>\nand SF<sub>5<\/sub>\nDerivatives\nat Rhodium: Conversion of SF<sub>6<\/sub>\ninto H<sub>2<\/sub>S&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">86.<\/td><td style=\"vertical-align: top; border: none;\">M.\nChilleck, T. Braun, B. Braun,\nS. Mebs, <span style=\"font-style: italic;\">Organometallics<\/span> <b>2014<\/b>,\n<i>33<\/i>,\n551-560.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1021\/om401076g\" target=\"_blank\">&#8222;Neutral\nand Cationic Zinc Complexes\nwith N- and S-Donor-Functionalized Cyclopentadienyl Ligands&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">85.<\/td><td style=\"vertical-align: top; border: none;\">T.\nAhrens, T. Braun, B. Braun, <span style=\"font-style: italic;\">Z.\nAnorg. Allg. Chem.<\/span> <b>2014<\/b>, <i>640<\/i>,\n93-99.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1002\/zaac.201300451\" target=\"_blank\">&#8222;Activation\nof 1,2-Dihydridodisilanes\nat Platinum(0) Phosphine Complexes: Syntheses and Structures of\nBissilyl Platinum(II)\nComplexes&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">84.<\/td><td style=\"vertical-align: top; border: none;\">M.\nTeltewskoi, S. I. Kall\u00e4ne, T. Braun, R. Herrmann, <span style=\"font-style: italic;\">Eur. J. Inorg. Chem.<\/span> <b>2013<\/b>, <i>33<\/i>,\n5762-5768.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1002\/ejic.201300972\" target=\"_blank\">Synthesis\nof Rhodium(I) Boryl\nComplexes: Catalytic N\u2013H Activation of Anilines and Ammonia&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">83.<\/td><td style=\"vertical-align: top; border: none;\">P.\nKl\u00e4ring, T. Braun, <span style=\"font-style: italic;\">Angew.\nChem.<\/span> <b>2013<\/b>, <i>125<\/i>,\n11302-11307; <span style=\"font-style: italic;\">Angew.\nChem. Int. Ed.<\/span> <b>2013<\/b>, <i>52<\/i>,\n11096-11101.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1002\/anie.201305106\" target=\"_blank\">&#8222;Insertion\nof CS<sub>2<\/sub>\ninto Iridium\u2013Fluorine Bonds&#8220; <\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">82.<\/td><td style=\"vertical-align: top; border: none;\">L.\nZ\u00e1mostn\u00e1, M.\nAhrens, T. Braun, <span style=\"font-style: italic;\">J.\nFluorine Chem.<\/span> <b>2013<\/b>, <i>155<\/i>,\n132-142.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1016\/j.jfluchem.2013.05.021\" target=\"_blank\">&#8222;Catalytic\nhydrodefluorination of\nfluoroaromatics with silanes as hydrogen source at a binuclear rhodium\ncomplex: Characterization of key intermediates&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">81.<\/td><td style=\"vertical-align: top; border: none;\">A.\nEi\u00dfler, P. Kl\u00e4ring, F. Emmerling, T. Braun, <span style=\"font-style: italic;\">Eur. J. Inorg. Chem.<\/span> <b>2013<\/b>, <i>27<\/i>,\n4775-4788.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1002\/ejic.201300625\" target=\"_blank\">&#8222;\u03b1-Dialdimine\nComplexes of Rhodium(I) and Iridium(I): Their Reactivity with Dioxygen\nand Dihydrogen&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">80.<\/td><td style=\"vertical-align: top; border: none;\">C.\nMitzenheim, T. Braun, <span style=\"font-style: italic;\">Angew.\nChem.<\/span> <b>2013<\/b>, <i>125<\/i>,\n8787-8790; <span style=\"font-style: italic;\">Angew.\nChem. Int. Ed.<\/span> <b>2013<\/b>, <i>52<\/i>,\n8625-8628.<br><em><em><a rel=\"noreferrer noopener\" href=\"https:\/\/doi.org\/10.1002\/ange.201302459\" target=\"_blank\">&#8222;Si-Si\nand Si-O Bond Activation at Platinum: Stepwise Formation of a SiH<sub>3<\/sub>\nComplex&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">79.<\/td><td style=\"vertical-align: top; border: none;\">A.\nL. Raza, J. Panetier, M. Teltewskoi, S. Macgregor, T. Braun, <span style=\"font-style: italic;\">Organometallics <\/span> <b>2013<\/b>, <i>32<\/i>,\n3795-3807.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1021\/om400150p\" target=\"_blank\">&#8222;Rhodium(I)\nSilyl Complexes for C\u2013F Bond Activation Reactions of Aromatic\nCompounds: Experimental and Computational Studies&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">78.<\/td><td style=\"vertical-align: top; border: none;\">B.\nRabay, T. Braun, J. P. Falkenhagen, <span style=\"font-style: italic;\">Dalton\nTrans.<\/span> <b>2013<\/b>, <i>42<\/i>,\n8058-8065.<br><em><em><a rel=\"noreferrer noopener\" href=\"https:\/\/doi.org\/10.1039\/C9DT00780F\" target=\"_blank\">&#8222;Photolytic\nC\u2013H activation and\ndehydrogenation of alkanes at cyclopentadienyl iridium complexes in a\nperfluorinated solvent&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">77.<\/td><td style=\"vertical-align: top; border: none;\">M.\nAhrens, G. Scholz, T. Braun, E. Kemnitz, <span style=\"font-style: italic;\">Angew.\nChem.<\/span> <b>2013<\/b>, <i>125<\/i>,\n5436-5440; <span style=\"font-style: italic;\">Angew.\nChem. Int. Ed.<\/span> <b>2013<\/b>, <i>52<\/i>,\n5328-5332.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1002\/anie.201300608\" target=\"_blank\">&#8222;Catalytic\nHydrodefluorination of Fluoromethanes at Room Temperature by\nSilylium-ion-like Surface Species&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">76.<\/td><td style=\"vertical-align: top; border: none;\">M.\nKuehnel, D. Lentz, T. Braun, <span style=\"font-style: italic;\">Angew.\nChem.<\/span> <b>2013<\/b>, <i>125<\/i>,\n3412-3433; <span style=\"font-style: italic;\">Angew.\nChem. Int. Ed.