Publications
| 186. | M. Talavera, S. Mollasalehi ,T. Braun, Chem. Sci. 2024, 15, 8472–8477. „C–H and C–F bond activation of fluorinated propenes at Rh: enabling cross-coupling reactions with outer-sphere C–C coupling“ |
| 185. | J. Cardozo, O. He, W. Ma, K. Ray, T. Braun, Z. anorg. allg. Chem. 2024, e202400028. „An Iminophosphinite Pincer Iridium Complex: Synthesis and Catalytic Tool for Alkane Transfer Dehydrogenations“ |
| 184. | R. Jaeger, S. Rachor, M. Ahrens, T. Braun, Chem. Eur. J. 2024, e202401571. „Activation of SO2F2 at a Rhodium PNP Pincer Complex: Ligand Supported S-F Bond Cleavage to Generate NSO2F Derivatives“ |
| 183. | C. Heinekamp, S. Kneiske, A. G. Buzanich, M. Ahrens, T. Braun, F. Emmerling, Cat. Sci. Technol. 2024, 14, 673-680. „A fluorolytic sol–gel route to access an amorphous Zr fluoride catalyst: a useful tool for C–F bond activation“ |
| 182. | C. Heinekamp, A. G. Buzanich, M. Ahrens, T. Braun, F. Emmerling, Chem. Commun. 2023, 59, 11224. „An amorphous Lewis-acidic zirconium chlorofluoride as HF shuttle: C–F bond activation and formation“ |
| 181. | D. Herbstritt, P. Tomar, T. Braun, Molecules 2023, 28, 6693. „Activation of SF5CF3 by the N-Heterocyclic Carbene SIMes „ |
| 180. | D. Herbstritt, P. Tomar, R. Müller, M, Kaupp, T. Braun, Eur. J. Chem. 2023, e202301556. „A 2,2-Difluoroimidazolidine Derivative for Deoxyfluorination Reactions: Mechanistic Insights by Experimental and Computational Studies“ |
| 179. | X. Pan, M. Talavera, T. Braun, J. Fluorine Chem. 2023, 267, 110116. „Efficient hydrostannation of fluorinated alkenes“ |
| 178. | D. Herbstritt, T. Braun, Chem. Commun. 2023, 59, 3850-3853. „Reduction of SF5CF3 via iridium catalysis: radical trifluoromethylation of aromatics“ |
| 177. | M. Bui, K. F. Hoffmann, T. Braun, S. Riedel, C. Heinekamp, K. Scheurell, G. Scholz, T. M. Stawski, F. Emmerling, ChemCatChem 2023, e202300350. „An Amorphous Teflate Doped Aluminium Chlorofluoride: A Solid Lewis-Superacid for the Dehydrofluorination of Fluoroalkanes“ |
| 176. | K. Kretschmar, V. Pelmenschikov, M. Kaupp, T. Braun, P. Wittwer, S. Rachor, J. Cardozo, Eur. J. Inorg. Chem. 2023, e202300099. „Bimetallic Carbonyl Complexes Based on Iridium and Rhodium: Useful Tools for Hydrodefluorination Reactions“ |
| 175. | D. Kass, S. Yao, K. B. Krause, T. Corona, L. Richter, T. Braun, S. Mebs, M. Haumann, H. Dau, T. Lohmiller, C. Limberg, M. Drieß, K. Ray, Angew. Chem. Int. Ed. 2023, e202209437. „Spectroscopic Properties of a Biologically Relevant [Fe2(μ-O)2] Diamond Core Motif with a Short Iron-Iron Distance“ |
| 174. | O. He, B. Cula, T. Braun, Helv. Chim. Acta 2023, 106, e202200156. „Indolyl Phosphine Nickel(II) Fluorido Complexes: Synthesis and Intermediates in Suzuki-Miyaura Cross-Coupling Reactions“ |
| 173. | A. Loges, G. Scholz, N. de Sousa Amadeu, J. Shao, D. Schultze, J. Fuller, B. Paulus, F. Emmerling, T. Braun, T. John, Eur. J. Mineral. 2022, 34, 507-521. „Studies on the local structure of the F ∕ OH site in topaz by magic angle spinning nuclear magnetic resonance and Raman spectroscopy“ |
| 172. | S. Sander, E. J. Cosgrove, R. Müller, M. Kaupp, T. Braun, Chem. Eur. J. 2023, 29, e202202768. „Hydrogen Bonding in Platinum Indolylphosphine Polyfluorido and Fluorido Complexes“ |
| 171. | S. G. Rachor, R. Müller, M. Kaupp, T. Braun, Eur. J. Inorg. Chem. 2023, 26, e202200668. „Hydrogen and Halogen Bonding to Au(I) Fluorido Complexes“ |
| 170. | S. G. Rachor, M. Ahrens, T. Braun, Angew. Chem. Int. Ed. 2022, 61, e202212858. „Conversion of a AuI Fluorido Complex into an N-Fluoroamido Derivative: N−F versus Au−N Reactivity“ |
| 169. | X. Pan, M. Talavera, T. Braun, J. Fluorine Chem. 2022, 263, 110046. „Dehydrofluorination reactions at Lewis acidic ACF in the presence of HSnBu3„ |
| 168. | S. Sander, T. Braun, Angew. Chem. Int. Ed. 2022, 61, e202204678. „Platinum-Catalyzed Hydrofluorination of Alkynes: Hydrogen Bonding to Indolylphosphine Ligands to Provide Fluoride Reactivity“ |
| 167. | S. G. Rachor, R. Jaeger, T. Braun, Eur. J. Inorg. Chem. 2022, 2022, e202200158. „Au(I) Fluorido Phosphine Complexes: Tools for the Hydrofluorination of Alkynes“ |
| 166. | M. Wozniak, S. Sander, B. Cula, M. Ahrens, T. Braun, Chem. Eur. J. 2022, 28, e202200626. „Reactivity of Xantphos-Type Rhodium Complexes Towards SF4: SF3 Versus SF2 Complex Generation“ |
| 165. | X. Pan, M. Talavera, G. Scholz, T. Braun, ChemCatChem 2022, 14, e202200029. „Chlorodefluorination of Fluoromethanes and Fluoroolefins at a Lewis Acidic Aluminum Fluoride“ |
| 164. | M. Talavera, T. Braun, Chem. Sci. 2022, 13, 1130-1135. „Competing C–H and C–F bond activation reactions of a fluorinated olefin at Rh: a fluorido vinylidene complex as an intermediate in an unprecedented dehydrofluorination step“ |
| 163. | S. G. Rachor, R. Müller, P. Wittwer, M. Kaupp, T. Braun, Inorg. Chem. 2022, 61, 357-367. „Synthesis, Reactivity, and Bonding of Gold(I) Fluorido-Phosphine Complexes“ |
| 162. | D. Dirican, M. Talavera, T. Braun, Chem. Eur. J. 2021, 27, 17707-17712. „Fluorination Reactions at a Platinum Carbene Complex: Reaction Routes to SF3, S(=O)F and Fluorido Complexes“ |
