Publications:

[2024] [2023] [2022] [2021] [2020] [2019] [2018] [2017] [2016] [2015] [2014] [2013] [2012] [2011] [2010] [2009] [2008] [2007] [2006] [2005] [2004] [2003] [2002] [2001] [2000] [1999] [1998] [1997] [1996] [1995] [1994] [1993] [1992] [1991]
  1. "ATP-Triggered Fe(CN)2CO Synthon Transfer from the Maturase HypCD to the Active Site of Apo-[NiFe]-Hydrogenase"
    A. Kwiatkowski, G. Caserta, A.-C. Schulz, S. Frielingsdorf, V. Pelmenschikov, K. Weisser, A. Belsom, J. Rappsilber, I. Sergueev, C. Limberg, M.-A. Mroginski, I. Zebger, O. Lenz,
    J. Am. Chem. Soc. 2024. DOI: 10.1021/jacs.4c09791 [abstract]

  2. "Trispyrazolyl Borate Iron Thiolate Complexes and the Dependence of their O2-Reactivity on the Reaction Space"
    K. Weißer, B. Cula, C. Limberg,
    Eur. J. Inorg. Chem. 2024, 27, e202400352. [abstract]

  3. "Divergent Interaction of (Iso)nitriles with a Linear Iron(I) Silylamide─A Combined Structural, Spectroscopic, and Computational Study"
    C. G. Werncke, I. Müller, K. Weißer, C. Limberg,
    Inorg. Chem. 2024, 63, 15236-15246. [abstract]

  4. "What determines the Lewis acidity of a bismuthane? Towards Bi-based FLPs"
    C. U. Hartmann, M. Reimann, B. Cula, M. Kaupp, C. Limberg,
    Chem. Eur. J. 2024, 30, e202402154. [abstract]

  5. "Appropriation of group II metals: synthesis and characterisation of the first alkaline earth metal supported transition metal carbonite complexes"
    S. Wolff, A. Ponsonby, A. Dallmann, C. Herwig, F. Beckmann, B. Cula, C. Limberg
    Chem. Commun. 2024, 60, 5816-5819. [abstract]

  6. "Questing for Homoleptic Mononuclear Manganese Complexes with Monodentate O-Donor Ligands"
    A. Pérez-Bitrián, J. Munárriz, K. B. Krause, J. Schlögl, K. F. Hoffmann, J. S. Sturm, A. N. Hadi, C. Teutloff, A. Wiesner, C. Limberg, S. Riedel,
    Chem. Sci. 2024, 15, 5564-5572. [abstract]

  7. "Stabilizing Monoatomic Two-Coordinate Bismuth(I) and Bismuth(II) Using a Redox Noninnocent Bis(germylene) Ligand"
    J. Xu, S. Pan, S. Yao, C. Lorent, C. Teutloff, Z. Zhang, J. Fan, A. Molino, K. B. Krause, J. Schmidt, R. Bittl, C. Limberg, L. Zhao, G. Frenking, M. Driess,
    J. Am. Chem. Soc. 2024, 146, 6025-6036. [abstract]

  8. "Controlling the Activation at NiII-CO22- Moieties through Lewis Acid Interactions in the Second Coordination Sphere"
    S. Wolff, V. Pelmenschikov, R. Müller, M. Ertegi, B. Cula, M. Kaupp, C. Limberg,
    Chem. Eur. J. 2024, 30, e202303112. [abstract]

  9. "Two Allogons of an O2-activating Bis(disiloxido)ferrate(II) Accessible Selectively just by Variation of the Crystallization Temperature"
    F. Beckmann, P. Woite, S. Yelin, D. Kass, D. Usvyat, M. Roemelt, C. Limberg,
    Chem. Eur. J. 2024, 30, e202303614. [abstract]

  10. "A Doubly Reduced Dipalladium Dibenzylideneacetone Complex"
    S. Paul, T. Lohmiller, J. Barrera, C. Herwig, B. Cula, A. Quensel, C. Limberg,
    Organometallics 2023, 42, 3434-3437. [abstract]

  11. "NMR spectroscopic investigations on the successive implementation of nickel and zinc ions to a NacNac-dibenzofuran-Br ligand precursor"
    K. B. Krause, B. Cula, A. Dallmann, C. Limberg,
    Z. Anorg. Allg. Chem. 2023, 649, e202300178. [abstract]

  12. "Further Perspectives on the Teflate versus Fluoride Analogy: The Case of a Co(II) Pentafluoroorthotellurate Complex"
    A. Pérez-Bitrián, J. Munárriz, J. S. Sturm, D. Wegener, K. B. Krause, A. Wiesner, C. Limberg, S. Riedel,
    Inorg. Chem. 2023, 62, 12947-12953. [abstract]

  13. "A class of non-aromatic 1,3-disilapyrroles acting as stable organosilicon-based triplet diradicals"
    Y. Xiong, S. Dong, S. Yao, C. Lorent, K. B. Krause, G. Vijaykumar, J. Zhu, C. Limberg, M. Driess,
    Nat. Synth. 2023, 2, 678-687. [abstract]

  14. "Cationic Tetrylene-Iron(0) Complexes: Access Points for Cooperative, Reversible Bond Activation and Open-Shell Iron(-I) Ferrato-Tetrylenes"
    P. M. Keil, A. Soyemi, K. Weisser, T. Szilvási, C. Limberg, T. J. Hadlington,
    Angew. Chem. 2023, 135, e202218141. [abstract]
    Angew. Chem. Int. Ed. 2023, 62, e202218141. [abstract]

  15. "Spectroscopic Properties of a Biologically Relevant [Fe2(μ-O)2] Diamond Core Motif with a Short Iron-Iron distance"
    D. Kass, S. Yao, K. B. Krause, T. Corona, L. Richter, T. Braun, S. Mebs, M. Haumann, H. Dau, T. Lohmiller, C. Limberg, M. Drieß, K. Ray,
    Angew. Chem. 2023, 135, e202209437. [abstract]
    Angew. Chem. Int. Ed. 2023, 62, e202209437. [abstract]

  16. "Stepwise assembly of the active site of [NiFe]-hydrogenase"
    G. Caserta, S. Hartmann, C. van Stappen, C. Karafoulidi-Retsou, C. Lorent, S. Yelin, M. Keck, J. Schoknecht, I. Sergueev, Y. Yoda, P. Hildebrandt, C. Limberg, S. DeBeer, I. Zebger, S. Frielingsdorf, O. Lenz,
    Nat. Chem. Biol. 2023, 19, 498-506. [abstract]

  17. "A Strained Intramolecular P/Al-FLP and its Reactivity toward Allene"
    P. Federmann, T. Bosse, S. Wolff, B. Braun-Cula, C. Herwig, C. Limberg,
    Chem. Commun. 2022, 58, 13451-13454. [abstract]

  18. "Unravelling the Role of the Pentafluoroorthotellurate Group as a Ligand in Nickel Chemistry"
    A. Pérez-Bitrián, K. F. Hoffmann, K. B. Krause, G. Thiele, C. Limberg, S. Hasenstab-Riedel,
    Chem. Eur. J. 2022, 28, e202202016. [abstract]

  19. "Low-coordinated iron(II) siloxide complexes - structural diversity and reactivity towards O2 and oxygen atom transfer reagents"
    S. Yelin, B. Cula, C. Limberg,
    Eur. J. Inorg. Chem. 2022, 14, e202200078. [abstract]

  20. "Synthesis of Intramolecular P/Al-based FLPs via Aluminium-Tin-Exchange and their Reactivity toward CO2"
    P. Federmann, R. Müller, F. Beckmann, C. Lau, B. Cula, M. Kaupp, C. Limberg,
    Chem. Eur. J. 2022, 28, e202200404. [abstract]

  21. "Ring-Opening of THF via an Intramolecular P/Al-based Frustrated Lewis Pair - Assistance by C6F5 Groups beyond Electronegativity?"
    P. Federmann, C. Herwig, F. Beckmann, B. Cula, C. Limberg,
    Organometallics 2021, 40, 4143-4149. [abstract]

  22. "Cobalt and Iron Stabilized Ketyl, Ketiminyl and Aldiminyl Radical Anions"
    G. Sieg, Q. Pessemesse, S. Reith, S. Yelin, C. Limberg, D. Munz, C. G. Werncke,
    Chem. Eur. J. 2021, 27, 16760-16767. [abstract]

  23. "Acidity of Al-O(H)-Al Sites in Molecular Aluminosilicate Models Enables Alcohol Dehydration Reactions"
    F. Beckmann, K. S. Lokare, L. Lätsch, C. Copéret, C. Limberg,
    J. Phys. Chem. C 2021, 125, 17690-17695. [abstract]

  24. "Stabilizing P≡P: P22-, P2·-, and P20 as bridging ligands"
    J. Sun, H. Verplancke, J. I. Schweizer, M. Diefenbach, C. Würtele, M. Otte, I. Tkach, C. Herwig, C. Limberg, S. Demeshko, M. C. Holthausen, S. Schneider,
    Chem 2021, 7, 1952-1962. [abstract]