<\/span> <b>2013<\/b>, <i>52<\/i>,\n3328-3348.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1002\/anie.201205260\" target=\"_blank\">&#8222;Synthesis\nof Fluorinated Building Blocks by Transition-Metal-Mediated\nHydrodefluorination Reactions&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">75.<\/td><td style=\"vertical-align: top; border: none;\">M.\nChilleck, T. Braun, R. Herrmann, B. Braun, <span style=\"font-style: italic;\">Organometallics<\/span> <b>2013<\/b>, <i>32<\/i>,\n1067-1074.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1021\/om301181e\" target=\"_blank\">&#8222;Zinc\nComplexes with the N-Donor-Functionalized Cyclopentadienyl Ligand\nC<sub>5<\/sub>Me<sub>4<\/sub>(CH<sub>2<\/sub>)<sub>2<\/sub>NMe<sub>2<\/sub>&#8222;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">74.<\/td><td style=\"vertical-align: top; border: none;\">J.\nVoigt, M. Chilleck, T. Braun, <span style=\"font-style: italic;\">Dalton\nTrans.<\/span> <b>2013<\/b>, <i>42<\/i>,\n4052-4058.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1039\/C3DT32530J\" target=\"_blank\">&#8222;Activation\nof Si\u2013Si and Si\u2013H bonds at Pt: a catalytic\nhydrogenolysis of silicon\u2013silicon bonds&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">73.<\/td><td style=\"vertical-align: top; border: none;\">D. Breyer, T. Braun,\nEfficient Preparations of Fluorine&nbsp;Compounds, Vol. 1, H. W.\nRoesky\n(Hrsg.), John Wiley &amp; Sons,\nHoboken <b>2012<\/b>,\n237-239.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1002\/9781118409466.ch35\" target=\"_blank\">&#8222;Palladium-Mediated Synthesis\nof 4-Vinyltetrafluoropyridine and\n2,3,5,6-Tetrafluoropyridine&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">72.<\/td><td style=\"vertical-align: top; border: none;\">M. Teltewskoi, T. Braun,\nEfficient Preparations of Fluorine&nbsp;Compounds, Vol. 1, H. W.\nRoesky\n(Hrsg.), John Wiley &amp; Sons,\nHoboken <b>2012<\/b>,\n235-236.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1002\/9781118409466.ch34\" target=\"_blank\">&#8222;Rhodium-Mediated Synthesis of\na Tetrafluoropyridyl-2-boronate Ester&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">71.<\/td><td style=\"vertical-align: top; border: none;\">F. Wehmeier, T. Braun,\nEfficient Preparations of Fluorine&nbsp;Compounds, Vol. 1, H. W.\nRoesky\n(Hrsg.), John Wiley &amp; Sons,\nHoboken <b>2012<\/b>,\n232-234.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1002\/9781118409466.ch33\" target=\"_blank\">&#8222;Rhodium-Mediated Synthesis of\n(3,3,3-Trifluoropropyl)trimethoxysilane and\n(3,3,3-Trifluoropropyl)triphenylsilane&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">70.<\/td><td style=\"vertical-align: top; border: none;\">G.\nMeier, T. Braun, <span style=\"font-style: italic;\">Angew.\nChem.<\/span> <b>2012<\/b>, <i>124<\/i>,\n12732-12737; <span style=\"font-style: italic;\">Angew.\nChem. Int. Ed.<\/span> <b>2012<\/b>, <i>51<\/i>,\n12564-12569.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1002\/ange.201207073\" target=\"_blank\">&#8222;Hydrogenation\nof a Rhodium Peroxido\nComplex by Formate Derivatives: Mechanistic Studies and the Catalytic\nFormation of H<sub>2<\/sub>O<sub>2<\/sub>\nfrom O<sub>2<\/sub>&#8222;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">69.<\/td><td style=\"vertical-align: top; border: none;\">D.\nBreyer, J. Berger, T. Braun,\nS. Mebs, <span style=\"font-style: italic;\">J.\nFluorine Chem.<\/span> <b>2012<\/b>, <i>143<\/i>,\n263-271.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1016\/j.jfluchem.2012.06.025\" target=\"_blank\">&#8222;Nickel fluoro complexes as intermediates in catalytic cross-coupling reactions&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">68.<\/td><td style=\"vertical-align: top; border: none;\">S.\nMebs, M. A. Chilleck, S. Grabowsky, T. Braun, <span style=\"font-style: italic;\">Chem. Eur. J.<\/span> <b>2012<\/b>, <i>18<\/i>,\n11647-11661.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1002\/chem.201200870\" target=\"_blank\">&#8222;Hapticity Uncovered: Real-Space Bonding Indicators for Zincocene Chemistry&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">67.<\/td><td style=\"vertical-align: top; border: none;\">A.-K.\nJungton, C. Herwig, T. Braun, C. Limberg, <span style=\"font-style: italic;\">Chem. Eur. J.<\/span> <b>2012<\/b>, <i>18<\/i>,\n10009-10013.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1002\/chem.201201295\" target=\"_blank\">&#8222;Activation\nand Coordination of Ammonia at [Cp*Ir(H<sub>2<\/sub>)]:\nNMR and\nMatrix Isolation Studies&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">66.<\/td><td style=\"vertical-align: top; border: none;\">A.-K.\nJungton, P.\nKl\u00e4ring, T. Braun, A. Ei\u00dfler, <span style=\"font-style: italic;\">Z.\nAnorg. Allg. Chem.<\/span> <b>2012<\/b>, <i>638<\/i>,\n505-511.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1002\/zaac.201100440\" target=\"_blank\">&#8222;Synthesis,\nReactivity and Structure of Iridium Tetrafluoropyridyl Complexes:\nAmmonia Coordination and Activation&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">65.<\/td><td style=\"vertical-align: top; border: none;\">P.\nKl\u00e4ring, A.-K. Jungton, T. Braun, C. M\u00fcller, <span style=\"font-style: italic;\">Eur. J. Inorg. Chem.<\/span> <b>2012<\/b>,\n1430-1436.