| 161. | S. Sander, R. Müller, M. Ahrens, M. Kaupp, T. Braun, Chem. Eur. J. 2021, 27, 14287-14298. „Platinum Indolylphosphine Fluorido and Polyfluorido Complexes: An Interplay between Cyclometallation, Fluoride Migration, and Hydrogen Bonding“ |
| 160. | M. Talavera, T. Braun, Chem. Eur. J. 2021, 27, 11926-11934. „Versatile Reaction Pathways of 1,1,3,3,3-Pentafluoropropene at Rh(I) Complexes [Rh(E)(PEt3)3 (E=H, GePh3, Si(OEt)3, F, Cl): C-F versus C-H Bond Activation Steps“ |
| 159. | R. Jaeger, M. Talavera, T. Braun, J. Fluorine Chem. 2021, 247, 109803. „Studies on the reactivity of Rh(I) complexes towards SF5Cl“ |
| 158. | C. Becker, T. Braun, B. Paulus, Catalysts 2021, 11, 565. „Theoretical Study on the Lewis Acidity of the Pristine AlF3 and Cl-Doped α-AlF3 Surfaces“ |
| 157. | M.-C. Kervarec, T. Braun, M. Ahrens, E. Kemnitz, Beilstein J. Org. Chem. 2020, 16, 2623-2635. „Activation of pentafluoropropane isomers at a nanoscopic aluminum chlorofluoride: hydrodefluorination versus dehydrofluorination“ |
| 156. | M. Talavera, T. Braun, Synlett 2020, 31, 1760-1774. „Rhodium(I) Complexes as Useful Tools for the Activation of Fluoroolefins“ |
| 155. | M. Talavera, S. Hinze, T. Braun, R. Laubenstein, R. Herrmann, Molecules 2020, 25, 3977. „A SF5 Derivative of Triphenylphosphine as an Electron-Poor Ligand Precursor for Rh and Ir Complexes“ |
| 154. | N. Pfister, M. Bui, T. Braun, P. Wittwer, M. Ahrens, Z. Anorg. Allg. Chem. 2020, 646, 808-815. „Synthesis and Reactivity of Iridium(I) Fluorido Complexes: Oxidative Addition of SF4 at trans-[Ir(F)(CO)(PEt3)2]“ |
| 153. | M.-C. Kervarec, E. Kemnitz, G. Scholz, S. Rudić, T. Braun, C. Jäger, A. A. L. Michalchuk, F. Emmerling, Chem. Eur. J. 2020, 26, 7314-7322. „A HF Loaded Lewis-Acidic Aluminium Chlorofluoride for Hydrofluorination Reactions“ |
| 152. | D. Dirican, N. Pfister, M. Wozniak, T. Braun, Chem. Eur. J. 2020, 26, 6945-6963. „Reactivity of Binary and Ternary Sulfur Halides towards Transition-Metal Compounds“ |
| 151. | M. Talavera, G. Meißner, S. G. Rachor, T. Braun, Chem. Commun. 2020, 56, 4452-4455. „C-F activation reactions at germylium ions: dehydrofluorination of fluoralkanes“ |
| 150. | C. P. Marshall, G. Scholz, T. Braun, E. Kemnitz, Catal. Sci. Technol. 2020, 10, 391-402. „Strong Lewis acidic catalysts for C-F bond activation by fluorination of activated γ-Al2O3„ |
| 149. | P. Tomar, T. Braun, E. Kemnitz, Eur. J. Inorg. Chem. 2019, 44, 4735-4739. „Preparation of NHC Stabilized Al(III)fluorides: Fluorination of [(SIMes)AlMe3] with SF4 or Me3SnF“ |
| 148. | M. Talavera, R. Müller, T. Ahrens, C. N. von Hahmann, B. Braun-Cula, M. Kaupp, T. Braun, Faraday Discuss. 2019, 220, 328-349. „Activation of tetrafluoropropenes by rhodium(I) germyl and silyl complexes“ |
| 147. | C. Xu, M. Talavera, S. Sander, T. Braun, Dalton Trans. 2019, 48, 16258-16267. „C-H and C-F bond activation reactions of pentafluorostyrene at rhodium complexes“ |
| 146. | M. Talavera, C. N. von Hahmann, R. Müller, M. Ahrens, M. Kaupp, T. Braun, Angew. Chem. Int. Ed. 2019, 58, 10688-10692; M. Talavera, C. N. von Hahmann, R. Müller, M. Ahrens, M. Kaupp, T. Braun, Angew. Chem. 2019, 131, 10798-10802. „C-H and C-F bond activation reactions of fluorinated propenes at rhodium: Distinctive reactivity of the refrigerant HFO-1234yf“ |
| 145. | C. P. Marshall, G. Scholz, T. Braun, E. Kemnitz, Dalton Trans. 2019, 48, 6834-6845. „Nb-doped variants of high surface aluminium fluoride: a very strong bi-acidic solid catalyst“ |
| 144. | Ò. Torres, N. Pfister, T. Braun, P. Wittwer, Dalton Trans. 2019, 48, 6153-6161. „C–F activation of perfluorophenazine at nickel: selectivity and mechanistic investigations“ |
| 143. | M. Kervarec, C. P.
Marshall, T. Braun, E. Kemnitz,
J.
Fluorine Chem. 2019, 221,
61-65. „Selective dehydrofluorination of 2-chloro-1,1,1,2-tetrafluoropropane (HCFC-244bb) to 2-chloro-3,3,3-trifluoropropene (HFO-1233xf) using nanoscopic aluminium fluoride catalysts at mild conditions“ |
| 142. | P. Roesch, R.
Müller, A. Dallmann, G. Scholz, M. Kaupp, T. Braun, B.
Braun-Cula, P. Wittwer, Chem.
Eur. J. 2019, 25,
4678-4682. „A Silylene-Boran Lewis Pair as a Tool for Trapping Water Molecule: Silanol Formation and Dehydrogenation“ |
| 141. | B. Calvo, C. P.
Marshall, T. Krahl, J. Kröhnert, A. Trunschke, G. Scholz, T.
Braun, E. Kemnitz, Dalton
Trans. 2018, 47,
16461-16473. „Comparative study of the strongest Lewis acids known: ACF and HS-AlF3 |
| 140. | H. Baumgarth, G.
Meier, C. N. von Hahmann, T. Braun, Dalton
Trans. 2018, 47,
16299-16304. „Reactivity of rhodium and iridium peroxido complexes towards hydrogen in the presence of B(C6F5)3 or [H(OEt2)2][B{3,5-(CF3)2C6H3}4] |
| 139. | N. Pfister, T.
Braun, P. Wittwer, M. Ahrens, Z.
Anorg. Allg. Chem. 2018, 644,
1064-1070. „Selective Formation and Characterization of a RhIII λ4-Trifluorosulfanyl Complex„ |
| 138. | P. Tomar, T. Braun,
E. Kemnitz, Chem.
Commun. 2018, 54,
9753-9756. „Photochemical activation of SF6 by N-heterocyclic carbenes to provide a deoxyfluorinating reagent“ |
| 137. | S. Mebs, S. I.
Kalläne, T. Braun, Z.