  25. "Mimicking of the histidine brace structural motif in molecular copper(I) compounds"
    R. Peifer, L. Müller, S. Hoof, F. Beckmann, B. Cula, C. Limberg,
    Z. Anorg. Allg. Chem. 2021, 647, 1789-1796. [abstract]

  26. "Cyanate Formation via Photolytic Splitting of Dinitrogen"
    B. Schluschaß, J.-H. Borter, S. Rupp, S. Demeshko, C. Herwig, C. Limberg, N. Maciulis, J. Schneider, C. Würtele, V. Krewald, D. Schwarzer, S. Schneider,
    JACS Au 2021, 1, 879-894. [abstract]

  27. "Binding of a TlCl entity by a tetragold tetramercaptothiacalixarene metalloligand via metallophilic interactions"
    N. Frank, I. Pryjomska-Ray, L. Grubert, D. Usvyat, S. Hecht, C. Limberg,
    Chem. Eur. J. 2021, 27, 8344-8349. [abstract]

  28. "Transformation of Formazanate at Nickel(II) Centers to Give a Singly Reduced Nickel Complex with Azoiminate Radical Ligands and Its Reactivity toward Dioxygen"
    D. Ar, A. F. R. Kilpatrick, B. Cula, C. Herwig, C. Limberg,
    Inorg. Chem. 2021, 60, 13844-13853. [abstract]

  29. "High‐spin square planar iron(II) alkali metal siloxide complexes – influence of the alkali metal and reactivity towards O2 and NO"
    F. Beckmann, D. Kass, M. Keck, S. Yelin, S. Hoof, B. Cula, C. Herwig, K. B. Krause, D. Ar, C. Limberg,
    Z. Anorg. Allg. Chem. 2021, 647, 960-967. [abstract]

  30. "Iron(III)‐tCDTA derivatives as MRI contrast agents: Increased T1 relaxivities at higher magnetic field strength and pH sensing"
    J. Xie, A. Haeckel, R. Hauptmann, I. Pryjomska Ray, C. Limberg, N. Kulak, B. Hamm, E. Schellenberger,
    Magn. Reson. Med. 2021, 85, 3370-3382. [abstract]

  31. "The Properties of Hydrotris(3‐mesitylpyrazol‐1‐yl) Borate Iron(II) Complexes with Aryl Carboxylate Co‐ligands – Stabilization of an Iron(III) Alkylperoxide"
    L. Müller, K. Baturin, S. Hoof, C. Lau, C. Herwig, C. Limberg,
    Z. Anorg. Allg. Chem. 2021, 647, 385-395. [abstract]

  32. "Electron transfer within β-diketiminato nickel bromide and cobaltocene redox couples activating CO2"
    P. Zimmermann, A. F. R. Kilpatrick, D. Ar, S. Demeshko, B. Cula, C. Limberg
    Chem. Commun. 2021, 57, 875-878. [abstract]

  33. "Versatile Coordination Behaviour of the Asymmetric Bis(3-mesityl-pyrazol-1-yl)(5-mesitylpyrazol-1-yl) Hydroborate Ligand towards Late 3d M2+ Ions"
    L. Müller, V. Nadurata, B. Cula, S. Hoof, C. Herwig, C. Limberg,
    Eur. J. Inorg. Chem. 2021, 2021, 71-85. [abstract]

  34. "Selective transformation of Nickel-bound formate to CO or C-C coupling products triggered by deprotonation and steered by alkali metal ions"
    P. Zimmermann, D. Ar, M. Rößler, P. Holze, B. Braun, C. Herwig, C. Limberg,
    Angew. Chem. 2021, 133, 2342-2351. [abstract]
    Angew. Chem. Int. Ed. 2021, 60, 2312-2321. [abstract]

  35. "Examination of Protonation-Induced Dinitrogen Splitting by in situ EXAFS Spectroscopy"
    J. Abbenseth, J.-P. Oudsen, B. Venderbosch, S. Demeshko, M. Finger, C. Herwig, C. Würtele, M. Holthausen, C. Limberg, M. Tromp, S. Schneider,
    Inorg. Chem. 2020, 59, 14367-14375. [abstract]

  36. "Hydroxo-Bridged Active Site of Flavodiiron NO Reductase Revealed by Spectroscopy and Computations"
    F. Folgosa, V. Pelmenschikov, M. Keck, C. Lorent, Y. Yoda, J. A. Birrell, M. Kaupp, M. Teixeira, K. Tamasaku, C. Limberg, L. Lauterbach,
    ChemRxiv 2020. DOI: 10.26434/chemrxiv.12928331.v1 [abstract]

  37. "Enhancing tris(pyrazolyl)borate-based models of cysteine/cysteamine dioxygenases via the sterics – increased reactivities, full product characterization and hints to initial superoxide formation"
    L. Müller, S. Hoof, M. Keck, C. Herwig, C. Limberg,
    Chem. Eur. J. 2020, 26, 11851-11861. [abstract]

  38. "The Coordination Behavior of Oxygen-depleted Calixarenes towards d10 Noble Metal Ions"
    M. Keck, S. Hoof, V. Rawat, A. Vigalok, C. Limberg,
    Z. Anorg. Allg. Chem. 2020, 646, 904-908. [abstract]

  39. "The large subunit of the regulatory [NiFe]-hydrogenase from Ralstonia eutropha – A minimal hydrogenase?"
    G. Caserta, C. Lorent, A. Ciaccafava, M. Keck, R. Breglia, C. Greco, C. Limberg, P. Hildebrandt, S. P. Cramer, I. Zebger, O. Lenz,
    Chem. Sci. 2020, 11, 5453-5465. [abstract]

  40. "Routes to Heterotrinuclear Metal Siloxide Complexes for Cooperative Activation of O2"
    M.-L. Wind, S. Hoof, B. Braun-Cula, C. Herwig, C. Limberg,
    Inorg. Chem. 2020, 59, 6866-6875. [abstract]

  41. "Mercaptothiacalixarenes steer 24 copper(I) centers to form a hollow-sphere structure featuring Cu2S2 motifs with exceptionally short Cu···Cu distances"
    N. Frank, A. Dallmann, B. Braun-Cula, C. Herwig, C. Limberg,
    Angew. Chem. 2020, 132, 6801-6805. [abstract]
    Angew. Chem. Int. Ed. 2020, 59, 6735-6739. [abstract]

  42. "A Polysiloxide Complex with two Chromium(III) η2-Superoxo Moieties"
    M.-L. Wind, B. Braun-Cula, F. Schax, C. Herwig, C. Limberg,
    Isr. J. Chem. 2020, 60, 1057-1060. [abstract]

  43. "Molecular Structural Motifs and O2 Activation Inspired by Enzymes and Solid Catalysts"
    S. Yelin, C. Limberg,
    Catal. Lett. 2020, 150, 1-11. [abstract]

  44. "Switching from a chromium(IV) peroxide to a chromium(III) superoxide upon coordination of a donor in the trans position"
    M.-L. Wind, S. Hoof, B. Braun-Cula, C. Herwig, C. Limberg,
    J. Am. Chem. Soc. 2019, 141, 14068-14072. [abstract]

  45. "Investigation of cubic Fe4M4 frameworks for application in nonaqueous energy storage"
    L. E. VanGelder, E. Schreiber, M.-L. Wind, C. Limberg, E. M. Matson,
    Chem. Eur. J. 2019, 25, 14421-14429. [abstract]

  46. "The Behavior of Trispyrazolylborato-Metal(II)-Flavonolate Complexes as Functional Models for Bacterial Quercetinase Assessment of the Metal Impact"
    S. Hoof, C. Limberg,
    Inorg. Chem. 2019, 58, 12843-12853. [abstract]

  47. "Selectivity of Tungsten Mediated Dinitrogen Splitting vs. Proton Reduction"
    B. Schluschaß, J. Abbenseth, S. Demeshko, M. Finger, A. Franke, C. Herwig, C. Würtele, I. Ivanović-Burmazović, C. Limberg, J. Telser, S. Schneider,
    Chem. Sci. 2019, 10, 10275-10282. [abstract]

  48. "Oxygen-depleted Calixarenes as Ligands for Molecular Models of Galactose Oxidase"
    M. Keck, S. Hoof, C. Herwig, A. Vigalok, C. Limberg,
    Chem. Eur. J. 2019, 25, 13285-13289. [abstract]

  49. "The influence of alkali metal ions on the stability and reactivity of chromium(III) superoxide moieties spanned by siloxide ligands"
    M.-L. Wind, S. Hoof, C. Herwig, B. Braun-Cula, C. Limberg,
    Chem. Eur. J. 2019, 25, 5743-5750. [abstract]

  50. "Bioinspired Trispyrazolylborato Nickel(II) Flavonolate Complexes and Their Reactivity Toward Dioxygen"
    S. Hoof, C. Limberg,
    Z. Anorg. Allg. Chem. 2019, 645, 170-174. [abstract]