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1002\/ejic.201100917\" target=\"_blank\">&#8222;Synthesis,\nStructure\nand Reactivity of Iridium Hydrido Fluorido Complexes&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">64.<\/td><td style=\"vertical-align: top; border: none;\">T.\nBraun, <span style=\"font-style: italic;\">Organometallics<\/span> <b>2012<\/b><span style=\"font-style: italic;\">,\n31<\/span>,\n1213-1215.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1021\/om300083u\" target=\"_blank\">&#8222;Organometallic\nChemistry Meets Fluorine&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">63.<\/td><td style=\"vertical-align: top; border: none;\">D.\nBreyer\n, T. Braun, P. Kl\u00e4ring, <span style=\"font-style: italic;\">Organometallics<\/span>\n<b>2012<\/b><span style=\"font-style: italic;\">,\n31<\/span>,\n1417-1424.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1021\/om200998d\" target=\"_blank\">&#8222;Synthesis\nand Reactivity of the Fluoro Complex\ntrans-[Pd(F)(4-C<sub>5<\/sub>NF<sub>4<\/sub>)(<sup>i<\/sup>Pr<sub>2<\/sub>PCH<sub>2<\/sub>CH<sub>2<\/sub>OCH<sub>3<\/sub>)<sub>2<\/sub>]:\nC-F Bond Formation and Catalytic C-F Bond Activation\nReactions&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">62.<\/td><td style=\"vertical-align: top; border: none;\">&gt;M.\nPrechtl, M. Teltewskoi, A. Dimitrov, E. Kemnitz, T. Braun, <span style=\"font-style: italic;\">Chem. Eur. J<\/span><i>.<\/i> <b>2011<\/b><span style=\"font-style: italic;\">,\n17<\/span>,\n14385-14388.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1002\/chem.201102853\" target=\"_blank\">&#8222;Catalytic\nC-H Bond Activation at Nanoscale Lewis Acidic Aluminium Fluorides:\nH\/D Exchange Reactions at Aromatic and Aliphatic Hydrocarbons&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">61.<\/td><td style=\"vertical-align: top; border: none;\">J.\nVoigt, T. Braun, <span style=\"font-style: italic;\">Dalton\nTrans<\/span><i>.<\/i> <b>2011<\/b><span style=\"font-style: italic;\">, 40<\/span>,\n12699-12704.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1039\/C1DT11351H\" target=\"_blank\">&#8222;Si\u2013H\nand Si\u2013Si activation at Pt: synthesis and reactivity of\nneutral and\ncationic silyl complexes&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">60.<\/td><td style=\"vertical-align: top; border: none;\">M.\nA. Chilleck, T.\nBraun, B. Braun, <span style=\"font-style: italic;\">Chem.\nEur. J<\/span><i>.<\/i> <b>2011<\/b><span style=\"font-style: italic;\">, 17<\/span>,\n12902-12905.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1002\/chem.201102699\" target=\"_blank\">&#8222;Cationic\nCyclopentadienyl Zinc\nComplexes with Slipped Triple-Decker and Half-Sandwich\nStructures&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">59.<\/td><td style=\"vertical-align: top; border: none;\">P.\nKl\u00e4ring, S. Pahl, T.\nBraun, A. Penner, <span style=\"font-style: italic;\">Dalton\nTrans<\/span><i>.<\/i> <b>2011<\/b><span style=\"font-style: italic;\"><\/span>,\n6785-6791.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1039\/C1DT10173K\" target=\"_blank\">&#8222;Facile\noxidative\naddition of water at iridium: reactivity of\ntrans-[Ir(4-C<\/span><sub style=\"font-style: italic;\">5<\/sub><span\nstyle=\"font-style: italic;\">NF<sub>4<\/sub>)(H)(OH)(PiPr<sub>3<\/sub>)<sub>2<\/sub>]\ntowards CO<sub>2<\/sub>\nand NH<sub>3<\/sub>&#8222;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">58.<\/td><td style=\"vertical-align: top; border: none;\">A.\nPenner, T.\nBraun,<span style=\"font-style: italic;\"><i>&nbsp;<\/i><\/span><span\nstyle=\"font-style: italic;\">Eur.\nJ. Inorg. Chem<\/span><i>. <\/i><span style=\"font-weight: bold;\">2011<\/span><span\nstyle=\"font-style: italic;\"><\/span>,\n2579-2587.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1002\/ejic.201100135\" target=\"_blank\">&#8222;Rhodium\nand Iridium\nComplexes with \u03b1-Diketimine Ligands: Oxidative Addition of H<sub>2<\/sub>\nand O<sub>2<\/sub><\/span><i>&#8222;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">57.<\/td><td style=\"vertical-align: top; border: none;\">G.\nMeier, T.\nBraun, <span style=\"font-style: italic;\">Angew.\nChem.<b> <\/b><\/span><b>2011<\/b>,<span style=\"font-style: italic;\"><i>\n123<\/i><\/span>,\n3338-3342; <i>Angew.\nChem. Int. Ed.<\/i><b> <\/b><b>2011<\/b>,<span style=\"font-style: italic;\"><i>\n50<\/i><\/span>,\n3280-3284.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1002\/ange.201007315\" target=\"_blank\">&#8222;A\nRhodium Peroxide\nComplex in Mono-, Di- and Peroxygenation Reactions&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">56.<\/td><td style=\"vertical-align: top; border: none;\">T.\nBraun, F. Wehmeier, <span style=\"font-style: italic;\">Eur.\nJ. Inorg. Chem<\/span><i>.<\/i> <b>2011<\/b><span style=\"font-style: italic;\"><\/span>,\n613-625.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1002\/ejic.201001184\" target=\"_blank\">&#8222;C-F\nBond Activation of\nHighly Fluorinated Molecules at Rhodium: From\nModel Reactions to Catalyis&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">55.<\/td><td style=\"vertical-align: top; border: none;\">D. Breyer, T.\nBraun, A. Penner, <span style=\"font-style: italic;\">Dalton\nTrans<\/span><i>.<\/i> <b>2010<\/b><span style=\"font-style: italic;\"><\/span>,\n7513-7520.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1039\/C0DT00086H\" target=\"_blank\">&#8222;Isolation\nand\nreactivity of palladium hydrido complexes: intermediates in the\nhydrodefluorination of pentafluorpyridine&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">54.