Kristallog. – Cryst. Mater. 2018, 233,
615-626. „Hapticity of asymmetric rhodium-allyl compounds in the light of real-space bonding indicators“ |
| 136. | M. A. Ellwanger, C.
von Randow, S. Steinhauer, Y. Zhou, A. Wiesner, H. Beckers, T. Braun,
S. Riedel, Chem. Commun. 2018,
54,
9301-9304. „Tuning the Lewis acidity of difluorido gold(III) complexes: the synthesis of [AuClF2(SIMes)] and [AuF2(OTeF5)(SIMes)]“ |
| 135. | A. L. Raza, M. F.
Kuehnel, M. Talavera, M. Teltewskoi, M. Ahrens, P. Kläring, T.
Braun, D. Lentz, J.
Fluorine Chem. 2018, 214,
80-85. „Reactivity of rhodium hydrido and silyl complexes towards 1,1-difluoroallene“ |
| 134. | P. Wittwer, A.
Stelzer, T. Braun, Eur.
J. Inorg. Chem. 2018, 27,
3187-3194. „Reactivity of Cp*Al towards Silanols: Formation and Hydrolysis of Alumosiloxanes“ |
| 133. | M. A.
Ellwanger, S. Steinhauer, P. Golz, T. Braun,
S. Riedel, Angew.
Chem. 2018, 130,
7328-7332; Angew.
Chem. Int. Ed. 2018, 57,
7210-7214. „Stabilization of Lewis Acidic AuF3 as an N-Heterocyclic Carbene Complex: Preparation and Characterization of [AuF3(SIMes)]“ |
| 132. | C. N. von Hahnmann,
M. Talavera, C. Xu, T. Braun, Chem.
Eur. J. 2018, 24,
11131-11138. „Reactivity of 3,3,3-Trifluoropropyne at Rhodium Complexes: Development of Hydroboration Reactions“ |
| 131. | C. P. Marshall, T.
Braun, E. Kemnitz, Catal.
Sci. Technol. 2018, 8,
3151-3159. „Modifying the reactivity of a solid Lewis acid: niobium and antimony doped nanoscopic aluminum fluoride“ |
| 130. | C. Berg, N.
Pfister, T. Braun, B. Braun-Cula, Chem.
Eur. J. 2018, 24,
7985-7990. „Diverse Reactivity of Platinum SF3 and SF2 Complexes towards EtOH and Me3SiOEt“ |
| 129. | M.
Wozniak, T. Braun, M. Ahrens, B. Braun-Cula, P. Wittwer, R. Herrmann,
R. Laubenstein, Organometallics
2018, 37,
821-828. „Activation of SF6 at a Xantphos-Type Rhodium Complex“ |
| 128. | B.
Calvo, T. Braun, E. Kemnitz, ChemCatChem
2018, 10,
403-406. „Hydrogen/Deuterium-Exchange Reactions of Methane with Aromatics and Cyclohexane Catalyzed by a Nanoscopic Aluminium Chlorofluoride“ |
| 127. | G.
Meißner, K. Kretschmar, T. Braun, E. Kemnitz, Angew.
Chem. 2017, 129,
16556-16559; Angew. Chem. Int. Ed. 2017, 56,
16338-16341. „Consecutive Transformations of Tetrafluoropropenes: Hydrogermylation and Catalytic C−F Activation Steps at a Lewis Acidic Aluminum Fluoride“ |
| 126. | R.
Laubenstein, M. Ahrens, T.
Braun, Z.
Anorg. Allg. Chem. 2017, 643,
1723-1729. „Synthesis and Structures of Gallium-β-Diketiminate Complexes: Isolation of a Dinuclear Gallium(II) Complex“ |
| 125. | J.
Kohlmann, T. Braun, J.
Fluorine
Chem. 2017, 203,
140-145. „Synthesis and reactivity of a cationic palladium complex as possible intermediate in a Suzuki-Miyaura cross-coupling reaction“ |
| 124. | K.
S. Lokare, P. Wittwer, B. Braun-Cula, N. Frank, S. Hoof, T. Braun, C.
Limberg, Z.
Anorg. Allg. Chem. 2017, 643,
1581-1588. „Mimicking Base Ineraction with Acidic Sites [Si-O(H)-Al] of Zeolites in Molecular Models“ |
| 123. | P.
Roesch, U. Warzok, M. Enke, R. Müller, C. Schattenberg, C. A.
Schalley, M. Kaupp, T. Braun, P. Wittwer, Chem. Eur. J. 2017, 23,
13964-13972. „Reactivity of the Sterically Demanding Siloxanediol Mes2Si(OH)-(μ-O)Si(OH)Mes2 Towards Water and Ether Molecules“ |
| 122. | M.
A. Ellwanger, S. Steinhauer, P. Golz, H. Beckers, A. Wiesner, B.
Braun-Cula, T. Braun, S. Riedel, Chem.
Eur. J. 2017, 23,
13501-12509. „Taming the High Reactivity of Gold(III) Fluoride: Fluorido Gold(III) Complexes with N-Based Ligands“ |
| 121. | G.
Meißner, M. Feist, T. Braun, E. Kemnitz, J. Organomet. Chem. 2017, 847,
234-241. „Selecive reduction of a C-Cl bond in halomethanes with Et3GeH at nanoscopic Lewis acidic Aluminium fluoride Formation of Fluorovinyl and Fluorido Complexes“ |
| 120. | J.
Kohlmann, T. Braun, R. Laubenstein, R. Herrmann, Chem. Eur. J. 2017, 23,
12218-12232. „Suzuki-Miyaura Cross-Coupling Reactions of Highly Fluorinated Arylboronic Esters: Catalytic Studies and Stoichiometric Model Reactions on the Transmetallation Step“ |
| 119. | G.
Meißner, D. Dirican, C. Jäger, T. Braun, E. Kemnitz, Catal.
Sci. Technol. 2017, 7,
3348-3354. „Et3GeH versus Et3SiH: controlling reaction pathways in catalytic C-F bond activations at a nanoscopic aluminium chlorofluoride“ |
| 118. | J.
Berger, T. Braun, T. Ahrens, P. Kläring, R. Laubenstein, B.
Braun-Cula, Chem. Eur.
J. 2017, 23,
8886-8900. „The Versatile Behavior of Platinum Alkyne Complexes towards XeF2: Formation of Fluorovinyl and Fluorido Complexes“ |
| 117. | C.
Berg, T. Braun, M. Ahrens, P. Wittwer, R. Herrmann, Angew.
Chem. 2017, 129,
4364-4368; Angew.
Chem. Int. Ed. 2017, 56,
4300-4304. „Activation of SF6 at Platinum Complexes: Formation of SF3 Derivatives and Their Application in Deoxyfluorination Reactions“ |
| 116. | A.
K. Siwek, M. Ahrens, M.
Feist, T. Braun, E. Kemnitz, ChemCatChem
2017, 9,
839-845. „Activation of Chlorinated Methanes at the Surface of Nanoscopic Lewis Acidic Aluminum Fluorides“ |
| 115. | T.
Ahrens, B. Schmiedecke, T. Braun, R. Herrmann, R. Laubenstein, Eur. J. Inorg. Chem. 2017, 3,
713-722. „Activation of CS2 and COS at a Rhodium(I) Germyl Complex: Generation of CS and Carbido Complexes“ |
| 114. | T.