  51. "Structure and Reactivity of Al–O(H)–Al Moieties in Siloxide Frameworks – Solution and Gas-phase Model Studies"
    K. S. Lokare, B. Braun-Cula, C. Limberg, M. Jorewitz, J. T. Kelly, K. R. Asmis, S. Leach, C. Baldauf, I. Goikoetxea, J. Sauer,
    Angew. Chem. 2019, 131, 912-917. [abstract]
    Angew. Chem. Int. Ed. 2019, 58, 902-906. [abstract]

  52. "Specific decoration of a discrete bismuth oxido cluster by selected peptides toward the design of metal tags"
    M. Bauer, D. Remmler, A. Dallmann, N. Jakubowski, H. G. Börner, U. Panne, C. Limberg,
    Chem. Eur. J. 2019, 25, 759-763. [abstract]

  53. "Stabilization of β-Diketiminato Nickel(I) with Alkaline Metal Halide Entities for Small Molecule Activation"
    P. Holze, B. Braun-Cula, S. Mebs, C. Limberg,
    Z. Anorg. Allg. Chem. 2018, 644, 973-981. [abstract]

  54. "Extending the Toolbox for the Modular Arrangement of Functions at Xanthene/Dibenzofuran Platforms: Introduction of Directly Linked Transition Metals beside Bismuthanes"
    K. Materne, C. Spröwitz, B. Braun-Cula, C. Limberg,
    Z. Anorg. Allg. Chem. 2018, 644, 700-705. [abstract]

  55. "A Biomimetic Nickel Complex with a Reduced CO2 Ligand Generated by Formate Deprotonation and its Behaviour towards CO2"
    P. Zimmermann, S. Hoof, B. Braun-Cula, C. Herwig, C. Limberg,
    Angew. Chem. 2018, 130, 7349-7353. [abstract]
    Angew. Chem. Int. Ed. 2018, 57, 7230-7233. [abstract]

  56. "Comparing Isomeric Tridentate Carbazole-Based Click Ligands: Metal Complexes and Redox Chemistry"
    I. Pryjomska-Ray, D. Zornik, M. Pätzel, K. B. Krause, L. Grubert, B. Braun-Cula, S. Hecht, C. Limberg,
    Chem. Eur. J. 2018, 24, 5341-5349. [abstract]

  57. "Copper(I) complexes based on ligand systems with two different binding sites: synthesis, structures and reaction with O2"
    S. T. Li, B. Braun-Cula, S. Hoof, C. Limberg,
    Dalton Trans. 2018, 47, 544-560. [abstract]

  58. "In Situ Formation of PBiP Ligands upon Complexation of a Mixed Phosphane/Bismuthane with Group 11 Metal Ions"
    K. Materne, S. Hoof, N. Frank, C. Herwig, C. Limberg,
    Organometallics 2017, 36, 4891-4895. [abstract]

  59. "O2 activation at a trispyrazolylborato nickel(II) malonato complex"
    S. Hoof, M. Sallmann, C. Herwig, B. Braun-Cula, C. Limberg,
    Dalton Trans. 2017, 46, 16792-16795. [abstract]

  60. "Mimicking Base Interaction with Acidic Sites [Si–O(H)–Al] of Zeolites in Molecular Models"
    K. S. Lokare, P. Wittwer, B. Braun-Cula, N. Frank, S. Hoof, T. Braun, C. Limberg,
    Z. Anorg. Allg. Chem. 2017, 643, 1581-1588. [abstract]

  61. "Bis(silylenyl)-substituted ferrocene-stabilized η6-arene iron(0) complexes: synthesis, structure and catalytic application"
    M.-P. Luecke, D. Porwal, A. Kostenko, Y.-P. Zhou, S. Yao, M. Keck, C. Limberg, M. Oestreich, M. Driess,
    Dalton Trans. 2017, 46, 16412-16418. [abstract]

  62. "Bismuthanes as Hemilabile Donors in an O2-Activating Palladium(0) Complex"
    K. Materne, B. Braun-Cula, C. Herwig, N. Frank, C. Limberg,
    Chem. Eur. J. 2017, 23, 11797-11801. [abstract]

  63. "A Hexanuclear Iron(II) Layer with Two Square-Planar FeO4 Units Spanned by Tetrasiloxide Ligands: Mimicking of Minerals and Catalysts"
    N. Manicke, S. Hoof, M. Keck, B. Braun-Cula, M. Feist, C. Limberg,
    Inorg. Chem. 2017, 56, 8554-8561. [abstract]

  64. "A high-spin square planar iron(II)-siloxide and its tetrahedral allogon - structural and spectroscopic models of Fe-zeolite sites"
    D. Pinkert, M. Keck, S. Ghassemi Tabrizi, C. Herwig, F. Beckmann, B. Braun-Cula, M. Kaupp, C. Limberg,
    Chem. Commun. 2017, 53, 8081-8084. [abstract]

  65. "Atomic Layer Deposition of Silica on Carbon Nanotubes"
    M. Karg, K. S. Lokare, C. Limberg, G. Clavel, N. Pinna,
    Chem. Mater. 2017, 29, 4920-4931. [abstract]

  66. "Activation of Small Molecules at Nickel(I) Moieties"
    P. Zimmermann, C. Limberg,
    J. Am. Chem. Soc. 2017, 139, 4233-4242. [abstract]

  67. "Activation of Dioxygen at a Lewis Acidic Nickel(II) Complex - Characterization of a Metastable Organoperoxide complex"
    P. Holze, T. Corona, N. Frank, B. Braun-Cula, C. Herwig, A. Company, C. Limberg,
    Angew. Chem. 2017, 129, 2347-2351. [abstract]
    Angew. Chem. Int. Ed. 2017, 56, 2307-2311. [abstract]

  68. "Creating Iron- and Rhenium-Bismuth bonds by Reactions with Organometallic Hydrides"
    R. Schiwon, B. Braun, R. Metzinger, C. Limberg,
    Z. Anorg. Allg. Chem. 2016, 642, 1198-1206. [abstract]

  69. "Ligands with Two Different Binding Sites and O2 Reactivity of their Copper(I) Complexes"
    S. T. Li, B. Braun-Cula, S. Hoof, M. Dürr, I. Ivanović-Burmazović, C. Limberg,
    Eur. J. Inorg. Chem. 2016, 25, 4017-4027. [abstract]

  70. "Cyclohexane oxidative dehydrogenation over copper oxide catalysts"
    S. L. Nauert, F. Schax, C. Limberg, J. M. Notestein,
    J. Catal. 2016, 341, 180-190. [abstract]

  71. "Trapping Aluminium Hydroxide Clusters from Speciation in Aluminium(III)/Water Systems With The Aid of Trisilanols - Reproducible, Large Scale Access to Molecular Aluminate Models"
    K. S. Lokare, N. Frank, B. Braun-Cula, I. Goikoetxea, J. Sauer, C. Limberg,
    Angew. Chem. 2016, 128, 12513-12517. [abstract]
    Angew. Chem. Int. Ed. 2016, 55, 12325-12329. [abstract]

    "Cover:"
    Angew. Chem. 2016, 128, 12292. [abstract]
    Angew. Chem. Int. Ed. 2016, 55, 12112. [abstract]

  72. "Molecular Design for Tailoring a Single-Source Precursor for Bismuth Ferrite"
    G. Bendt, R. Schiwon, S. Salamon, J. Landers, U. Hagemann, C. Limberg, H. Wende, S. Schulz,
    Inorg. Chem. 2016, 55, 7542-7549. [abstract]

  73. "Multimetallic systems composed of CpFe(CO)2-, Cp2Re- and (RCO2)2Bi- moieties"
    R. Schiwon, F. Schax, B. Braun, C. Limberg,
    J. Organomet. Chem. 2016, 821, 71-77. [abstract]

  74. "The Effect of Substituents at Lewis Acidic Bismuth(III) Centers on Its Propensity to Bind a Noble Metal Donor"
    C. Tschersich, S. Hoof, N. Frank, C. Herwig, C. Limberg,
    Inorg. Chem. 2016, 55, 1837-1842. [abstract]

  75. "An iron(II) hydride complex of a ligand with two adjacent β-diketiminate binding sites and its reactivity"
    H. Gehring, R. Metzinger, B. Braun, C. Herwig, S. Harder, K. Ray, C. Limberg,
    Dalton Trans. 2016, 45, 2989-2996. [abstract]

  76. "The binuclear nickel center in the A-cluster of acetyl-CoA synthase (ACS) and two biomimetic dinickel complexes studied by X-ray absorption and emission spectroscopy"
    P. Schrapers, S. Mebs, Y. Ilina, D. S. Warner, C. Wörmann, N. Schuth, R. Kositzki, H. Dau, C. Limberg, H. Dobbek, M. Haumann,
    J. Phys.: Conf. Ser. 2016, 712, 012029. [abstract]

  77. "Abrupt versus Gradual Spin-Crossover in FeII(phen)2(NCS)2 and FeIII(dedtc)3 Compared by X-ray Absorption and Emission Spectroscopy and Quantum-Chemical Calculations"
    S. Mebs, B. Braun, R. Kositzki, C. Limberg, M. Haumann,
    Inorg. Chem. 2015, 54, 11606-11624. [abstract]