<\/td><td style=\"vertical-align: top; border: none;\">A.-K. Jungton, A.\nMeltzer, C. Pr\u00e4sang, T.\nBraun, M. Driess, A. Penner, <span style=\"font-style: italic;\">Dalton\nTrans<\/span><i>.<\/i> <b>2010<\/b><span style=\"font-style: italic;\"><\/span>,\n5436-5438.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1039\/b906189d\" target=\"_blank\">&#8222;Addition\nof\n[(<i><font face=\"Symbol\">h<\/font><\/i><sup>5<\/sup><i>-C<sub>5<\/sub>Me<sub>5<\/sub>)IrH<sub>4<\/sub>]\nto a zwitterionic silylene: stepwise formation of\niridium(<font size=\"-1\">V<\/font>)\nand iridium(<font size=\"-1\">III<\/font>)<\/i><\/span><i>-silylene\ncomplexes&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">53.<\/td><td style=\"vertical-align: top; border: none;\">M. Teltewskoi, J. A.\nPanetier, Stuart A.\nMacgregor, T. Braun, <i>Angew.\nChem.<\/i><b>\n2010<\/b><i>,\n122<\/i>, 4039-4043; <i>Angew.\nChem. Int. Ed.<\/i><b>\n2010<\/b><i>,\n49<\/i>, 3947-3951.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1002\/ange.201001070\" target=\"_blank\">&#8222;A Highly Reactive\nRhodium(I)-Boryl Complex as a Useful Tool\nfor C-H Bond Activation and Catalytic C-F Bond Borylation&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">52.<\/td><td style=\"vertical-align: top; border: none;\">A. Penner, T.\nSchr\u00f6der,T. Braun, and B.\nZiemer&nbsp; &nbsp;<i>Eur.\nJ. Inorg. Chem<\/i>. <b>2009<\/b>,\n4464-4464.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1002\/ejic.200900531\" target=\"_blank\">&#8222;Synthesis,\nStructure,\nand Reactivity of Rhodium Bipyridine Compounds:\nFormation of a Rh<\/span><sup style=\"font-style: italic;\">II<\/sup><span\nstyle=\"font-style: italic;\"> Hydrido Cluster and a Rh<\/span><sup\nstyle=\"font-style: italic;\">III<\/sup><span style=\"font-style: italic;\">\nPeroxide Complex&#8220;<\/span><\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">51.<\/td><td style=\"vertical-align: top; border: none;\">M. Ahijado-Salomon,\nAnn-Katrin Jungton, T.\nBraun,&nbsp;&nbsp;<span style=\"font-style: italic;\">Dalton\nTrans<\/span><i>.<\/i> <b>2009<\/b><span style=\"font-style: italic;\"><\/span>,\n7669-7677.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1039\/b906189d\" target=\"_blank\">&#8222;Activation of ethylene and\nammonia at iridium: C-H <\/i><span style=\"font-style: italic;\">versus<\/span><i>\nN-H\noxidative addition&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">50.<\/td><td style=\"vertical-align: top; border: none;\">T. Braun,&nbsp;M.\nAhijado-Salomon, K.\nAltenh\u00f6ner, M. Teltewskoi, S. Hinze,&nbsp;&nbsp;<i>Angew.\nChem.<\/i><b>\n2009<\/b><i>,\n121<\/i>, 1850-1854; <i>Angew.\nChem. Int. Ed.<\/i><b>\n2009<\/b><i>,\n48<\/i>, 1818-1822.<br><em><em><a rel=\"noreferrer noopener\" href=\"http:\/\/dx.doi.org\/10.1002\/ange.200805041\" target=\"_blank\">&#8222;C-F Activation at Rhodium\nBoryl Complexes: Formation of\n2-Fluoroalkyl-1,3,2-Dioxoborolanes by Catalystic Functionalization of\nHexafluoropropene&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">49.<\/td><td style=\"vertical-align: top; border: none;\">G. Meier, T.\nBraun,&nbsp;<i>Angew.\nChem.<\/i><b>\n200<span style=\"font-style: italic;\">9<\/span><\/b><i>,\n121<\/i>, 1546-1548; <i>Angew.\nChem. Int. Ed.<\/i><b>\n2009<\/b><i>,\n48<\/i>, 1575-1577.<br><em><em><a rel=\"noreferrer noopener\" href=\"https:\/\/doi.org\/10.1002\/anie.200805237\" target=\"_blank\">&#8222;Catalytic C-F Activation and\nHydrodefluorination of\nFluoroalkyl Groups&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">48.<\/td><td style=\"vertical-align: top; border: none;\">A. Roscher, T.\nBraun,&nbsp;<span style=\"font-style: italic;\">Dalton\nTrans<\/span><i>.<\/i> <b>2009<\/b><span style=\"font-style: italic;\"><\/span>,\n1378-1382.<br><em><em><a rel=\"noreferrer noopener\" href=\"https:\/\/scholar.google.com\/scholar_url?url=https:\/\/pubs.rsc.org\/en\/content\/articlehtml\/2009\/dt\/b815586k&amp;hl=de&amp;sa=T&amp;oi=gsb-ggp&amp;ct=res&amp;cd=0&amp;d=180609946410944230&amp;ei=AhDiX7zWGI7gygSm-KCACw&amp;scisig=AAGBfm2eAiAibXGD4UqXSli-xvUimjcv_Q\" target=\"_blank\">&#8222;Towards a Catalytic\nHydrogenolysis of Silicon-Silicon Bonds:\nFormation of Si-H Bonds from Disilanes and H<sub>2<\/sub>\nat\nPlatinum&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">47.<\/td><td style=\"vertical-align: top; border: none;\">E. Yegen, U. Zimmermann,\nW. E. S. Unger, T. Braun, <span style=\"font-style: italic;\">Plasma\nProcesses and\nPolymers&nbsp;<\/span><b>2009<\/b><i>,\n6<\/i>, 11-16.<br><em><em><a rel=\"noreferrer noopener\" href=\"https:\/\/scholar.google.com\/scholar_url?url=https:\/\/onlinelibrary.wiley.com\/doi\/abs\/10.1002\/ppap.200800100&amp;hl=de&amp;sa=T&amp;oi=gsb&amp;ct=res&amp;cd=0&amp;d=12224903151451837719&amp;ei=TBDiX77FLcedywTxxouACw&amp;scisig=AAGBfm1YUkmakUw2PzZk1RagLiu0I5YFzA\" target=\"_blank\">&#8222;C-F bond cleavage during\nderivatization reaction of amino\ngroups with TFAB and PFB at plasma processed organic surfaces&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">46.<\/td><td style=\"vertical-align: top; border: none;\">M. Ahijado-Salomon, T.\nBraun, A. Penner,&nbsp;<i>Angew.\nChem.<\/i><b>\n2008<\/b><i>,\n120<\/i>, 8999-9003; <i>Angew.\nChem. Int. Ed.<\/i><b>\n2008<\/b><i>,\n47<\/i>, 8867-8871.