Ahrens, M. Teltewskoi, M.
Ahrens, T. Braun, R. Laubenstein, Dalton
Trans. 2016, 45,
17495-17507. „Competing reaction pathways of 3,3,3-trifluoropropene at rhodium hydrido, silyl and germyl complexes: C-F bond activation versus hydrogermylation“ |
| 113. | R. Herrmann, P. Wittwer, T. Braun, Eur. J. Inorg. Chem. 2016, 4898-4905. „Platinum Complexes Bearing a tripodal Germyl Ligand“ |
| 112. | H.
Baumgarth, G. Meier, T. Braun,
B. Braun-Cula, Eur. J.
Inorg. Chem. 2016,
4565-4572. „Rhodium and Iridium Fluorido and Bifluorido Complexes Derived from Peroxido Precursors“ |
| 111. | L.
Zámostná, T. Braun, Nachrichten
aus der Chemie 2016, 64,
829-835. „Inertes Schwefelhexafluorid aktivieren“ |
| 110. | B.
Calvo, J. Wuttke, T. Braun,
E. Kemnitz, ChemCatChem. 2016,
8,
1945-1950. „Heterogeneous Catalytic Hydroarylation of Olefins at a Nanoscopic Aluminium Chlorofluoride“ |
| 109. | A.
C. Stelzer, P. Hrobárik, T. Braun, M. Kaupp, B. Braun-Cula, Inorg. Chem. 2016, 55,
4915-4923. „Completing the Heterocubane Family [Cp*AlE]4 (E = O, S, Se, and Te) by Selective Oxygenation and Sulfuration of [Cp*Al]4: Density Functional Theory Calculations of [Cp*AlE]4 and Reactivity of [Cp*AlO]4 toward Hydrolysis“ |
| 108. | C.
Mitzenheim, T. Braun, R. Laubenstein, B. Braun, R. Herrmann, Datlton Trans. 2016, 45,
6394-6404. „Hydrodealkoxylation reactions of silyl ligands at platinum: reactivity of SIH3 and SiH2Me complexes“ |
| 107. | C.
Berg, R.
Laubenstein, T. Braun, B. Braun, Chem.
Commun. 2016, 52,
3931-3934. „Palladium-mediated borylation of pentafluorosulfanyl functionalized compounds: the crucial role of metal fluorido complexes“ |
| 106. | T.
Ahrens, T. Braun, B. Braun, R. Herrmann, Dalton Trans. 2016, 45,
4716-4728. „Synthesis of a rhodium(I) germyl complex: a useful tool for C-H and C-F bond activation reactions“ |
| 105. | S.
I. Kalläne, R.
Laubenstein, T. Braun, M. Dietrich, Eur.
J. Inorg. Chem. 2016,
530-537. „Activation of Si-Si and Si-H Bonds at a Platinum Bis(diphenylphosphanyl)ferrocene (dppf) Complex: Key Steps for the Catalytic Hydrogenolysis of Disilanes“ |
| 104. | R.
Laubenstein, M.-D. Serb, U. Englert, G. Raabe, T. Braun, B. Braun, Chem. Commun. 2016, 52,
1214-1217. „Is it all in the hinge? A kryptoracemate and three of its alternative racemic polymorphs of an aminonitrile“ |
| 103. | F.
Liebau, T. Braun, B. Braun, J.
Fluorine Chem. 2015, 180,
192-200. „Dehydrogenation of cycloalkanes at rhodium complexes bearing fluorinated cyclopentadienyl ligands“ |
| 102. | J.
Berger, T. Braun, R. Herrmann, B. Braun, Dalton Trans. 2015, 44,
19553-19565. „Reactivity of platinum alkyne complexes towards N-fluorobenzenesulfonimide: formaiton of platinum compounds bearing a β-fluorovinyl ligand“ |
| 101. | S.
I. Kalläne, T. Braun, M. Teltewskoi, B. Braun, R. Herrmann, R.
Laubenstein, Chem.
Commun. 2015, 51,
14613-14616. „Remarkable reactivity of a rhodium(I) boryl complex towards CO2 and CS2: isolation of a carbido complex“ |
| 100. | L.
Zámostná, T.
Braun, Angew.
Chem. 2015, 127,
10798-10802; Angew.
Chem. Int. Ed. 2015, 54,
10652-10656. „Catalytic Degradation of Sulfur Hexafluoride by Rhodium Complexes“ |
| 99. | A.
Bittner, T. Braun, R. Herrmann, S. Mebs, Chem. Eur. J. 2015, 21,
12299-12302. „Rhodium-Mediated Oxygenation of Nitriles with Dioxygen: Isolation of Rhodium Derivatives of Peroxyimidic Acids“ |
| 98. | H.
Baumgarth, T. Braun, B. Braun, R. Laubenstein, R. Herrmann, Eur. J. Inorg. Chem. 2015, 2015,
3157-3168. „Synthesis of an iridium Peroxido Complex and its Reactivity Towards Brønsted Acids“ |
| 97. | M.
Feist, M. Ahrens, A. Siwek,
T. Braun, E. Kemnitz, J.
Therm.
Anal. Calorim. 2015, 121,
929-935. „Triethylsilane-loaded aluminium chlorofluoride“ |
| 96. | A.
L. Raza, T. Braun, Chem.
Sci. 2015, 6,
4255-4260. „Consecutive C-F bond activation and C-F bond formation of heteroaromatics at rhodium: the peculiar role of FSi(OEt)3„ |
| 95. | L.
Zámostná, S. Sander, T. Braun, R. Laubenstein, B.
Braun, R. Herrmann, P. Kläring, Dalton
Trans. 2015, 44,
9450-9469. „Synthesis and structure of rhodium(I) silyl carbonyl complexes: photochemical C-F and C-H bond activation of fluorinated aromatic compounds“ |
| 94. | S.
I. Kalläne, M. Teltewskoi, T. Braun, B. Braun, Organometallics 2015, 34,
1156-1169. „C-H and C-F Bond Activations at a Rhodium(I) Boryl Complex: Reaction Steps for the Catalytic Borylation of Fluorinated Aromatics“ |
| 93. | M.
A. Chilleck, L. Hartenstein, T. Braun, P. W. Roesky, B. Braun, Chem. Eur. J. 2015, 21,
2594-2602. „Cationic Zinc Organyls as Precatalysts for Hydroamination Reactions“ |
| 92. | T.
Ahrens, J. Kohlmann, M. Ahrens, T. Braun, Chem. Rev. 2015, 115,
931-972. „Functionalization of Fluorinated Molecules by Transition-Metal-Mediated C-F Bond Activation to Access Fluorinated Building Blocks“ |
| 91. | R.
Herrmann, T. Braun, S. Mebs, Eur.
J.
Inorg. Chem. 2014, 28,
4826-4835. „[Ge(H)(2-C6H4PPh2)3] as Ligand precursor at Ruthenium: Formation and Reactivity of [Ru(Cl){Ge(2-C6H4PPh2)3)}]“ |
| 90. | S.
