Publications

160.M. Talavera, T. Braun, Chem. Eur. J. 2021, 27, 11926.
„Versatile Reaction Pathways of 1,1,3,3,3-Pentafluoropropene at Rh(I) Complexes [Rh(E)(PEt3)3 (E=H, GePh3, Si(OEt)3, F, Cl): C-F versus C-H Bond Activation Steps“
Reaction scheme for activation of 1,1,3,3,3-Pentafluoropropene

159.R. Jaeger, M. Talavera, T. Braun, J. Fluorine Chem. 2021, 247, 109803.
„Studies on the reactivity of Rh(I) complexes towards SF5Cl“

158.C. Becker, T. Braun, B. Paulus, Catalysts 2021, 11, 565.
„Theoretical Study on the Lewis Acidity of the Pristine AlF3 and Cl-Doped α-AlF3 Surfaces“

157. M.-C. Kervarec, T. Braun, M. Ahrens, E. Kemnitz, Beilstein J. Org. Chem. 2020, 16, 2623.
„Activation of pentafluoropropane isomers at a nanoscopic aluminum chlorofluoride: hydrodefluorination versus dehydrofluorination“

156. M. Talavera, T. Braun, Synlett 2020, 31, 1760.
„Rhodium(I) Complexes as Useful Tools for the Activation of Fluoroolefins“

155.M. Talavera, S. Hinze, T. Braun, R. Laubenstein, R. Herrmann, Molecules 2020, 25, 3977.
„A SF5 Derivative of Triphenylphosphine as an Electron-Poor Ligand Precursor for Rh and Ir Complexes“

154.N. Pfister, M. Bui, T. Braun, P. Wittwer, M. Ahrens, Z. Anorg. Allg. Chem. 2020, 646, 808-815.
„Synthesis and Reactivity of Iridium(I) Fluorido Complexes: Oxidative Addition of SF4 at trans-[Ir(F)(CO)(PEt3)2]“

153.M.-C. Kervarec, E. Kemnitz, G. Scholz, S. Rudić, T. Braun, C. Jäger, A. A. L. Michalchuk, F. Emmerling, Chem. Eur. J. 2020, 26, 7314-7322.
„A HF Loaded Lewis-Acidic Aluminium Chlorofluoride for Hydrofluorination Reactions“

152.D. Dirican, N. Pfister, M. Wozniak, T. Braun, Chem. Eur. J. 2020, 26, 6945-6963.
„Reactivity of Binary and Ternary Sulfur Halides towards Transition-Metal Compounds“

151.M. Talavera, G. Meißner, S. G. Rachor, T. Braun, Chem. Commun. 2020, 56, 4452-4455.
„C-F activation reactions at germylium ions: dehydrofluorination of fluoralkanes“

150.C. P. Marshall, G. Scholz, T. Braun, E. Kemnitz, Catal. Sci. Technol. 2020, 10, 391-402.
„Strong Lewis acidic catalysts for C-F bond activation by fluorination of activated γ-Al2O3

149.P. Tomar, T. Braun, E. Kemnitz, Eur. J. Inorg. Chem. 2019, 44, 4735-4739.
„Preparation of NHC Stabilized Al(III)fluorides: Fluorination of [(SIMes)AlMe3] with SF4 or Me3SnF“

148.M. Talavera, R. Müller, T. Ahrens, C. N. von Hahmann, B. Braun-Cula, M. Kaupp, T. Braun, Faraday Discuss. 2019, 220, 328-349.
„Activation of tetrafluoropropenes by rhodium(I) germyl and silyl complexes“

147.C. Xu, M. Talavera, S. Sander, T. Braun, Dalton Trans. 2019, 48, 16258-16267.
„C-H and C-F bond activation reactions of pentafluorostyrene at rhodium complexes“

146.M. Talavera, C. N. von Hahmann, R. Müller, M. Ahrens, M. Kaupp, T. Braun, Angew. Chem. Int. Ed. 2019, 58, 10688-10692; M. Talavera, C. N. von Hahmann, R. Müller, M. Ahrens, M. Kaupp, T. Braun, Angew. Chem. 2019, 131, 10798-10802.
„C-H and C-F bond activation reactions of fluorinated propenes at rhodium: Distinctive reactivity of the refrigerant HFO-1234yf“