<br><em><em><a rel=\"noreferrer noopener\" href=\"https:\/\/scholar.google.com\/scholar_url?url=https:\/\/onlinelibrary.wiley.com\/doi\/abs\/10.1002\/anie.200803768&amp;hl=de&amp;sa=T&amp;oi=gsb&amp;ct=res&amp;cd=0&amp;d=14333879551591249943&amp;ei=hRDiX6TQMJaTygTghbOACw&amp;scisig=AAGBfm0nOguOP3b2YoGVqRiA4s0pJTd1fQ\" target=\"_blank\">&#8222;Stepwise Oxygenation of\nPinacolborane by a Rhodiumperoxo\nComplex: Detection of an Intermediate Metal Borate and Perborate&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">45.<\/td><td style=\"vertical-align: top; border: none;\">M. Ahijado-Salomon, T.\nBraun, I. Krossing, <span style=\"font-style: italic;\">Dalton\nTrans<\/span><i>.<\/i> <b>2008<\/b><span style=\"font-style: italic;\"><\/span>,\n5197-5206.<br><em><em><a rel=\"noreferrer noopener\" href=\"https:\/\/doi.org\/10.1039\/B807077F\" target=\"_blank\">&#8222;Iridium Derivates of\nFluornated Aromatics by C-H Activation:\nIsolation of Classical and Non-classical Hydrides&#8220;<\/a><\/em><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">44.<\/td><td style=\"vertical-align: top; border: none;\">T. Schraub, P. Fischer, A. Steffen, T. Braun, U. Radius, A. Mix <i>J. Am. Chem. Soc.<\/i> <b>2008<\/b>, <span style=\"font-style: italic;\">130<\/span>,\n9304-9317.<br><em><a>&#8222;C\u2212F Activation of Fluorinated Arenes using NHC-Stabilized Nickel(0) Complexes: Selectivity and Mechanistic Investigations&#8220;<\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">43.<\/td><td style=\"vertical-align: top; border: none;\">M. Ahijado, T. Braun, <i>Angew.\nChem.<\/i><b>\n2008<\/b><i>,\n120<\/i>, 2996-3000; <i>Angew.\nChem. Int. Ed.<\/i><b>\n2008<\/b><i>,\n47<\/i>, 2954-2958.<br><em><a>&#8222;Rhodium Derivatives of\nPeroxoboronic Acids and Peroxoboric\nAcid: Formation of Metallatrioxaborolanes from an <font face=\"Symbol\">h<\/font><\/i><sup>2<\/sup>\n-Peroxo Complex&#8220;<\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">42.<\/td><td style=\"vertical-align: top; border: none;\">A. Steffen, T. Braun, B.\nNeumann, H.-G. Stammler <i>Angew.\nChem<\/i>. <b>2007<\/b>, <i>119 <\/i>,8828-8832; <i>Angew. Chem. Int.\nEd.<\/i><b>\n200<span style=\"font-style: italic;\">7<\/span><\/b><i>,\n46<\/i>, 8674-8678.<br><em><a>&#8222;Palladium Fluro Complexes:\nUseful Tools to Access\nOrganometallic Metallamacrocycles&#8220;<\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">41.<\/td><td style=\"vertical-align: top; border: none;\">A. Steffen, T.\nHagemeister, T. Braun, P. Jutzi, B.\nNeumann,\nH.-G. Stammler <i>Organometallics<\/i>. <b>2007<\/b>, <i>26 <\/i>,\n3820\u20133825.<br><em><a>&#8222;Synthesis of 3,3,3-\nTrifluoropropyl Substituted\nCyclopentadienes and Their Zirconocene Derivatites: Catalytic\nApplications in the Polymerization of Ethylene&#8220;<\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">40.<\/td><td style=\"vertical-align: top; border: none;\">T. Braun, D. Noveski, M.\nAhijado, F. Wehmeier, <i>Dalton\nTrans<\/i>. <b>2007<\/b>,\n5118-5132.<br><em><a>&#8222;Hydrodefluorination of\nPentafluoropyridine at Rhodium using\nDihydrogen: Detection of Unusual Rhodium Hydrido Complexes&#8220;<\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">39.<\/td><td style=\"vertical-align: top; border: none;\">T. Braun, F. Wehmeier,\nK. Altenh\u00f6ner, <i>Angew.\nChem.<\/i>. <b>2007<\/b>, <i>119<\/i>,\n5415-5418;&nbsp;<i>Angew.\nChem. Int. Ed.<\/i><b>\n200<span style=\"font-style: italic;\">7<\/span><\/b><i>,\n46<\/i>, 5321-5324.<br><em><a>&#8222;Catalytic C-F Bond Activation\nof Hexafluoropropene by\nRhodium:\nFormation of (3,3,3- Trifluoropropyl)silanes&#8220;<\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">38.<\/td><td style=\"vertical-align: top; border: none;\">L. Weber, G. Noveski, T.\nBraun, H.-G. Stammler, B.\nNeumann, <i>Eur. J. Inorg. Chem<\/i>. <b>2007<\/b>,\n562-567.<br><em><a>&#8222;Synthesis\nof the &nbsp;<\/i><i><font face=\"Symbol\">h<\/font><\/i><sup>2<\/sup><i>-1-Phosphaallen\nComplexes [(<\/i><i><font face=\"Symbol\">h<\/font><\/i><sup>5<\/sup><i>-C<sub>5<\/sub>H<sub>5<\/sub>)(CO)(NO)W{<\/i><i><font\nface=\"Symbol\">h<\/font><\/i><sup>2<\/sup><i>-R<sup>1<\/sup>P=C=C(<\/i><i>R<sup>2<\/sup><\/i><i>)H}]\n(<\/i><i>R<sup>1<\/sup><\/i><i>\n= tBu,\nCy;&nbsp;<\/i><i>R<sup>2<\/sup><\/i><i>\n= Ph,H) from [<\/i><i>(<\/i><i><font face=\"Symbol\">h<\/font><\/i><sup>5<\/sup><i>-C<sub>5<\/sub>H<sub>5<\/sub>)(CO)(NO)W=C=C(<\/i><i>R<sup>2<\/sup><\/i><i>)H}<\/i><i>]&nbsp;<\/i><i>(<\/i><i>R<sup>2<\/sup><\/i><i>\n= Ph,H)<\/i><i>\nand Inversely Polarized\nPhosphaalkenes&nbsp;<\/i><i>R<sup>1<\/sup><\/i><i>P=C(NMe<sub>2<\/sub>)<sub>2<\/sub>\n<\/i><i>(<\/i><i>R<sup>1<\/sup><\/i><i>\n= tBu, Cy),<\/i><i>\nand Their Structure&#8220;<\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">37.<\/td><td style=\"vertical-align: top; border: none;\">T. Braun, R. N. Perutz,\nComprehensive Organometallic\nChemistry III, Vol. 1, R. H. Crabtree, M. P. Mingos (Hrsg.), Elsevier,\nOxford <b>2007<\/b>,\n725-758.<br><em><a>&#8222;Transition-Metal\nMediated\nC-F Bond Activation&#8220;<\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">36.<\/td><td style=\"vertical-align: top; border: none;\">T. Braun, J. Izundu, A.\nSteffen, B. Neumann, H.-G.\nStammler, <i>Dalton Trans.<\/i> <b>2006<\/b>,\n5118-5132.<br><em><a>&#8222;Reactivity of a Palladium\nFluoro Complex Towards Silanes and\nBu<sub>3<\/sub>SnCH=CH<sub>2<\/sub>:\nCatalytic\nDerivatisation of Pentafluoropyridine Based on Carbon-Fluorine Bond\nActivation Reactions&#8220;<\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">35.