I.
Kalläne, T. Braun, Angew.
Chem. 2014, 126,
9465-9469; Angew.
Chem. Int. Ed. 2014, 53,
9311-9315. „Catalytic Borylation of SCF3-Functionalized Arenes by Rhodium(I) Boryl Complexes: Regioselective C-H Activation at the ortho-Position“ |
| 89. | G.
Meier, V. Steck, B. Braun, A. Eißler, R. Herrmann, M. Ahrens,
R. Laubenstein, T. Braun, Eur.
J.
Inorg. Chem. 2014,
2793-2808. „Synthesis and Structures of Fluorinated (β-Diketiminato)rhodium Complexes: Si-H Activation of Silanes at a Carbonyl Complex“ |
| 88. | S.
I.
Kalläne, T. Braun, B. Braun, S. Mebs, Dalton
Trans. 2014, 43,
6786-6801. „Versatile reactivity of a rhodium(I) boryl complex towards ketones and imines“ |
| 87. | L.
Zámostná, T. Braun, B. Braun, Angew.
Chem. 2014, 126,
2783-2787; Angew.
Chem. Int. Ed. 2014, 53,
2745-2749. „S-F and S-C Activation of SF6 and SF5 Derivatives at Rhodium: Conversion of SF6 into H2S“ |
| 86. | M.
Chilleck, T. Braun, B. Braun,
S. Mebs, Organometallics 2014,
33,
551-560. „Neutral and Cationic Zinc Complexes with N- and S-Donor-Functionalized Cyclopentadienyl Ligands“ |
| 85. | T.
Ahrens, T. Braun, B. Braun, Z.
Anorg. Allg. Chem. 2014, 640,
93-99. „Activation of 1,2-Dihydridodisilanes at Platinum(0) Phosphine Complexes: Syntheses and Structures of Bissilyl Platinum(II) Complexes“ |
| 84. | M.
Teltewskoi, S. I. Kalläne, T. Braun, R. Herrmann, Eur. J. Inorg. Chem. 2013, 33,
5762-5768. Synthesis of Rhodium(I) Boryl Complexes: Catalytic N–H Activation of Anilines and Ammonia“ |
| 83. | P.
Kläring, T. Braun, Angew.
Chem. 2013, 125,
11302-11307; Angew.
Chem. Int. Ed. 2013, 52,
11096-11101. „Insertion of CS2 into Iridium–Fluorine Bonds“ |
| 82. | L.
Zámostná, M.
Ahrens, T. Braun, J.
Fluorine Chem. 2013, 155,
132-142. „Catalytic hydrodefluorination of fluoroaromatics with silanes as hydrogen source at a binuclear rhodium complex: Characterization of key intermediates“ |
| 81. | A.
Eißler, P. Kläring, F. Emmerling, T. Braun, Eur. J. Inorg. Chem. 2013, 27,
4775-4788. „α-Dialdimine Complexes of Rhodium(I) and Iridium(I): Their Reactivity with Dioxygen and Dihydrogen“ |
| 80. | C.
Mitzenheim, T. Braun, Angew.
Chem. 2013, 125,
8787-8790; Angew.
Chem. Int. Ed. 2013, 52,
8625-8628. „Si-Si and Si-O Bond Activation at Platinum: Stepwise Formation of a SiH3 Complex“ |
| 79. | A.
L. Raza, J. Panetier, M. Teltewskoi, S. Macgregor, T. Braun, Organometallics 2013, 32,
3795-3807. „Rhodium(I) Silyl Complexes for C–F Bond Activation Reactions of Aromatic Compounds: Experimental and Computational Studies“ |
| 78. | B.
Rabay, T. Braun, J. P. Falkenhagen, Dalton
Trans. 2013, 42,
8058-8065. „Photolytic C–H activation and dehydrogenation of alkanes at cyclopentadienyl iridium complexes in a perfluorinated solvent“ |
| 77. | M.
Ahrens, G. Scholz, T. Braun, E. Kemnitz, Angew.
Chem. 2013, 125,
5436-5440; Angew.
Chem. Int. Ed. 2013, 52,
5328-5332. „Catalytic Hydrodefluorination of Fluoromethanes at Room Temperature by Silylium-ion-like Surface Species“ |
| 76. | M.
Kuehnel, D. Lentz, T. Braun, Angew.
Chem. 2013, 125,
3412-3433; Angew.
Chem. Int. Ed. 2013, 52,
3328-3348. „Synthesis of Fluorinated Building Blocks by Transition-Metal-Mediated Hydrodefluorination Reactions“ |
| 75. | >M.
Chilleck, T. Braun, R. Herrmann, B. Braun, Organometallics 2013, 32,
1067-1074. „Zinc Complexes with the N-Donor-Functionalized Cyclopentadienyl Ligand C5Me4(CH2)2NMe2„ |
| 74. | J.
Voigt, M. Chilleck, T. Braun, Dalton
Trans. 2013, 42,
4052-4058. „Activation of Si–Si and Si–H bonds at Pt: a catalytic hydrogenolysis of silicon–silicon bonds“ |
| 73. | D. Breyer, T. Braun,
Efficient Preparations of Fluorine Compounds, Vol. 1, H. W.
Roesky
(Hrsg.), John Wiley & Sons,
Hoboken 2012,
237-239. „Palladium-Mediated Synthesis of 4-Vinyltetrafluoropyridine and 2,3,5,6-Tetrafluoropyridine“ |
| 72. | M. Teltewskoi, T. Braun,
Efficient Preparations of Fluorine Compounds, Vol. 1, H. W.
Roesky
(Hrsg.), John Wiley & Sons,
Hoboken 2012,
235-236. „Rhodium-Mediated Synthesis of a Tetrafluoropyridyl-2-boronate Ester“ |
| 71. | F. Wehmeier, T. Braun,
Efficient Preparations of Fluorine Compounds, Vol. 1, H. W.
Roesky
(Hrsg.), John Wiley & Sons,
Hoboken 2012,
232-234. „Rhodium-Mediated Synthesis of (3,3,3-Trifluoropropyl)trimethoxysilane and (3,3,3-Trifluoropropyl)triphenylsilane“ |
| 70. | G.
Meier, T. Braun, Angew.
Chem. 2012, 124,
12732-12737; Angew.
Chem. Int. Ed. 2012, 51,
12564-12569. „Hydrogenation of a Rhodium Peroxido Complex by Formate Derivatives: Mechanistic Studies and the Catalytic Formation of H2O2 from O2„ |
| 69. | D.
Breyer, J. Berger, T. Braun,
S. Mebs, J.
Fluorine Chem. 2012, 143,
263-271. „Nickel fluoro complexes as intermediates in catalytic cross-coupling reactions“ |
| 68. | S.
Mebs, M. A. Chilleck, S. Grabowsky, T. Braun, Chem. Eur. J. 2012, 18,
11647-11661. „Hapticity Uncovered: Real-Space Bonding Indicators for Zincocene Chemistry“ |
| 67. | A.-K.
Jungton, C. Herwig, T. Braun, C. Limberg, Chem. Eur. J. 2012, 18,
10009-10013. „Activation and Coordination of Ammonia at [Cp*Ir(H2)]: NMR and Matrix Isolation Studies“ |
| 66. | A.-K.