  78. "Reaction of a polydentate cysteine-based ligand and its nickel(II) complex with electrophilic and nucleophilic methyl-transfer reagents – from S-methylation to acetyl coenzyme A synthase reactivity"
    D. S. Warner, C. Limberg, F. J. Oldenburg, B. Braun,
    Dalton Trans. 2015, 44, 18378-18385. [abstract]

  79. "Utilizing the Trispyrazolyl Borate Ligand for the Mimicking of O2-Activating Mononuclear Nonheme Iron Enzymes"
    M. Sallmann, C. Limberg,
    Acc. Chem. Res. 2015, 48, 2734-2743. [abstract]

  80. "A structural and functional model for the 1-aminocyclopropane-1-carboxylic acid Oxidase"
    M. Sallmann, F. Oldenburg, B. Braun, M. Réglier, A. J. Simaan, C. Limberg,
    Angew. Chem. 2015, 127, 12501-12505. [abstract]
    Angew. Chem. Int. Ed. 2015, 54, 12325-12328. [abstract]

  81. "PBiP Pincer Complexes of Pt, Pd and Ir Featuring Metal–Metal Bonds Synthesized by Oxidative Addition of Bismuth–Halide Bonds"
    C. Tschersich, B. Braun, C. Herwig, C. Limberg,
    Organometallics 2015, 34, 3782-3787. [abstract]

  82. "Reactivity of an Octanuclear Copper(I) Siloxide Compound – Isolation of a Copper(II) Oxo Compound with a Supertetrahedral Core"
    F. Schax, C. Limberg,
    Z. Anorg. Allg. Chem. 2015, 641, 2060-2064. [abstract]

  83. "Structure and Mechanism Leading to Formation of the Cysteine Sulfinate Product Complex of a Biomimetic Cysteine Dioxygenase Model"
    M. Sallmann, S. Kumar, P. Chernev, J. Nehrkorn, A. Schnegg, D. Kumar, H. Dau, C. Limberg, S. P. de Visser,
    Chem. Eur. J. 2015, 21, 7470-7479. [abstract]

  84. "Dioxygenation of cysteamine to hypotaurine at a tris(pyrazolyl)borate iron(II) unit - cysteamine dioxygenase mimicking?"
    M. Sallmann, B. Braun, C. Limberg,
    Chem. Commun. 2015, 51, 6785-6787. [abstract]

  85. "A Heterobimetallic Superoxide Complex formed through O2 Activation between Chromium(II) and a Lithium Cation"
    F. Schax, S. Suhr, B. Braun, E. Bill, C. Herwig, C. Limberg,
    Angew. Chem. 2015, 127, 1368-1372. [abstract]
    Angew. Chem. Int. Ed. 2015, 54, 1352-1356. [abstract]

  86. "Bioinspired Copper(I) Complexes that exhibit combined Monooxygenase and Catechol Dioxygenase Activity"
    A. Arnold, R. Metzinger, C. Limberg,
    Chem. Eur. J. 2015, 21, 1198-1207. [abstract]

  87. "Late Metal Scaffolds that Activate Both, Dinitrogen and Reduced Dinitrogen Species NxHy"
    C. Köthe, C. Limberg,
    Z. Anorg. Allg. Chem. 2015, 641, 18-30. [abstract]

  88. "Coordination of noble metals by an ambiphilic PBiP pincer ligand: Metallophilic Bi–Cu and Bi–Ag interactions"
    C. Tschersich, B. Braun, C. Herwig, C. Limberg,
    J. Organomet. Chem. 2015, 784, 62-68. [abstract]

  89. "Hydride binding to the active site of [FeFe]-hydrogenase"
    P. Chernevl, C. Lambertz, A. Bruenje, N. Leidel, K. Sigfridsson, R. Kositzki, C.-H. Hsieh, S. Yao, R. Schiwon, M. Driess, C. Limberg, T. Happe, M. Haumann,
    Inorg. Chem. 2014, 53, 12164-12177. [abstract]

  90. "Dioxygen Activation by Chromium(II)- and Chromium(IV)-Siloxide Complexes"
    F. Schax, E. Bill, C. Herwig, C. Limberg,
    Angew. Chem. 2014, 126, 12955-12959. [abstract]
    Angew. Chem. Int. Ed. 2014, 53, 12741-12745. [abstract]

  91. "Synthesis, Characterization and Interconversion of β-diketiminato Nickel NxHy Complexes"
    C. Köthe, B. Braun, C. Herwig, C. Limberg,
    Eur. J. Inorg. Chem. 2014, 5296-5303. [abstract]

  92. "A Cubic Fe4Mo4 Oxo Framework and its Reversible Four-Electron Redox Chemistry"
    Jan. P. Falkenhagen, B. Braun, E. Bill, D. Sattler, C. Limberg,
    Inorg. Chem. 2014, 53, 7294-7308. [abstract]

  93. "Three-coordinate nickel(II) and nickel(I) thiolate complexes based on the β-diketiminate ligand system"
    B. Horn, C. Limberg, C. Herwig, B. Braun,
    Inorg. Chem. 2014, 51, 6867-6874. [abstract]

  94. "Iron-Silicates, Iron-modulated Zeolites and molecular models thereof"
    D. Pinkert, C. Limberg,
    Chem. Eur. J. 2014, 20, 9166-9175. [abstract]

  95. "Bis(η5-Pentamethylcyclopentadienyl) Complexes of Molybdenum"
    J. H. Shin, D. G. Churchill, G. Parkin, S. Roggan, C. Jankowski, C. Limberg, I. Tonks J. Bercaw,
    Inorg. Synth. 2014, 36, 58-62. [abstract]

  96. "Molecular CuII-O-CuII Complexes: Still Waters Run Deep"
    P. Haack, C. Limberg,
    Angew. Chem. 2014, 126, 4368-4380, [abstract]
    Angew. Chem. Int. Ed. 2014, 53, 4282-4293. [abstract]

  97. "A new tripodal trisilanol ligand and its complexation behavior towards CuI, CuII and ZnII"
    F. Schax, B. Braun, C. Limberg,
    Eur. J. Inorg. Chem. 2014, 53, 2124-2130. [abstract]

  98. "The Activation of Sulfur Hexafluoride at Highly Reduced Low-Coordinate Nickel Dinitrogen Complexes"
    P. Holze, B. Horn, C. Limberg, C. Matlachowski, S. Mebs,
    Angew. Chem. 2014, 126, 2788-2791, [abstract]
    Angew. Chem. Int. Ed. 2014, 53, 2750-2753. [abstract]

  99. "A Novel Pentadentate Redox-Active Ligand and its IronIII Complexes: Electronic Structures and O2 Reactivity"
    R. Metzinger, S. Demeshko, C. Limberg,
    Chem. Eur. J. 2014, 4721-4735. [abstract]

  100. "Iron chemistry of an asymmetrically substituted, triazole-functionalised calixarene ligand"
    M. Ritter, A. Molad, V. Rawat, A. Vigalok, C. Limberg,
    Supramol. Chem. 2014, 26, 530-537. [abstract]

  101. "Shining light on integrity of a tetracobalt-polyoxometalate water oxidation catalyst by X-ray spectroscopy before and after catalysis"
    R. Schiwon, K. Klingan, H. Dau, C. Limberg,
    Chem. Commun. 2014, 50, 100-102. [abstract]

  102. "Iron-Molybdenum-oxo complexes as initiators for olefin autoxidation with O2"
    J. P. Falkenhagen, S. Demeshko, S. Horn, M. Haumann, B. Braun, S. Mebs, C. Limberg,
    Dalton Trans. 2014, 43, 806-816. [abstract]

  103. "Nickel(I)-mediated transformations of carbon dioxide in closed synthetic cycles: reductive cleavage and coupling of CO2 generating NiICO, NiIICO3 and NiIIC2O4NiII entities"
    B. Horn, C. Herwig, B. Braun, C. Limberg,
    Chem. Commun. 2013, 49, 10923-10925. [abstract]

  104. "Access to a CuII-O-CuII Motif: Spectroscopic Properties, Solution Structure, and Reactivity"
    P. Haack, A. Kärgel, C. Greco,J. Dokic, B. Braun, F. F. Pfaff, S. Mebs, K. Ray, C. Limberg,
    J. Am. Chem. Soc. 2013, 135, 16148-16160. [abstract]

  105. "Direct Proof for a Lower Reactivity of Monomeric vs. Dimeric Oxidovanadium Complexes in Alcohol Oxidation"
    C. Gunnar Werncke, R. Metzinger, C. Limberg,
    Z. Anorg. Allg. Chem. 2013, 639, 2426-2432. [abstract]

  106. "A High-Valent Heterobimetallic [CuIII(μ-O)2NiIII]2+ Core with Nucleophilic Oxo Groups"
    S. Kundu, F. F. Pfaff, E. Miceli, I. Zaharieva, C. Herwig, S. Yao, E. R. Farquhar, U. Kuhlmann, E. Bill, P. Hildebrandt, H. Dau, M. Driess, C. Limberg, K. Ray,
    Angew. Chem. 2013, 125, 5732-5736, [abstract]
    Angew. Chem. Int. Ed. 2013, 52, 5622-5626. [abstract]