<\/td><td style=\"vertical-align: top; border: none;\">T. Braun, V. Schorlemer,\nB.\nNeumann, H.-G. Stammler, <i>J.\nFluorine Chem.<\/i> <b>2006<\/b>, <i>127<\/i>,\n367-372.<br><em><a>&#8222;Palladium mediated activation\nof C-F bonds in\n2,4,6-trifluoropyrimidine: synthesis and structure of palladium\npyrimidyloxy and pyrimidinone derivatives&#8220;<\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">34.<\/td><td style=\"vertical-align: top; border: none;\">L. Weber, P. Bayer, T.\nBraun,\nH.-G. Stammler, B. Neumann, <i>Organometallics<\/i> <b>2006<\/b>, <i>25<\/i>,\n1786-1794.<br><em><a>&#8222;Arsaalkenes RAs=C(NMe<sub>2<\/sub>)<sub>2<\/sub>\n[R = PhC(O), 4-EtC<sub>6<\/sub>H<sub>4<\/sub>C(O),\n2,4,6-Me<sub>3<\/sub>C<sub>6<\/sub>H<sub>2<\/sub>C(O),\ntBuC(O), Me<sub>3<\/sub>Si]:\nVersatile Reagents in the\nChemistry of Heterocumulenes&#8220;<\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">33.<\/td><td style=\"vertical-align: top; border: none;\">L. Weber, I. Domke, C.\nSchmitd,\nT. Braun, H.-G. Stammler,\nB. Neumann, <i>Dalton Trans<\/i>. <b>2006<\/b>,\n2127-2132.<br><em><a>&#8222;Syntheses, Structures,\nLuminescence and Electrochemistry of\nBenzene- and Biphenyl-centered Bis- and Tris-1,3,2-diazaboroles and\n-1,3,2-diazaborolodines&#8220;<\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">32.<\/td><td style=\"vertical-align: top; border: none;\">L. Weber, P. Bayer, S.\nUthmann,\nT. Braun, H.-G. Stammler,\nB. Neumann, <i>Eur. J. Inorg. Chem<\/i>. <b>2006<\/b>,\n137-143.<br><em><a>&#8222;Reactivity of Inversely\nPolarized Arsaalkenes RAs=C(NMe<sub>2<\/sub>)<sub>2<\/sub>\n{R = [<\/i><i><font face=\"Symbol\">h<\/font><\/i><sup>5<\/sup><i>-C<sub>5<\/sub>Me<sub>5<\/sub>)(CO)<sub>2<\/sub>Fe],\ntBuC(O), 4-EtC<sub>6<\/sub>H<sub>4<\/sub>C(O)}\ntowards Phosphavinylidene Complexes [<\/i><i><font face=\"Symbol\">h<\/font><\/i><sup>5<\/sup><i>-(C<sub>5<\/sub>H<sub>5<\/sub>)(CO)<sub>2<\/sub>M=P=C(SiMe<sub>3<\/sub>)<sub>2<\/sub>]\n(M = Mo, W)&#8220;<\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">31.<\/td><td style=\"vertical-align: top; border: none;\">T. Braun, A. Steffen, V.\nSchorlemer, B. Neumann, H.-G.\nStammler, <i>Dalton Trans<\/i>. <b>2005<\/b>,\n3331-3336.<br><em><a>&#8222;Routes to Unique Palladium\nA-Frame Complexes with a Bridging\nFluoro-Ligand&#8220;<\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">30.<\/td><td style=\"vertical-align: top; border: none;\">M. Ahijado, T. Braun, D.\nNoveski, N. Kocher, B. Neumann, D.\nStalke, H.-G. Stammler, <i>Angew.\nChem.<\/i> <b>2005<\/b>, <span style=\"font-style: italic;\">117<\/span>,\n7107-7111; <i>Angew. Chem. Int. Ed<\/i>. <b>2005<\/b>, <i>44<\/i>,\n6947-6951.<br><em><a>&#8222;Rhodium- mediated Formation of\nPeroxides from Dioxygen:\nIsolation of Hydroperoxo, Silylperoxo and Methylperoxo Intermediates&#8220;<\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">29.<\/td><td style=\"vertical-align: top; border: none;\">T. Braun, <i>Angew.\nChem.<\/i> <b>2005<\/b>,\n117,\n5138-5140; <i>Angew.\nChem. Int. Ed<\/i>. <b>2005<\/b>, <i>44<\/i>,\n5012-5014.<br><em><a>&#8222;Oxidative Atdition of NH<sub>3<\/sub>\nto a\nTransition Metal: a Key-Step for the Metal-Mediated Derivatization of\nAmmonia?&#8220;<\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">28.<\/td><td style=\"vertical-align: top; border: none;\">T. Braun, A. Steffen, M.\nI.\nSladek, B. Neumann, H.-G.\nStammler, <i>Organometallics<\/i> <b>2005<\/b>, <i>23<\/i>,\n4057-4064.<br><em><a>&#8222;Catalytic C-C Coupling\nReactions at Ni by C-F Activation of a\nPyrimidine in the Presence of a C-Cl Bond: The Crucial Role of Highly\nReactive Fluoro Complexes&#8220;<\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">27.<\/td><td style=\"vertical-align: top; border: none;\">D. Noveski, T. Braun, B.\nNeumann, A. Stammler, H.-G.\nStammler, <i>Dalton Trans<\/i>. <b>2004<\/b>,\n4106-4119.<br><em><a>&#8222;C-F or C-H bond activation and\nC-C coupling reactions of\nfluorinated pyridines at rhodium: synthesis, structure and reactivity\nof a variety of tetrafluoropyridyl complexes&#8220;<\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">26.<\/td><td style=\"vertical-align: top; border: none;\">N. A. Jasim, R. N.\nPerutz, A.\nC. Whitwood, T. Braun, J.\nIzundu, B. Neumann, S. Rothfeld, H.-G. Stammler, <i>Organometallics<\/i>\n<b>2004<\/b>, <i>23<\/i>,\n6140-6149.<br><em><a>&#8222;Contrasting reactivity of\nfluoropyridines at palladium and\nplatinum: C-F oxidative atdition at palladium, alkyl transfer from\nphosphorus to platinum&#8220;<\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">25.<\/td><td style=\"vertical-align: top; border: none;\">D. Noveski, T. Braun, S.\nKr\u00fcckemeier, <i>J.\nFluorine Chem<\/i>. <b>2004<\/b>, <i>125<\/i>,\n959-966.<br><em><a>&#8222;Synthesis and Reactivity of\nRhodium Fluoro Complexes&#8220;<\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">24.<\/td><td style=\"vertical-align: top; border: none;\">D. Noveski, T. Braun,\nM.\nSchulte, B. Neumann, H.-G.\nStammler, <i>Dalton Trans<\/i>. <b>2003<\/b>,\n4075-4083.<br><em><a>&#8222;C-F activation and\nhydrodefluorination of fluorinated alkenes\nat rhodium&#8220;<\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">23.<\/td><td style=\"vertical-align: top; border: none;\">T. Braun, S. Rothfeld,\nV.\nSchorlemer, A. Stammler, H.-G.