Jungton, P.
Kläring, T. Braun, A. Eißler, Z.
Anorg. Allg. Chem. 2012, 638,
505-511. „Synthesis, Reactivity and Structure of Iridium Tetrafluoropyridyl Complexes: Ammonia Coordination and Activation“ |
| 65. | P.
Kläring, A.-K. Jungton, T. Braun, C. Müller, Eur. J. Inorg. Chem. 2012,
1430-1436. „Synthesis, Structure and Reactivity of Iridium Hydrido Fluorido Complexes“ |
| 64. | T.
Braun, Organometallics 2012,
31,
1213-1215. „Organometallic Chemistry Meets Fluorine“ |
| 63. | D.
Breyer
, T. Braun, P. Kläring, Organometallics
2012,
31,
1417-1424. „Synthesis and Reactivity of the Fluoro Complex trans-[Pd(F)(4-C5NF4)(iPr2PCH2CH2OCH3)2]: C-F Bond Formation and Catalytic C-F Bond Activation Reactions“ |
| 62. | >M.
Prechtl, M. Teltewskoi, A. Dimitrov, E. Kemnitz, T. Braun, Chem. Eur. J. 2011,
17,
14385-14388. „Catalytic C-H Bond Activation at Nanoscale Lewis Acidic Aluminium Fluorides: H/D Exchange Reactions at Aromatic and Aliphatic Hydrocarbons“ |
| 61. | J.
Voigt, T. Braun, Dalton
Trans. 2011, 40,
12699-12704. „Si–H and Si–Si activation at Pt: synthesis and reactivity of neutral and cationic silyl complexes“ |
| 60. | M.
A. Chilleck, T.
Braun, B. Braun, Chem.
Eur. J. 2011, 17,
12902-12905. „Cationic Cyclopentadienyl Zinc Complexes with Slipped Triple-Decker and Half-Sandwich Structures“ |
| 59. | P.
Kläring, S. Pahl, T.
Braun, A. Penner, Dalton
Trans. 2011,
6785-6791. „Facile oxidative addition of water at iridium: reactivity of trans-[Ir(4-C5NF4)(H)(OH)(PiPr3)2] towards CO2 and NH3„ |
| 58. | A.
Penner, T.
Braun, Eur.
J. Inorg. Chem. 2011,
2579-2587. „Rhodium and Iridium Complexes with α-Diketimine Ligands: Oxidative Addition of H2 and O2„ |
| 57. | G.
Meier, T.
Braun, Angew.
Chem. 2011,
123,
3338-3342; Angew.
Chem. Int. Ed. 2011,
50,
3280-3284. „A Rhodium Peroxide Complex in Mono-, Di- and Peroxygenation Reactions“ |
| 56. | T.
Braun, F. Wehmeier, Eur.
J. Inorg. Chem. 2011,
613-625. „C-F Bond Activation of Highly Fluorinated Molecules at Rhodium: From Model Reactions to Catalyis“ |
| 55. | D. Breyer, T.
Braun, A. Penner, Dalton
Trans. 2010,
7513-7520. „Isolation and reactivity of palladium hydrido complexes: intermediates in the hydrodefluorination of pentafluorpyridine“ |
| 54. | A.-K. Jungton, A.
Meltzer, C. Präsang, T.
Braun, M. Driess, A. Penner, Dalton
Trans. 2010,
5436-5438. „Addition of [(h5-C5Me5)IrH4] to a zwitterionic silylene: stepwise formation of iridium(V) and iridium(III)-silylene complexes“ |
| 53. | M. Teltewskoi, J. A.
Panetier, Stuart A.
Macgregor, T. Braun, Angew.
Chem.
2010,
122, 4039-4043; Angew.
Chem. Int. Ed.
2010,
49, 3947-3951. „A Highly Reactive Rhodium(I)-Boryl Complex as a Useful Tool for C-H Bond Activation and Catalytic C-F Bond Borylation“ |
| 52. | A. Penner, T.
Schröder,T. Braun, and B.
Ziemer Eur.
J. Inorg. Chem. 2009,
4464-4464. „Synthesis, Structure, and Reactivity of Rhodium Bipyridine Compounds: Formation of a RhII Hydrido Cluster and a RhIII Peroxide Complex“ |
| 51. | M. Ahijado-Salomon,
Ann-Katrin Jungton, T.
Braun, Dalton
Trans. 2009,
7669-7677. „Activation of ethylene and ammonia at iridium: C-H versus N-H oxidative addition“ |
| 50. | T. Braun, M.
Ahijado-Salomon, K.
Altenhöner, M. Teltewskoi, S. Hinze, Angew.
Chem.
2009,
121, 1850-1854; Angew.
Chem. Int. Ed.
2009,
48, 1818-1822. „C-F Activation at Rhodium Boryl Complexes: Formation of 2-Fluoroalkyl-1,3,2-Dioxoborolanes by Catalystic Functionalization of Hexafluoropropene“ |
| 49. | G. Meier, T.
Braun, Angew.
Chem.
2009,
121, 1546-1548; Angew.
Chem. Int. Ed.
2009,
48, 1575-1577. „Catalytic C-F Activation and Hydrodefluorination of Fluoroalkyl Groups“ |
| 48. | A. Roscher, T.
Braun, Dalton
Trans. 2009,
1378-1382. „Towards a Catalytic Hydrogenolysis of Silicon-Silicon Bonds: Formation of Si-H Bonds from Disilanes and H2 at Platinum“ |
| 47. | E. Yegen, U. Zimmermann,
W. E. S. Unger, T. Braun, Plasma
Processes and
Polymers 2009,
6, 11-16. „C-F bond cleavage during derivatization reaction of amino groups with TFAB and PFB at plasma processed organic surfaces“ |
| 46. | M. Ahijado-Salomon, T.
Braun, A. Penner, Angew.
Chem.
2008,
120, 8999-9003; Angew.
Chem. Int. Ed.
2008,
47, 8867-8871. „Stepwise Oxygenation of Pinacolborane by a Rhodiumperoxo Complex: Detection of an Intermediate Metal Borate and Perborate“ |
| 45. | M. Ahijado-Salomon, T.
Braun, I. Krossing, Dalton
Trans. 2008,
5197-5206. „Iridium Derivates of Fluornated Aromatics by C-H Activation: Isolation of Classical and Non-classical Hydrides“ |
| 44. | T. Schraub, P. Fischer, A. Steffen, T. Braun, U. Radius, A. Mix J. Am. Chem. Soc. 2008, 130,
9304-9317. „C−F Activation of Fluorinated Arenes using NHC-Stabilized Nickel(0) Complexes: Selectivity and Mechanistic Investigations“ |
| 43. | M. Ahijado, T. Braun, Angew.
Chem.
2008,
120, 2996-3000; Angew.
Chem. Int. Ed.
2008,
47, 2954-2958. „Rhodium Derivatives of Peroxoboronic Acids and Peroxoboric Acid: Formation of Metallatrioxaborolanes from an h2 -Peroxo Complex“ |
| 42. | A. Steffen, T. Braun, B.