  107. "Reduction and Hydrogenation of a Diazene by a (β-Diketiminato)nickel Hydrazide"
    C. Köthe, R. Metzinger, C. Limberg,
    Eur. J. Inorg. Chem. 2013, 3937-3942. [abstract]

  108. "Heterometallic Complexes with Rhenium- and Iron-Bismuth Bonds"
    R. Schiwon, R. Metzinger, C. Pfirrmann, C. Limberg,
    Z. Naturforsch. 2013, 68b, 561-568. [abstract]

  109. "Synthesis of a Chiral, Polydentate Ligand System Setting Out from L-Cysteine and First Nickel Complex Thereof"
    D. S. Warner, S. Mebs, C. Limberg,
    Z. Anorg. Allg. Chem. 2013, 639, 1577-1583. [abstract]

  110. "A Dinuclear Molecular Iron(II) Silicate with Two High-Spin Square-Planar FeO4 Units"
    D. Pinkert, S. Demeshko, F. Schax, B. Braun, F. Meyer, C. Limberg,
    Angew. Chem. 2013, 125, 5260-5263, [abstract]
    Angew. Chem. Int. Ed. 2013, 52, 5155-5158. [abstract]

  111. "Hydride Reactivity of NiII-X-NiII-Entities: Mixed-valent Hydrido Complexes and Reversible Metal Reduction"
    H. Gehring, R. Metzinger, C. Herwig, J. Intemann, S. Harder, C. Limberg,
    Chem. Eur. J. 2013, 19, 1629-1636. [abstract]

  112. "CO oxidation at nickel centres by N2O or O2 to yield a novel hexanuclear carbonate"
    B. Horn, C. Limberg, C. Herwig, M. Feist, S. Mebs,
    Chem. Commun. 2012, 48, 8243-8245. [abstract]

  113. "A chiral tripodal ligand containing three N-heterocyclic donor functions and its copper complexes – crystallization of [LCuI]22+/[L2CuII]2+ stereoisomers and tyrosinase activity"
    A. Arnold, C. Limberg, R. Metzinger,
    Inorg. Chem. 2012, 51, 12210-12217. [abstract]

  114. "Sulfur-linked Phenolates as Ligands for the Syntheses of Low-Nuclearity Iron(III) Complexes"
    R. Metzinger, C. Limberg,
    Z. Anorg. Allg. Chem. 2012, 638, 2225-2234. [abstract]

  115. "Reductive Deprotonation and Dehydrogenation of Phenylhydrazine at a Nickel Center To Give a Nickel Diazenido Complex"
    C. Köthe, R. Metzinger, C. Herwig, C. Limberg,
    Inorg. Chem. 2012, 51, 9740-9747. [abstract]

  116. "Copper(I) Siloxides – Aggregated solid state structures, Cu-Cu interactions and dynamic solution behavior"
    F. Schax, C. Limberg, C. Mügge,
    Eur. J. Inorg. Chem. 2012, 4661-4668. [abstract]

  117. "Activation and coordination of ammonia at [Cp*Ir(H)2]: NMR and matrix isolation studies"
    A.-K. Jungton, C. Herwig, T. Braun, C. Limberg,
    Chem. Eur. J. 2012, 18, 10009-10013. [abstract]

  118. "Gold- and Platinum- Bismuth Donor-Acceptor Interactions supported by an ambiphilic PBiP Pincer Ligand"
    C. Tschersich, C. Limberg, S. Roggan, C. Herwig, N. Ernsting, S. Kovalenko, S. Mebs,
    Angew. Chem. 2012, 124, 5073-5077, [abstract]
    Angew. Chem. Int. Ed. 2012, 51, 4989-4992. [abstract]

  119. "A Trispyrazolylborato-Iron-Cysteinato-Complex as a functional Model for the Cysteine-Dioxygenase"
    M. Sallmann, I. Siewert, L. Fohlmeister, C. Limberg, C. Knispel,
    Angew. Chem. 2012, 124, 2277-2280, [abstract]
    Angew. Chem. Int. Ed. 2012, 51, 2234-2237. [abstract]

  120. "The Conversion of Nickel-Bound CO to an Acetyl Thioester: Organometallic Chemistry Relevant to the Acetyl Co-enzyme A Synthase Active Site"
    B. Horn, C. Limberg, C. Herwig, S. Mebs,
    Angew. Chem. 2011, 123, 12829-12833, [abstract]
    Angew. Chem. Int. Ed. 2011, 50, 12621-12625. [abstract]

  121. "Organoelement Complexes of a Dinucleating Double β-Diiminato Ligand – Precedent Cases from Groups 1, 2 and 13"
    J. P. Falkenhagen, P. Haack, C. Limberg, B. Braun,
    Z. Anorg. Allg. Chem. 2011, 637, 1741-1749. [abstract]

  122. "Surface-inspired Molecular Vanadium Oxide Catalysts for the Oxidative Dehydrogenation of Alcohols: Evidence for Metal Cooperation and Peroxide Intermediates"
    G. Werncke, C. Limberg, C. Knispel, S.Mebs,
    Chem. Eur. J. 2011, 17, 12129-12135. [abstract]

  123. "A molecular Mo4Bi4 framework composed exclusively of unsupported metal–metal bonds "
    C. Knispel, C. Limberg, C. Tschersich,
    Chem. Commun. 2011, 47, 10794-10796. [abstract]

  124. "Four-coordinate Trispyrazolylborato Manganese and Iron Complexes with a Pyrazolato Co-ligand: Syntheses and Properties as Oxidation Catalysts"
    T. Tietz, C. Limberg, R. Stößer, B. Ziemer,
    Chem. Eur. J. 2011, 17, 10010-10020. [abstract]

  125. "C-H Bond Activation in a Molybdenumoxo-Bismuth Compound"
    C. Knispel, C. Limberg,
    Organometallics 2011, 30, 3701-3703. [abstract]

  126. "Unprecedented Binding and Activation of CS2 in a Dinuclear Copper(I) Complex"
    P. Haack, C. Limberg, T. Tietz, R. Metzinger,
    Chem. Commun. 2011, 47, 6374-6376. [abstract]

  127. "N2 Activation in NiI-NN-NiI units: The Influence of Alkali Metal Cations and CO Reactivity"
    B. Horn, S. Pfirrmann, C. Limberg, C. Herwig, B. Braun, S. Mebs, R. Metzinger,
    Z. Anorg. Allg. Chem. 2011, 637, 1169-1174. [abstract]

  128. "Transition metal complexes of the novel hexadentate ligand 1,4-Bis(di(N-methylimidazol-2-yl)methyl)phthalazine"
    S. Roggan, C. Limberg, C. Knispel,T. D. Tilley,
    Dalton Trans. 2011, 40, 4315-4323. [abstract]

  129. "Dinuclear Copper Complexes Based on Parallel β-Diiminato Binding Sites and their Reactions with O2 - Evidence for a Cu-O-Cu Entity"
    P. Haack, C. Limberg, K. Ray, B. Braun, U. Kuhlmann, P. Hildebrandt, C. Herwig,
    Inorg. Chem. 2011, 50, 2133-2142. [abstract]

  130. "Haloperoxidase Activity of Oxovanadium(V) Thiobisphenolates"
    G. Werncke, C. Limberg, C. Knispel, R. Metzinger, B. Braun,
    Chem. Eur. J. 2011, 17, 2931-2938. [abstract]

  131. "A reduced β-diketiminato-ligated Ni3H4 unit catalyzing H/D exchange"
    S. Pfirrmann, C. Limberg, C. Herwig, C. Knispel, B. Braun, E. Bill, R. Stößer,
    J. Am. Chem. Soc. 2010, 132, 13684-13691. [abstract]

  132. "Monooxygenase-Like Reactivity of an Unprecedented, Heterobimetallic FeO2Ni Moiety"
    S. Yao, C. Herwig, Y. Xiong, A. Company, E. Bill, C. Limberg, M. Driess,
    Angew. Chem. 2010, 122, 7208-7212. [abstract]
    Angew. Chem. Int. Ed. 2010, 49, 7054-7058. [abstract]

  133. "Progress in the Compilation of an Oxovanada-Silsesquioxane Portfolio and catalytic activity of organometallic Representatives in Ethylene Polymerisation"
    C. Ohde,C. Limberg, D. Schmidt, M. Enders, S. Demeshko, C. Knispel,
    Z. Anorg. Allg. Chem. 2010, 636, 2315-2322. [abstract]

  134. "The Mechanism of Water Oxidation: From Electrolysis via Homogenous to Biological Catalysis"
    H. Dau, C. Limberg, T. Reier, M. Risch, S. Roggan, P. Strasser,
    ChemCatChem 2010, 2, 724-761. [abstract]