\nStammler, <i>Inorg. Chem. Commun<\/i>. <b>2003<\/b>, <i>6<\/i>,\n752-755.<br><em><a>&#8222;Palladium Mediated Activation\nof a C-F Bond in\nPentafluoropyridine: Synthesis, Structure and Reactivity of a\nPyridyloxy Complex&#8220;<\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">22.<\/td><td style=\"vertical-align: top; border: none;\">A. Bockholt, T. Braun,\nP.\nJutzi, B. Neumann, A. Stammler,\nH.-G. Stammler, <i>Organosilicon\nChemistry V<\/i>, (Hrsg.:\nN. Auner, J. Weis), Wiley-VCH <b>2003<\/b>,\nS. 50-54.<br><em><a>&#8222;New Donor-Stabilized\nOrganosilicon Cations: Synthesis,\nStructure and Reactivity&#8220;<\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">21.<\/td><td style=\"vertical-align: top; border: none;\">T. Braun, M. I. Sladek,\nB.\nNeumann, H.-G. Stammler, <i>New.\nJ. Chem<\/i>. <b>2003<\/b>, <i>27<\/i>,\n313-318. <br><em><a>3-Fluoropyridyl Nickel\nComplexes as Useful Tools for the\nSelective Synthesis of New 2,4,5,6-Tetrafluoropyridines: A Route\nComplementing the Established Methods to Access Fluorinated Pyridines&#8220;<\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">20.<\/td><td style=\"vertical-align: top; border: none;\">T. Braun, R. N. Perutz, <i>Perspectives\nin\nOrganometallic Chemistry<\/i>,\n(Hrsg.: C. G. Screttas, B. R.\nSteele), RSC <b>2003<\/b>,\nS. 136-151.<br><em><a>&#8222;Routes to Fluorinated Organic\nDerivatives by Nickel Mediated\nC-F Activation of Heteroaromatics&#8220;<\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">19.<\/td><td style=\"vertical-align: top; border: none;\">T. Braun, G.\nM\u00fcnch, B.\nWindm\u00fcller, O.\nGevert, M. Laubender, H. Werner, <i>Chem.\nEur. J.<\/i> <b>2003<\/b>, <i>9<\/i>,\n2516-2530. <br><em><a>&#8222;Synthesis, Molecular\nStructure, and C-C Coupling Reactions of\nCarbeneruthenium(II) Complexes with C<sub>5<\/sub>H<sub>5<\/sub>Ru(=CRR&#8216;)\nand C<sub>5<\/sub>Me<sub>5<\/sub>Ru(=CRR&#8216;)\nas\nMolecular Units&#8220;<\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">18.<\/td><td style=\"vertical-align: top; border: none;\">T. Braun, D. Noveski, B.\nNeumann, H.-G. Stammler,<i> Angew.\nChem.<\/i> <b>2002<\/b>, <i>114<\/i>,\n2870-2873; <i>Angew.\nChem. Int. Ed<\/i>. <b>2002<\/b>, <i>41<\/i>,\n2745-2747. <br><em><a>&#8222;Conversion of\nHexafluoropropene into 1,1,1-Trifluoropropane\nby C-F Activation at Rhodium&#8220;<\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">17.<\/td><td style=\"vertical-align: top; border: none;\">T. Braun, B.\nBl\u00f6cker,\nV. Schorlemer, B. Neumann,\nA. Stammler, H.-G. Stammler, <i>J.\nChem. Soc., Dalton Trans<\/i>. <b>2002<\/b>,\n2213-2218.<br><em><a>&#8222;Synthesis, Structure and\nReactivity of Fluorovinyl Nickel\nComplexes: Formation of a Phosphonioethenyl Complex&#8220;<\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">16.<\/td><td style=\"vertical-align: top; border: none;\">M. I. Sladek, T. Braun,\nB.\nNeumann, H.-G-Stammler, <i>J.\nChem. Soc., Dalton Trans<\/i>. <b>2002<\/b>,\n297-299.<br><em><a>&#8222;Aromatic C-F Activation at Ni\nin the Presence of a Carbon\nChlorine Bond: The Nickel Mediated Synthesis of new Pyrimidines&#8220;<\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">15.<\/td><td style=\"vertical-align: top; border: none;\">T. Braun, R. N. Perutz, <i>Chem.\nCommun<\/i>. <b>2002<\/b>,\n2749-2757.<br><em><a>&#8222;Routes to Fluorinated Organic\nDerivatives by Nickel Mediated\nC-F Activation of Heteroaromatics&#8220;<\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">14.<\/td><td style=\"vertical-align: top; border: none;\">I. Atheaux, F. Delpech,\nB.\nDonnadieu, S. Sabo-Etienne, B.\nChaudret, K. Hussein, J.-C. Barthelat, T. Braun, S. B. Duckett, R. N.\nPerutz, <i>Organometallics<\/i> <b>2002<\/b>,\n5347-5357.<br><em><a>&#8222;Exchange Processes in\nComplexes with Two Ruthenium (<\/i><i><font face=\"Symbol\">h<\/font><\/i><sup>2<\/sup><i>-silane)\nLinkages: Role of the Secondary Interactions between Silicon and\nHydrogen Atoms&#8220;<\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">13.<\/td><td style=\"vertical-align: top; border: none;\">T. Braun, R.N. Perutz,\nM. I.\nSladek, <i>Chem. Commun<\/i>. <b>2001<\/b>,\n2254-2255.<br><em><a>&#8222;Catalytic C-F Activation of\nPolyfluorinated Pyridines by\nNickel-Mediated Cross-Coupling Reactions&#8220;<\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">12.<\/td><td style=\"vertical-align: top; border: none;\">T. Braun, L. Cronin, C.\nL.\nHiggitt, J. E. McGrady, R. N.\nPerutz, M. Reinhold, <i>New. J.\nChem<\/i>. <b>2001<\/b>, <i>25<\/i>,\n19-21.<br><em><a>&#8222;Coordination and oxidative\natdition of octafluoronaphthalene\nat a nickel-centre: isolation of an intermediate in C-F bond activation&#8220;<\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">11.<\/td><td style=\"vertical-align: top; border: none;\">T.\nBraun, S. J. Archibald, J.\nA. Gaunt, J. E. Hobson, R. N.\nPerutz, <i>J. Chem. Soc., Dalton\nTrans<\/i>. <b>2000<\/b>,\n2013-1018.<br><em><a>&#8222;Chemistry of Nickel\nTetrafluoropyridyl Derivatives: Synthesis\nand Structure of a Binuclear Complex With Bridging Pyridyl Ligands&#8220;<\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">10.<\/td><td style=\"vertical-align: top; border: none;\">T. Braun, S. P. Foxon,\nR. N.\nPerutz, P. H. Walton, <i>Angew.\nChem<\/i>. <b>1999<\/b>, <i>111<\/i>,\n3543-3545; <i>Angew.\nChem<\/i>. Int. Ed. <b>1999<\/b>, <span style=\"font-style: italic;\">38<\/span>,\n3326-3329.