Neumann, H.-G. Stammler Angew.
Chem. 2007, 119 ,8828-8832; Angew. Chem. Int.
Ed.
2007,
46, 8674-8678. „Palladium Fluro Complexes: Useful Tools to Access Organometallic Metallamacrocycles“ |
| 41. | A. Steffen, T.
Hagemeister, T. Braun, P. Jutzi, B.
Neumann,
H.-G. Stammler Organometallics. 2007, 26 ,
3820–3825. „Synthesis of 3,3,3- Trifluoropropyl Substituted Cyclopentadienes and Their Zirconocene Derivatites: Catalytic Applications in the Polymerization of Ethylene“ |
| 40. | T. Braun, D. Noveski, M.
Ahijado, F. Wehmeier, Dalton
Trans. 2007,
5118-5132. „Hydrodefluorination of Pentafluoropyridine at Rhodium using Dihydrogen: Detection of Unusual Rhodium Hydrido Complexes“ |
| 39. | T. Braun, F. Wehmeier,
K. Altenhöner, Angew.
Chem.. 2007, 119,
5415-5418; Angew.
Chem. Int. Ed.
2007,
46, 5321-5324. „Catalytic C-F Bond Activation of Hexafluoropropene by Rhodium: Formation of (3,3,3- Trifluoropropyl)silanes“ |
| 38. | L. Weber, G. Noveski, T.
Braun, H.-G. Stammler, B.
Neumann, Eur. J. Inorg. Chem. 2007,
562-567. „Synthesis of the h2-1-Phosphaallen Complexes [(h5-C5H5)(CO)(NO)W{h2-R1P=C=C(R2)H}] (R1 = tBu, Cy; R2 = Ph,H) from [(h5-C5H5)(CO)(NO)W=C=C(R2)H}] (R2 = Ph,H) and Inversely Polarized Phosphaalkenes R1P=C(NMe2)2 (R1 = tBu, Cy), and Their Structure“ |
| 37. | T. Braun, R. N. Perutz,
Comprehensive Organometallic
Chemistry III, Vol. 1, R. H. Crabtree, M. P. Mingos (Hrsg.), Elsevier,
Oxford 2007,
725-758. „Transition-Metal Mediated C-F Bond Activation“ |
| 36. | T. Braun, J. Izundu, A.
Steffen, B. Neumann, H.-G.
Stammler, Dalton Trans. 2006,
5118-5132. „Reactivity of a Palladium Fluoro Complex Towards Silanes and Bu3SnCH=CH2: Catalytic Derivatisation of Pentafluoropyridine Based on Carbon-Fluorine Bond Activation Reactions“ |
| 35. | T. Braun, V. Schorlemer,
B.
Neumann, H.-G. Stammler, J.
Fluorine Chem. 2006, 127,
367-372. „Palladium mediated activation of C-F bonds in 2,4,6-trifluoropyrimidine: synthesis and structure of palladium pyrimidyloxy and pyrimidinone derivatives“ |
| 34. | L. Weber, P. Bayer, T.
Braun,
H.-G. Stammler, B. Neumann, Organometallics 2006, 25,
1786-1794. „Arsaalkenes RAs=C(NMe2)2 [R = PhC(O), 4-EtC6H4C(O), 2,4,6-Me3C6H2C(O), tBuC(O), Me3Si]: Versatile Reagents in the Chemistry of Heterocumulenes“ |
| 33. | L. Weber, I. Domke, C.
Schmitd,
T. Braun, H.-G. Stammler,
B. Neumann, Dalton Trans. 2006,
2127-2132. „Syntheses, Structures, Luminescence and Electrochemistry of Benzene- and Biphenyl-centered Bis- and Tris-1,3,2-diazaboroles and -1,3,2-diazaborolodines“ |
| 32. | L. Weber, P. Bayer, S.
Uthmann,
T. Braun, H.-G. Stammler,
B. Neumann, Eur. J. Inorg. Chem. 2006,
137-143. „Reactivity of Inversely Polarized Arsaalkenes RAs=C(NMe2)2 {R = [h5-C5Me5)(CO)2Fe], tBuC(O), 4-EtC6H4C(O)} towards Phosphavinylidene Complexes [h5-(C5H5)(CO)2M=P=C(SiMe3)2] (M = Mo, W)“ |
| 31. | T. Braun, A. Steffen, V.
Schorlemer, B. Neumann, H.-G.
Stammler, Dalton Trans. 2005,
3331-3336. „Routes to Unique Palladium A-Frame Complexes with a Bridging Fluoro-Ligand“ |
| 30. | M. Ahijado, T. Braun, D.
Noveski, N. Kocher, B. Neumann, D.
Stalke, H.-G. Stammler, Angew.
Chem. 2005, 117,
7107-7111; Angew. Chem. Int. Ed. 2005, 44,
6947-6951. „Rhodium- mediated Formation of Peroxides from Dioxygen: Isolation of Hydroperoxo, Silylperoxo and Methylperoxo Intermediates“ |
| 29. | T. Braun, Angew.
Chem. 2005,
117,
5138-5140; Angew.
Chem. Int. Ed. 2005, 44,
5012-5014. „Oxidative Atdition of NH3 to a Transition Metal: a Key-Step for the Metal-Mediated Derivatization of Ammonia?“ |
| 28. | T. Braun, A. Steffen, M.
I.
Sladek, B. Neumann, H.-G.
Stammler, Organometallics 2005, 23,
4057-4064. „Catalytic C-C Coupling Reactions at Ni by C-F Activation of a Pyrimidine in the Presence of a C-Cl Bond: The Crucial Role of Highly Reactive Fluoro Complexes“ |
| 27. | D. Noveski, T. Braun, B.
Neumann, A. Stammler, H.-G.
Stammler, Dalton Trans. 2004,
4106-4119. „C-F or C-H bond activation and C-C coupling reactions of fluorinated pyridines at rhodium: synthesis, structure and reactivity of a variety of tetrafluoropyridyl complexes“ |
| 26. | N. A. Jasim, R. N.
Perutz, A.
C. Whitwood, T. Braun, J.
Izundu, B. Neumann, S. Rothfeld, H.-G. Stammler, Organometallics
2004, 23,
6140-6149. „Contrasting reactivity of fluoropyridines at palladium and platinum: C-F oxidative atdition at palladium, alkyl transfer from phosphorus to platinum“ |
| 25. | D. Noveski, T. Braun, S.
Krückemeier, J.
Fluorine Chem. 2004, 125,
959-966. „Synthesis and Reactivity of Rhodium Fluoro Complexes“ |
| 24. | D. Noveski, T. Braun,
M.
Schulte, B. Neumann, H.-G.
Stammler, Dalton Trans. 2003,
4075-4083. „C-F activation and hydrodefluorination of fluorinated alkenes at rhodium“ |
| 23. | T. Braun, S. Rothfeld,
V.
Schorlemer, A. Stammler, H.-G.
Stammler, Inorg. Chem. Commun. 2003, 6,
752-755. „Palladium Mediated Activation of a C-F Bond in Pentafluoropyridine: Synthesis, Structure and Reactivity of a Pyridyloxy Complex“ |
| 22. | A. Bockholt, T. Braun,
P.