145.C. P. Marshall, G. Scholz, T. Braun, E. Kemnitz, Dalton Trans. 2019, 48, 6834-6845.
„Nb-doped variants of high surface aluminium fluoride: a very strong bi-acidic solid catalyst“

144.Ò. Torres, N. Pfister, T. Braun, P. Wittwer, Dalton Trans. 2019, 48, 6153-6161.
„C–F activation of perfluorophenazine at nickel: selectivity and mechanistic investigations“

143.M. Kervarec, C. P. Marshall, T. Braun, E. Kemnitz, J. Fluorine Chem. 2019, 221, 61-65.
„Selective dehydrofluorination of 2-chloro-1,1,1,2-tetrafluoropropane (HCFC-244bb) to 2-chloro-3,3,3-trifluoropropene (HFO-1233xf) using nanoscopic aluminium fluoride catalysts at mild conditions“

142.P. Roesch, R. Müller, A. Dallmann, G. Scholz, M. Kaupp, T. Braun, B. Braun-Cula, P. Wittwer, Chem. Eur. J. 2019, 25, 4678-4682.
„A Silylene-Boran Lewis Pair as a Tool for Trapping Water Molecule: Silanol Formation and Dehydrogenation“

141.B. Calvo, C. P. Marshall, T. Krahl, J. Kröhnert, A. Trunschke, G. Scholz, T. Braun, E. Kemnitz, Dalton Trans. 2018, 47, 16461-16473.
„Comparative study of the strongest Lewis acids known: ACF and HS-AlF3

140.H. Baumgarth, G. Meier, C. N. von Hahmann, T. Braun, Dalton Trans. 2018, 47, 16299-16304.
„Reactivity of rhodium and iridium peroxido complexes towards hydrogen in the presence of B(C6F5)3 or [H(OEt2)2][B{3,5-(CF3)2C6H3}4]

139.N. Pfister, T. Braun, P. Wittwer, M. Ahrens, Z. Anorg. Allg. Chem. 2018, 644, 1064-1070.
„Selective Formation and Characterization of a RhIII λ4-Trifluorosulfanyl Complex„

138.P. Tomar, T. Braun, E. Kemnitz, Chem. Commun. 2018, 54, 9753-9756.
„Photochemical activation of SF6 by N-heterocyclic carbenes to provide a deoxyfluorinating reagent“

137.S. Mebs, S. I. Kalläne, T. Braun, Z. Kristallog. – Cryst. Mater. 2018, 233, 615-626.
„Hapticity of asymmetric rhodium-allyl compounds in the light of real-space bonding indicators“

136.M. A. Ellwanger, C. von Randow, S. Steinhauer, Y. Zhou, A. Wiesner, H. Beckers, T. Braun, S. Riedel, Chem. Commun. 2018, 54, 9301-9304.
„Tuning the Lewis acidity of difluorido gold(III) complexes: the synthesis of [AuClF2(SIMes)] and [AuF2(OTeF5)(SIMes)]“

135.A. L. Raza, M. F. Kuehnel, M. Talavera, M. Teltewskoi, M. Ahrens, P. Kläring, T. Braun, D. Lentz, J. Fluorine Chem. 2018, 214, 80-85.
„Reactivity of rhodium hydrido and silyl complexes towards 1,1-difluoroallene“

134.P. Wittwer, A. Stelzer, T. Braun, Eur. J. Inorg. Chem. 2018, 27, 3187-3194.
„Reactivity of Cp*Al towards Silanols: Formation and Hydrolysis of Alumosiloxanes“

133.M. A. Ellwanger, S. Steinhauer, P. Golz, T. Braun, S. Riedel, Angew. Chem. 2018, 130, 7328-7332; Angew. Chem. Int. Ed. 2018, 57, 7210-7214.
„Stabilization of Lewis Acidic AuF3 as an N-Heterocyclic Carbene Complex: Preparation and Characterization of [AuF3(SIMes)]“