<br><em><a>&#8222;Nickel-Assisted\nCarbon-Fluorine Bond Activation of\n2,4,6-Trifluoropyrimidine: The Synthesis of New Pyrimidine and\nPyrimidinone Derivatives&#8220;<\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">9.<\/td><td style=\"vertical-align: top; border: none;\">T. Braun, S. Parsons, R.\nN.\nPerutz, M.Voith, <i>Organometallics<\/i> <b>1999<\/b>, <i>18<\/i>,\n1710-1716.<br><em><a>&#8222;Reactivity of a Nickelfluoride\nComplex: Preparation of new\nTetrafluoropyridyl Derivatives&#8220;<\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">8.<\/td><td style=\"vertical-align: top; border: none;\">H. Werner, T. Braun, T.\nDaniel,\nO. Gevert, M. Schulz, <i>J.\nOrganomet. Chem<\/i>. <b>1997<\/b>, <i>541<\/i>,\n127-141.<br><em><a>&#8222;Cyclopentadienyl- und\nPentamethylcyclopentadienyl-Rutheniumkomplexe mit Carboxylat-,\nVinylester- und Carben-Liganden&#8220;<\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">7.<\/td><td style=\"vertical-align: top; border: none;\">T. Braun, M. Laubender,\nO.\nGevert, H. Werner, <i>Chem.\nBer.\/Recl<\/i>. <b>1997<\/b>, <i>130<\/i>,\n559-564.<br><em><a>&#8222;Halfsandwich-Type\nTriisopropylstibane Ruthenium Compounds\nwith 16-, 17- and 18-Electron Configurations and an Unsymmetrical\nBinuclear 18\/16-Electron Ru<sub>2<\/sub>(SbiPr<sub>3<\/sub>)\nSpecies&#8220;<\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">6.<\/td><td style=\"vertical-align: top; border: none;\">P. LeGendre, T. Braun,\nC.\nBruneau, P. H. Dixneuf, <i>J.\nOrg. Chem<\/i>. <b>1996<\/b>, <i>61<\/i>,\n8453-8456.<br><em><a>&#8222;Preparation of Optically\nActive Cyclic Carbonates and\n1,2-Diols via Enantioselective Hydrogenation of <font face=\"Symbol\">a<\/font>-Methylenedioxolanones\nCatalyzed by Chiral Ruthenium (II) Complexes&#8220;<\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">5.<\/td><td style=\"vertical-align: top; border: none;\">T. Braun, P. Meuer, H.\nWerner, <i>Organometallics<\/i> <b>1996<\/b>, <i>15<\/i>,\n4075-4077.<br><em><a>&#8222;<font face=\"Symbol\">h<\/font><\/i><sup>3<\/sup><i>-2.3.4-Butadienyl\nand&nbsp;<\/i><i><font face=\"Symbol\">h<\/font><\/i><sup>3<\/sup><i>-3.4.5-Pentatrienyl\nRuthenium Complexes From Vinylidene and Allenylidene Precursors&#8220;<\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">4.<\/td><td style=\"vertical-align: top; border: none;\">T. Braun, O. Gevert, H.\nWerner, <i>J. Am.\nChem.\nSoc<\/i>. <b>1995<\/b>, <i>117<\/i>,\n7291-7292.<br><em><a>&#8222;A Ruthenium-Mediated [C<sub>1<\/sub>\n+ C<sub>2<\/sub>]\nCoupling Reaction: Formation of <font face=\"Symbol\">\u03c0<\/font>-Allyl\nComplexes from Carbenemetal\nPrecursors&#8220;<\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">3.<\/td><td style=\"vertical-align: top; border: none;\">T. Braun, P. Steinert,\nH.\nWerner, <i>J. Organomet.\nChem<\/i>. <b>1995<\/b>, <i>488<\/i>,\n169-176.<br><em><a>&#8222;Vinylidene transition metal\ncomplexes XXXIV:\nThe preparation and structure of neutral vinylidene and allenylidene\nruthenium(II) compounds of the half-sandwich type containing <sup>i<\/sup>Pr<sub>2<\/sub>PCH<sub>2<\/sub>CO<sub>2<\/sub>Me\nas supporting ligand&#8220;<\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">2.<\/td><td style=\"vertical-align: top; border: none;\">H. Werner, T. Daniel, T.\nBraun,\nO. N\u00fcrnberg, <i>J.\nOrganomet. Chem<\/i>. <b>1994<\/b>, <i>480<\/i>,\n145-153.<br><em><a>&#8222;Five-membered OsC<sub>3<\/sub>N\nheterocycles from\nosmium azavinylidenes as precursors&#8220;<\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n\n\n\n<figure class=\"wp-block-table\"><table><tbody><tr><td style=\"vertical-align: top; border: none;\" width=\"2%;\">1.<\/td><td style=\"vertical-align: top; border: none;\">T. Daniel, N. Mahr, T.\nBraun,\nH. Werner, <i>Organometallics<\/i> <b>1993<\/b>, <i>12<\/i>,\n1475-1477.<br><em><a>&#8222;Insertion of a Vinylidene Unit\ninto a Ru-O Bond: Synthesis\nand Molecular Structure of [C<sub>5<\/sub>H<sub>5<\/sub>(PPh<sub>3<\/sub>)Ru{<font face=\"Symbol\">k<\/font><sup>2<\/sup>(C,O)-C(=CHCO<sub>2<\/sub>Me)OC(CH<sub>3<\/sub>)=O}]&#8220;<\/a><\/em><\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-css-opacity is-style-wide\"\/>\n","protected":false},"excerpt":{"rendered":"<p>Publications 195. S. Mollasalehi, J. Borel, T. Braun, Eur. J. Inorg. Chem. 2025, 29, e202500509.<\/p>\n","protected":false},"author":2,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":{"neve_meta_sidebar":"full-width","neve_meta_container":"","neve_meta_enable_content_width":"on","neve_meta_content_width":100,"neve_meta_title_alignment":"","neve_meta_author_avatar":"","neve_post_elements_order":"","neve_meta_disable_header":"","neve_meta_disable_footer":"","neve_meta_disable_title":"on","footnotes":""},"class_list":["post-10","page","type-page","status-publish","hentry"],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v27.3 - https:\/\/yoast.com\/product\/yoast-seo-wordpress\/ -->\n<title>Publications - Prof. Dr. Thomas Braun - Humboldt Universit\u00e4t zu Berlin<\/title>\n<meta name=\"description\" content=\"Publications of Prof. Dr. Thomas Braun.\" \/>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"https:\/\/www2.hu-berlin.de\/chemie\/braun\/publikationen\/\" \/>\n<meta property=\"og:locale\" content=\"de_DE\" \/>\n<meta property=\"og:type\" content=\"article\" \/>\n<meta property=\"og:title\" content=\"Publications - 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