Jutzi, B. Neumann, A. Stammler,
H.-G. Stammler, Organosilicon
Chemistry V, (Hrsg.:
N. Auner, J. Weis), Wiley-VCH 2003,
S. 50-54. „New Donor-Stabilized Organosilicon Cations: Synthesis, Structure and Reactivity“ |
| 21. | T. Braun, M. I. Sladek,
B.
Neumann, H.-G. Stammler, New.
J. Chem. 2003, 27,
313-318. 3-Fluoropyridyl Nickel Complexes as Useful Tools for the Selective Synthesis of New 2,4,5,6-Tetrafluoropyridines: A Route Complementing the Established Methods to Access Fluorinated Pyridines“ |
| 20. | T. Braun, R. N. Perutz, Perspectives
in
Organometallic Chemistry,
(Hrsg.: C. G. Screttas, B. R.
Steele), RSC 2003,
S. 136-151. „Routes to Fluorinated Organic Derivatives by Nickel Mediated C-F Activation of Heteroaromatics“ |
| 19. | T. Braun, G.
Münch, B.
Windmüller, O.
Gevert, M. Laubender, H. Werner, Chem.
Eur. J. 2003, 9,
2516-2530. „Synthesis, Molecular Structure, and C-C Coupling Reactions of Carbeneruthenium(II) Complexes with C5H5Ru(=CRR‘) and C5Me5Ru(=CRR‘) as Molecular Units“ |
| 18. | T. Braun, D. Noveski, B.
Neumann, H.-G. Stammler, Angew.
Chem. 2002, 114,
2870-2873; Angew.
Chem. Int. Ed. 2002, 41,
2745-2747. „Conversion of Hexafluoropropene into 1,1,1-Trifluoropropane by C-F Activation at Rhodium“ |
| 17. | T. Braun, B.
Blöcker,
V. Schorlemer, B. Neumann,
A. Stammler, H.-G. Stammler, J.
Chem. Soc., Dalton Trans. 2002,
2213-2218. „Synthesis, Structure and Reactivity of Fluorovinyl Nickel Complexes: Formation of a Phosphonioethenyl Complex“ |
| 16. | M. I. Sladek, T. Braun,
B.
Neumann, H.-G-Stammler, J.
Chem. Soc., Dalton Trans. 2002,
297-299. „Aromatic C-F Activation at Ni in the Presence of a Carbon Chlorine Bond: The Nickel Mediated Synthesis of new Pyrimidines“ |
| 15. | T. Braun, R. N. Perutz, Chem.
Commun. 2002,
2749-2757. „Routes to Fluorinated Organic Derivatives by Nickel Mediated C-F Activation of Heteroaromatics“ |
| 14. | I. Atheaux, F. Delpech,
B.
Donnadieu, S. Sabo-Etienne, B.
Chaudret, K. Hussein, J.-C. Barthelat, T. Braun, S. B. Duckett, R. N.
Perutz, Organometallics 2002,
5347-5357. „Exchange Processes in Complexes with Two Ruthenium (h2-silane) Linkages: Role of the Secondary Interactions between Silicon and Hydrogen Atoms“ |
| 13. | T. Braun, R.N. Perutz,
M. I.
Sladek, Chem. Commun. 2001,
2254-2255. „Catalytic C-F Activation of Polyfluorinated Pyridines by Nickel-Mediated Cross-Coupling Reactions“ |
| 12. | T. Braun, L. Cronin, C.
L.
Higgitt, J. E. McGrady, R. N.
Perutz, M. Reinhold, New. J.
Chem. 2001, 25,
19-21. „Coordination and oxidative atdition of octafluoronaphthalene at a nickel-centre: isolation of an intermediate in C-F bond activation“ |
| 11. | T.
Braun, S. J. Archibald, J.
A. Gaunt, J. E. Hobson, R. N.
Perutz, J. Chem. Soc., Dalton
Trans. 2000,
2013-1018. „Chemistry of Nickel Tetrafluoropyridyl Derivatives: Synthesis and Structure of a Binuclear Complex With Bridging Pyridyl Ligands“ |
| 10. | T. Braun, S. P. Foxon,
R. N.
Perutz, P. H. Walton, Angew.
Chem. 1999, 111,
3543-3545; Angew.
Chem. Int. Ed. 1999, 38,
3326-3329. „Nickel-Assisted Carbon-Fluorine Bond Activation of 2,4,6-Trifluoropyrimidine: The Synthesis of New Pyrimidine and Pyrimidinone Derivatives“ |
| 9. | T. Braun, S. Parsons, R.
N.
Perutz, M.Voith, Organometallics 1999, 18,
1710-1716. „Reactivity of a Nickelfluoride Complex: Preparation of new Tetrafluoropyridyl Derivatives“ |
| 8. | H. Werner, T. Braun, T.
Daniel,
O. Gevert, M. Schulz, J.
Organomet. Chem. 1997, 541,
127-141. „Cyclopentadienyl- und Pentamethylcyclopentadienyl-Rutheniumkomplexe mit Carboxylat-, Vinylester- und Carben-Liganden“ |
| 7. | T. Braun, M. Laubender,
O.
Gevert, H. Werner, Chem.
Ber./Recl. 1997, 130,
559-564. „Halfsandwich-Type Triisopropylstibane Ruthenium Compounds with 16-, 17- and 18-Electron Configurations and an Unsymmetrical Binuclear 18/16-Electron Ru2(SbiPr3) Species“ |
| 6. | P. LeGendre, T. Braun,
C.
Bruneau, P. H. Dixneuf, J.
Org. Chem. 1996, 61,
8453-8456. „Preparation of Optically Active Cyclic Carbonates and 1,2-Diols via Enantioselective Hydrogenation of a-Methylenedioxolanones Catalyzed by Chiral Ruthenium (II) Complexes“ |
| 5. | T. Braun, P. Meuer, H.
Werner, Organometallics 1996, 15,
4075-4077. „h3-2.3.4-Butadienyl and h3-3.4.5-Pentatrienyl Ruthenium Complexes From Vinylidene and Allenylidene Precursors“ |
| 4. | T. Braun, O. Gevert, H.
Werner, J. Am.
Chem.
Soc. 1995, 117,
7291-7292. „A Ruthenium-Mediated [C1 + C2] Coupling Reaction: Formation of π-Allyl Complexes from Carbenemetal Precursors“ |
| 3. | T. Braun, P. Steinert,
H.
Werner, J. Organomet.
Chem. 1995, 488,
169-176. „Vinylidene transition metal complexes XXXIV: The preparation and structure of neutral vinylidene and allenylidene ruthenium(II) compounds of the half-sandwich type containing iPr2PCH2CO2Me as supporting ligand“ |
| 2. | H. Werner, T. Daniel, T.
Braun,
O. Nürnberg, J.
Organomet. Chem. 1994, 480,
145-153. „Five-membered OsC3N heterocycles from osmium azavinylidenes as precursors“ |
| 1. | T. Daniel, N. Mahr, T.
Braun,
H. Werner, Organometallics 1993, 12,
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