  135. "Complexes of Click-Derived Bistriazolylpyridines: Remarkable Electronic Influence of Remote Substituents on Thermodynamic Stability as well as Electronic and Magnetic Properties"
    M. Ostermeier, M.-A. Berlin, R. Meudtner, S. Demeshko, F. Meyer, C. Limberg, S. Hecht,
    Chem. Eur. J. 2010, 16, 10202-10213. [abstract]

  136. "From Surface-Inspired Oxovanadium Silsesquioxane Models to Active Catalysts for the Oxidation of Alcohols with O2 - the Cinnamic Acid/Metavanadate System"
    C. Ohde, C. Limberg,
    Chem. Eur. J. 2010, 16, 6892-6899. [abstract]

  137. "Bismuth Allyloxides"
    C. Knispel, C. Limberg, B. Ziemer,
    Inorg. Chem. 2010, 49, 4313-4318. [abstract]

  138. "Heterometallic Complexes with Re-Bi Metal Bonds"
    R. Schiwon, C. Knispel, C. Limberg,
    Organometallics 2010, 29, 1670-1674. [abstract]

  139. "Oxovanadium(IV) Silsesquioxane Complexes"
    C. Ohde, C. Limberg, R. Stößer, S. Demeshko,
    Inorg. Chem. 2010, 5, 2479-2485. [abstract]

  140. "Reversible P4 Activation with Nickel(I) and a η3-Coordinated Tetraphosphorus Ligand between Two NiI Centers"
    S. Yao, Y. Xiong, C. Milsmann, E. Bill, S. Pfirrmann, C. Limberg, M. Driess,
    Chem. Eur. J. 2010, 16, 436-439. [abstract]

  141. "Resonant inelastic X-ray scattering on synthetic nickel compounds and Ni-Fe hydrogenase protein"
    O. Sanganas, S. Löscher, S. Pfirrmann, N. Marinos, P. Glatzel, T.-C. Weng, C. Limberg, M. Driess, H. Dau, M. Haumann,
    J. Phys.: Conf. Ser. 2009, 190, 012199. [abstract]

  142. "β-Diketiminato Nickel(I) Complexes with Very Weak Ligation Allowing For H2 and N2 Activation"
    S. Pfirrmann, S. Yao, B. Ziemer, R. Stößer, M. Driess, C. Limberg,
    Organometallics 2009, 28, 6855-6860.[abstract]

  143. "Peculiar Binding Modes of a Ligand with two Adjacent β-Diiminato Binding Sites in Alkali and Alkaline-Earth Metal Chemistry"
    D. F.-J. Piesik, P. Haack, S. Harder, C. Limberg,
    Inorg. Chem. 2009, 48, 11259-11264. [abstract]

  144. "O–O Bond Activation in Heterobimetallic Peroxides: Synthesis of the Unique Peroxide [LNi(µ,η2:η2-O2)K] and its Conversion to a Bis(µ-Hydroxo) Ni-Zn Complex"
    S. Yao, Y. Xiong, M. Vogt, H. Grützmacher, C. Herwig, C. Limberg, M. Driess,
    Angew. Chem. 2009, 121, 8251-8251. [abstract]
    Angew. Chem. Int. Ed. 2009, 48, 8107-8110. [abstract]

  145. "Low-Molecular Weight Analogues of the Soluble Methane Monooxygenase: From the Structural Mimicking of Resting-States and Intermediates to Functional Models"
    I. Siewert, C. Limberg,
    Chem. Eur. J. 2009, 15, 10316-10328. [abstract]

  146. "Zinc complexes of a tripodal ligand containing three different N-heterocyclic donor functions"
    M. Wagner, C. Limberg,
    Inorg. Chim. Acta 2009, 362, 4809-4812. [abstract]

  147. "Stabilizing the Boat Conformation of Piperazines Coordinated to IronII: iso-Butyl Substituents Lead to Robust Oxidation Catalysts via Hyperconjugation"
    M. Ostermeier, C. Limberg, C. Herwig, B. Ziemer,
    Z. Anorg. Allg. Chem. 2009, 635, 1823-1830. [abstract]

  148. "A novel tripodal ligand containing three different N-heterocyclic donor functions and its application in catechol dioxygenase mimicking"
    M. Wagner, C. Limberg, T. Tietz,
    Chem. Eur. J. 2009, 15, 5567-5576. [abstract]

  149. "A Dinuclear NiI-Dinitrogen Complex and its Reduction in Single Electron Steps"
    S. Pfirrmann, C. Limberg, C. Herwig, R. Stößer, B. Ziemer,
    Angew. Chem. 2009, 121, 3407-3411. [abstract]
    Angew. Chem. Int. Ed. 2009, 48, 3357-3361. [abstract]

  150. "What Does it Really Take to Stabilize Complexes of Late Transition Metals with Terminal Oxo Ligands?"
    C. Limberg,
    Angew. Chem. 2009, 121, 2305-2308. [abstract]
    Angew. Chem. Int. Ed. 2009, 48, 2270-2273. [abstract]

  151. "Iron and Nickel Complexes Containing β-Diketiminato ligands with Thioether Tethers"
    S. Pfirrmann, C. Limberg, E. Hoppe,
    Z. Anorg. Allg. Chem. 2009, 635, 312-316. [abstract]

  152. "Opening of bent Bi-C bonds by silanols to give stable Cp2Mo(µ-BiOR)2MoCp2 complexes"
    C. Knispel, C. Limberg, M. Mehring,
    Organometallics 2009, 28, 646-651. [abstract]

  153. "A low-coordinate nickel(II) hydride complex and its reactivity"
    S. Pfirrmann, C. Limberg, B. Ziemer,
    Dalton Trans. 2008, 6689-6691. [abstract]

  154. "A Trispyrazolylborato Iron Malonato Complex as a Functional Model for the Acetylacetone Dioxygenase"
    I. Siewert, C. Limberg,
    Angew. Chem. 2008, 120, 8071-8074. [abstract]
    Angew. Chem. Int. Ed. 2008, 47, 7953-7956. [abstract]

  155. "A Dinuclear Iron Complex Based on Parallel Malonate Binding Sites: Cooperative Activation of Dioxygen and Biomimetic Ligand Oxidation"
    I. Siewert , C. Limberg, S. Demeshko, E. Hoppe,
    Chem. Eur. J. 2008, 14, 9377-9388. [abstract]

  156. "Low-Coordinate Iron Complexes Based on Bis(pyrazolyl)borate and Their Reactivity"
    M. Wagner, C. Limberg, B. Ziemer,
    Eur. J. Inorg. Chem. 2008, 3970-3976. [abstract]

  157. "V4O10: Spectroscopic Fingerprint of a Well-Defined, Molecular Metaloxo Aggregate"
    C. Herwig, C. Limberg,
    Inorg. Chem. 2008, 47, 2937-2939. [abstract]

  158. "Dinuclear iron complexes based on parallel β-diiminato binding sites: syntheses, structures and reaction with O2"
    M. F. Pilz, C. Limberg, S. Demeshko, F. Meyer, B. Ziemer,
    Dalton Trans. 2008, 1917-1923. [abstract]

  159. "V2O5/SiO2 surface inspired, silsesquioxane-derived oxovanadium complexes and their properties"
    C. Ohde, M. Brandt, C. Limberg, J. Döbler, J. Sauer, B. Ziemer,
    Dalton Trans. 2008, 326-331. [abstract]

  160. "Reactions of permanganyl chloride with allene in low-temperature matrices"
    M. Brandt, C. Limberg,
    Inorg. Chim. Acta 2008, 361, 436-448. [abstract]

  161. "Multifunctional "Clickates" as Versatile Extended Heteroaromatic Building Blocks: Efficient Synthesis via Click Chemistry, Conformational Preferences, and Metal Coordination"
    R. M. Meudtner, M. Ostermeier, R. Goddard, C. Limberg, S. Hecht,
    Chem. Eur. J. 2007, 13, 9834-9840. [abstract]

  162. "Solvent-Dependent Oxidation of a (Pyridylmethyl)amino Ligand by FeCl3 To Give a Water-Soluble Blue Fluorophore"
    M. Ostermeier, C. Limberg, B. Ziemer, V. Karunakaran,
    Angew. Chem. 2007, 119, 5423-5426. [abstract]
    Angew. Chem. Int. Ed. 2007, 46, 5329-5331. [abstract]

  163. "Molybdocene – Based Compounds containing Mo-Sb and Mo-Sn Bonds"
    C. Knispel, C. Limberg, L. Zimmer, B. Ziemer,
    Z. Anorg. Allg. Chem. 2007, 633, 2278-2284. [abstract]

  164. "Dinuclear Zinc Complexes Based on Parallel β-Diiminato Binding Sites: Syntheses, Structures and Properties as CO2/Epoxide Copolymerization Catalysts"
    M. F. Pilz, C. Limberg, B. B. Lazarov, K. C. Hultzsch, B. Ziemer,
    Organometallics 2007, 26, 3668-3676. [abstract]

  165. "A Xanthene-based Ligand with Two Adjacent Malonate Binding Sites"
    I. Siewert, C. Limberg,
    Z. Naturforsch. 2007, 62b, 1251-1258. [abstract]

  166. "Oxovanadium(V) Tetrathiacalix[4]arene Complexes and Their Activity as Oxidation Catalysts"
    E. Hoppe, C. Limberg,
    Chem. Eur. J. 2007, 13, 7006-7016. [abstract]

  167. "Calixarene-Based Oxovanadium complexes as Molecular Models for Catalytically Active Surface Species and Homogeneous Catalysts"
    C. Limberg,
    Eur. J. Inorg. Chem. 2007, 3303-3314.[abstract]

  168. "The SOHIO Process as an Inspiration for Molecular Organometallic Chemistry"
    C. Limberg,
    Top. Organomet. Chem. 2007, 22, 79-95. [abstract]

  169. "Reactivity and Properties of [-O-BiIII···O=Mo-]n Chains"
    S. Roggan, C. Limberg, B. Ziemer, M. Siemons, U. Simon,
    Inorg. Chem. 2006, 45, 9020-9031. [abstract]

  170. "Mono- and Dinuclear Oxovanadium(V)calixarene Complexes and Their Activity as Oxidation Catalysts"
    E. Hoppe, C. Limberg, B. Ziemer,
    Inorg. Chem. 2006, 45, 8308-8317. [abstract]

  171. "Molecular molybdenum/bismuth compounds"
    S. Roggan, C. Limberg,
    Inorg. Chim. Acta 2006, 359, 4698-4722. [abstract]

  172. "Catalytic Epoxidation and 1,2-Dihydroxylation of Olefins with Bispidine-Iron(II)/H2O2 Systems"
    M. R. Bukowski, P. Comba, A. Lienke, C. Limberg, C. L. de Laorden, R. Mas-Ballesté, M. Merz, L. Que Jr.,
    Angew. Chem., 2006, 118, 3524-3528. [abstract]
    Angew. Chem. Int. Ed. 2006, 45, 3446-3449. [abstract]

  173. "Xanthene-Based Ligand with Two Adjacent β-Diiminato Binding Sites"
    M. F. Pilz, C. Limberg, B. Ziemer,
    J. Org. Chem. 2006, 71, 4559-4564. [abstract]

  174. "High-valent Molybdenum Imido Complexes with Tethered Olefins"
    I. Siewert, C. Limberg, B. Ziemer,
    Z. Anorg. Allg. Chem. 2006, 632, 1078-1082. [abstract]

  175. "Vanadium calixarene complexes as molecular models for supported vanadia"
    E. Hoppe, C. Limberg, B. Ziemer, C. Mügge,
    J. Mol. Cat. 2006, 251, 34-40. [abstract]

  176. "The Coordination Chemistry of Iron with the 1,4-Bis(2-pyridyl-methyl)piperazine Ligand"
    M. Ostermeier, C. Limberg, B. Ziemer,
    Z. Anorg. Allg. Chem. 2006, 632, 1287-1292. [abstract]

  177. "Organometallic Mo-O-Bi complexes"
    S. Roggan, C. Limberg, B. Ziemer, M. Brandt,
    J. Organomet. Chem. 2005, 690, 5282-5289. [abstract]

  178. "Molecular Compounds with Mo-O-Bi Moieties"
    S. Roggan, C. Limberg, B. Ziemer,
    Angew. Chem. 2005, 117, 5393-5397. [abstract]
    Angew. Chem. Int. Ed 2005, 44, 5259-5262. [abstract]

  179. "„Bent Bonds" between Bismuth and Carbon Atoms as a Result of C-H Activation in Mo-Bi Complexes"
    S. Roggan, C. Limberg, G. Schnakenburg, S. Sandhöffner, H. Pritzkow, B. Ziemer,
    Chem. Eur. J. 2005, 11, 225. [abstract]

  180. "A (H2O)4/crown ether network spanned between organometallic complex metal fragments"
    C. Wippert-Rodrigues, C. Limberg, H. Pritzkow,
    Chem. Commun. 2004, 2734-2735. [abstract]

  181. "Metalation of 2-Propenylphenol"
    C. Wippert-Rodriguez, C. Limberg, H. Pritzkow,
    Eur. J. Inorg. Chem. 2004, 3644-3650. [abstract]

  182. "Intramolecular C-H Activation in Complexes with Mo-Bi Metal Bonds"
    S. Roggan, C. Limberg, B. Ziemer, M. Brandt,
    Angew. Chem. 2004, 116, 2906-2910. [abstract]
    Angew. Chem. Int. Ed. 2004, 43, 2846-2849. [abstract]

  183. "Bispidine Ligand Effects on the Iron / Hydrogen Peroxide Chemistry"
    M. R. Bukowski, P. Comba, C. Limberg, M. Merz, L. Que Jr., T. Wistuba,
    Angew. Chem. 2004, 116, 1303-1307. [abstract]
    Angew. Chem. Int. Ed., Engl. 2004, 43, 1283-1287. [abstract]

  184. "The Role of Radicals in Metal-Assisted Oxygenation Reactions"
    C. Limberg,
    Angew. Chem. 2003, 115, 6112-6136. [abstract]
    Angew. Chem. Int. Ed., Engl. 2003, 42, 5932. [abstract]

  185. "Synthesis, Structures and Properties of Oxovanadium(V) Complexes with Ketone and Ketolate Ligands"
    T. Wistuba, C. Limberg, H. Pritzkow,
    Z. Anorg. Allg. Chem. 2002, 628, 2340-2344. [abstract]

  186. "Synthesis of Heterometallic Bismuth/Molybdenum Alkoxides and Their Behavior on Silica Surfaces"
    C. Limberg, M. Hunger, W. Habicht, E. Kaifer,
    Inorg. Chem. 2002, 41, 3359-3365. [abstract]

  187. "Reactions of Cyclopentadienylmolybdenum compounds with Bismuth Alkoxides"
    M. Hunger, C. Limberg, E. Kaifer, P. Rutsch,
    J. Organomet. Chem. 2002, 641, 9-14. [abstract]

  188. "The Reaction of Permanganyl Chloride with Olefins: Intermediates and Mechanism as Derived from Matrix-Isolation Studies and Density Functional Theory Calculations"
    T. Wistuba, C. Limberg,
    Chem. Eur. J. 2001, 7, 4674-4685. [abstract]

  189. "The Photochemistry of [CpMo(CO)3(η1-C3H5)] in Frozen Gas Matrices at 10 K and the Behaviour of [CpMo(CO)2(η3-C3H5)] Isomers in Different Media"
    C. Limberg, A. J. Downs, T. M. Greene, T. Wistuba,
    Eur. J. Inorg. Chem. 2001, 2613-2618. [abstract]

  190. "The Activation of O2 at Ruthenium Complexes: Catalytic Chlorination of Unsaturated Organic Substrates within the System O2/HCl/H2O"
    C. Limberg, J. H. Teles,
    Adv. Syn. Catal. 2001, 343, 447-449. [abstract]

  191. "Synthesis of Molybdenum(II) and Molybdenum(IV) Complexes Bearing Tethered  Homoallylic Phosphines"
    C. Wippert Rodrigues, B. Antelmann, C. Limberg, E. Kaifer, H. Pritzkow,
    Organometallics 2001, 20, 1825-1831. [abstract]

  192. "Dynamic Behaviour, Solution and Crystal Structure of an Allylmolybdenum/Oxo/Hydroxo Heterocubane"
    C. Borgmann, C. Limberg, S. Cunskis, P. Kircher,
    Eur. J. Inorg. Chem. 2001, 349-352. [abstract]

  193. "Synthesis of Heteronuclear Molybdenum/Bismuth Alkoxides Stabilized by Organic Ligands"
    M. Hunger, C. Limberg, P. Kircher,
    Organometallics 2000, 19, 1044-1050. [abstract]

  194. "On the Trail of CrO2Cl2 in Its Reactions with Organic Compounds "
    C. Limberg,
    Chem. Eur. J. 2000, 6, 2083-2089. [abstract]

  195. "Trapping of an Organic Radical by an O=CrVI Function"
    T. Wistuba, C. Limberg, P. Kircher,
    Angew. Chem. 1999, 111, 3222-3224. [abstract]
    Angew. Chem. Int. Ed. 1999, 38, 3037-3039. [abstract]

  196. "Oxygen Transfer from Chromyl Chloride to Alkynes and Allene - IR-Spectroscopic Identification of η1-Ketene and Cyclopropanone Complexes of O=CrCl2"
    T. Wistuba, C. Limberg,
    Eur. J. Inorg. Chem. 1999, 1335-1342. [abstract]

  197. "Synthesis of Oxochromium(VI) Alkoxides via Epoxide Cleavage. Structure, Reactivity, and Mechanism"
    C. Limberg, T. Wistuba,
    J. Org. Chem. 1999, 64, 6169-6176. [abstract]

  198. "Syntheses and Ligating Properties of Molybdocene Alkoxides - The First Heterodimetallic Alkoxide Containing Molybdenum and Bismuth"
    M. Hunger, C. Limberg, P. Kircher,
    Angew. Chem. 1999, 111, 1171-1174. [abstract]
    Angew. Chem. Int. Ed. 1999, 38, 1105-1108. [abstract]

  199. "Syntheses, Structures, and Spectroscopic Properties of Alkoxide, Hydroxide, and Siloxide Complexes with (η3-allyl)Mo-Moieties"
    C. Borgmann, C. Limberg, L. Zsolnai, K. Heinze,
    Z. Naturforsch. 1999, 54b, 473-481. [abstract]

  200. "Synthesis and X-ray structures of complexes with (η3-allyl)Mo units in oxygen-rich coordinationspheres"
    C. Borgmann, C. Limberg, E. Kaifer, H. Pritzkow, L. Zsolnai,
    J. Organomet. Chem. 1999, 580, 214-224. [abstract]

  201. "Reactive Intermediates in Olefin Oxidations with Chromyl Chloride. IR-Spectroscopic Proof for O=CrCl2- Epoxide Complexes"
    C. Limberg, R. Köppe,
    Inorg. Chem. 1999, 38, 2106-2116. [abstract]

  202. "Synthesis and X-ray structure of a complex containing two (η3-allyl)MoII units bridged by MoVIO42- and exhibiting an unusual type of aggregation"
    C. Borgmann, C. Limberg, L. Zsolnai,
    Chem. Commun. 1998, 2729-2730. [abstract]

  203. "Catalysis of esterification reactions by oxo-molybdenum-alkoxides: X-ray structures of Cl2(O)Mo(µ-nPr)2(µ-HOnPr)Mo(O)Cl2 and Cl2(O)Mo(µ-OEt)2(µ2-η1η1-HOCH2CH2OH)Mo(O)Cl2]"
    M. Hunger, C. Limberg, L. Zsolnai,
    Polyhedron 1998, 17, 3935-3945. [abstract]

  204. "NMR spectroscopic evidence for chromium(VI) alkoxides with α-hydrogen atoms"
    C. Limberg, S. Cunskis, A. Frick,
    Chem. Commun. 1998, 225-226. [abstract]

  205. "Matrix Isolation and Characterization of a Reactive Intermediate in Olefin Oxidation with Chromyl Chloride"
    C. Limberg, R. Köppe, H. Schnöckel,
    Angew. Chem. 1998, 110, 512-515. [abstract]
    Angew. Chem. Int. Ed. 1998, 37, 496-499. [abstract]

  206. "Synthesis, structure and properties of bisallyltris(trimethylphosphine)molybdenum(II) - X-ray crystal ctructures of [Mo(η1:η2-C3H5)2(PMe3)3] and PMe4+[MoCl4(PMe3)2]- "
    C. Borgmann, C. Limberg, A. Driess,
    J. Organomet. Chem. 1997, 541, 367-375. [abstract]

  207. "The [Cl2OMo(µ-OC2H5)2(µ-HOC2H5)MoOCl2]/PMe3 System: A Chameleon Yielding the X-ray Structures of MoOCl2(PMe3)3, MoOCl3(PMe3)2, Mo4O4Cl4(µ2-OEt)4(PMe3)2(µ3-O)2 and MoOCl3(OPMe3)(PMe3)"
    C. Limberg, M. Büchner, K. Heinze, O. Walter,
    Inorg. Chem., 1997, 36, 872-879. [abstract]

  208. "Intermediates and products of the reaction of MoCl5 with ethanol: crystal structures of [MoOCl3(EtOH)] and H[MoOCl4]·2EtOH"
    C. Limberg, R. Boese, B. Schiemenz,
    J. Chem. Soc., Dalton Trans., 1997, 1633-1637. [abstract]

  209. "Modeling the Formation of Molybdenum Oxides from Alkoxides: Crystal Structures of [Mo4O4Cl4(µ2-OEt)4H(OEt)2(µ3-OH)2] and [PPN]+[Et3NH]+[Cl2(O)Mo(µ2-O)2Mo(O)Cl2]2-"
    C. Limberg, A. J. Downs, A. J. Blake, S. Parsons,
    Inorg. Chem., 1996, 35, 4439-4448. [abstract]

  210. "Synthesis and crystal structure of an encapsulated fragment of MoO2 in the unique Mo8 oxo-cluster compound [Mo8O8Cl6(µ3-O)4(OH)2(µ-OH)4(µ-OEt)4(HOEt)4] and its relevance to the sol-gel synthesis of molybdenum oxides"
    A. J. Blake, A. J. Downs, C. Limberg, S. Parsons,
    J. Chem. Soc., Dalton Trans., 1995, 3263-3268. [abstract]

  211. "Bis(triphenylphosphine)iminium Tetrachloro oxo molybdenum(V) at 150 K"
    A. J. Blake, S. Parsons, A. J. Downs, C. Limberg,
    Acta Cryst. Sec. C, 1995, 571-573. [abstract]

  212. "Isolation and crystal structure of a dimeric oxomolybdenum(V) complex containing two ethoxy bridges and one ethanol bridge"
    C. Limberg, S. Parsons, A. J. Downs, D. J. Watkin,
    J. Chem. Soc., Dalton Trans., 1994, 1169-1174. [abstract]

  213. "Synthesis and X-Ray crystal structure of a unique puckered six-membered metallacycle in Mo6O6Cl6(µ3-O)2(µ2-OEt)6(µ2-Cl)2"
    C. Limberg, S. Parsons, A. J. Downs,
    J. Chem. Soc., Chem. Commun., 1994, 497-498. [abstract]

  214. "Preparation, characterisation and reactions of tellurocarbonyl difluoride and triflouromethanetellurenyl iodide"
    R. Boese, A. Haas, C. Limberg,
    J. Chem. Soc., Dalton Trans., 1993, 2547-2556. [abstract]

  215. "Neue Synthese für Tellurocarbonyl-difluorid"
    A. Haas, C. Limberg,
    Chimia 1992, 46, 78-78. [abstract]

  216. "Synthesis and characterization of 2,2,4,4-tetrafluoro-1,3-ditelluretane and -1-selena-3-telluretane via the intermediate difluorotelluroketone"
    R. Boese, A. Haas, C. Limberg,
    J. Chem. Soc., Chem. Commun., 1991, 1378-1379. [abstract]

  217. "Preparation of perfluoroorganoselenides from perfluoroalkenes and selenium or diseleniumdichloride"
    A. Haas, C. Limberg, S. R. Sterlin,
    J. Fluorine Chem., 1991, 53, 71-78. [abstract]

  218. "Abfangen von Hexafluorselenoaceton durch Cycloadditionen mit Dienen sowie Darstellung von Hg[SeCF(CF3)2]2 und (CH3)3SiSeCF(CF3)2"
    A. Haas, C. Limberg, M. Spehr,
    Chem. Ber., 1991, 124, 423-426. [abstract]

Reviews in Angewandte Chemie

Basistexte Chemie:
Clusterverbindungen von Hauptgruppenelementen. Von C. E. Housecroft. 94 S., ISBN 3-527-29397-3;

Periodizität: Eigenschaften der Hauptgruppenelemente. Von N. C. Norman. 93 S., ISBN 3-527-29398-1;

Anorganische Materialien. Von M. T. Weller. 92 S., ISBN 3-527-29399-X;

Konzepte der Übergangsmetallchemie. Von M. J. Winter. 92 S., ISBN 3-527-29400-7.

Alle VCH Verlagsgemeinschaft, Weinheim, 1995

C. Limberg, Angew. Chem. 1997, 109 309.

Other publications

  1. "Sauerstoff - das Element des Lebens" - Aktuelle Wochenschau,
    C. Limberg, C. Herwig,
    German Chemical Society 2016, 20. [abstract]

  2. "Organometallic Oxidation Catalysis" - Topics in Organometallic Chemistry,
    eds. F. Meyer, C. Limberg,
    Springer Berlin Heidelberg 2007, 22.

  3. "ADHOC 2005 in Köln: Das Neuste zur Aktivierung von Disauerstoff und zur Homogenen Katalytischen Oxidation"
    C. Limberg,
    Angew. Chem. 2005, 117, 6256-6258; Angew. Chem. Int. Ed. 2005, 44, 6102-6104.

  4. "Oxygenations with Metaloxo Compounds - Reactive Intermediates, Mechanisms and Models"
    C. Limberg,
    Humboldt-Spektrum, 2003 , 2-3, 1-6.

  5. Beiträge für "Catalysis from A-Z - A concise Encyclopedia", 2nd edition Hrsg.: B. Cornils, W. A. Herrmann, R. Schlögl, C.-H. Wong;
    ISBN 3-527-29855-X, Wiley-VCH Verlag GmbH, Weinheim 2001 .

  6. "Wie kann Sauerstoff aktiviert und doch kontrolliert werden? Metalle machen es möglich!" C. Limberg,
    Jahrbuch der Akademie der Wissenschaften zu Göttingen 2001, Vandenhoeck und Ruprecht, S. 186-196.

Humboldt University Berlin - Faculty of Mathematics and Natural Sciences - Department of Chemistry - AG Limberg
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