132.C. N. von Hahnmann, M. Talavera, C. Xu, T. Braun, Chem. Eur. J. 2018, 24, 11131-11138.
„Reactivity of 3,3,3-Trifluoropropyne at Rhodium Complexes: Development of Hydroboration Reactions“

131.C. P. Marshall, T. Braun, E. Kemnitz, Catal. Sci. Technol. 2018, 8, 3151-3159.
„Modifying the reactivity of a solid Lewis acid: niobium and antimony doped nanoscopic aluminum fluoride“

130.C. Berg, N. Pfister, T. Braun, B. Braun-Cula, Chem. Eur. J. 2018, 24, 7985-7990.
„Diverse Reactivity of Platinum SF3 and SF2 Complexes towards EtOH and Me3SiOEt“

129.M. Wozniak, T. Braun, M. Ahrens, B. Braun-Cula, P. Wittwer, R. Herrmann, R. Laubenstein, Organometallics 2018, 37, 821-828.
„Activation of SF6 at a Xantphos-Type Rhodium Complex“

128.B. Calvo, T. Braun, E. Kemnitz, ChemCatChem 2018, 10, 403-406.
„Hydrogen/Deuterium-Exchange Reactions of Methane with Aromatics and Cyclohexane Catalyzed by a Nanoscopic Aluminium Chlorofluoride“

127.G. Meißner, K. Kretschmar, T. Braun, E. Kemnitz, Angew. Chem. 2017, 129, 16556-16559; Angew. Chem. Int. Ed. 2017, 56, 16338-16341.
„Consecutive Transformations of Tetrafluoropropenes: Hydrogermylation and Catalytic C−F Activation Steps at a Lewis Acidic Aluminum Fluoride“

126.R. Laubenstein, M. Ahrens, T. Braun, Z. Anorg. Allg. Chem. 2017, 643, 1723-1729.
„Synthesis and Structures of Gallium-β-Diketiminate Complexes: Isolation of a Dinuclear Gallium(II) Complex“

125.J. Kohlmann, T. Braun, J. Fluorine Chem. 2017, 203, 140-145.
„Synthesis and reactivity of a cationic palladium complex as possible intermediate in a Suzuki-Miyaura cross-coupling reaction“

124.K. S. Lokare, P. Wittwer, B. Braun-Cula, N. Frank, S. Hoof, T. Braun, C. Limberg, Z. Anorg. Allg. Chem. 2017, 643, 1581-1588.
„Mimicking Base Ineraction with Acidic Sites [Si-O(H)-Al] of Zeolites in Molecular Models“

123.P. Roesch, U. Warzok, M. Enke, R. Müller, C. Schattenberg, C. A. Schalley, M. Kaupp, T. Braun, P. Wittwer, Chem. Eur. J. 2017, 23, 13964-13972.
„Reactivity of the Sterically Demanding Siloxanediol Mes2Si(OH)-(μ-O)Si(OH)Mes2 Towards Water and Ether Molecules“

122.M. A. Ellwanger, S. Steinhauer, P. Golz, H. Beckers, A. Wiesner, B. Braun-Cula, T. Braun, S. Riedel, Chem. Eur. J. 2017, 23, 13501-12509.
„Taming the High Reactivity of Gold(III) Fluoride: Fluorido Gold(III) Complexes with N-Based Ligands“

121.G. Meißner, M. Feist, T. Braun, E. Kemnitz, J. Organomet. Chem. 2017, 847, 234-241.
„Selecive reduction of a C-Cl bond in halomethanes with Et3GeH at nanoscopic Lewis acidic Aluminium fluoride Formation of Fluorovinyl and Fluorido Complexes“

120.J. Kohlmann, T. Braun, R. Laubenstein, R. Herrmann, Chem. Eur. J. 2017, 23, 12218-12232.
„Suzuki-Miyaura Cross-Coupling Reactions of Highly Fluorinated Arylboronic Esters: Catalytic Studies and Stoichiometric Model Reactions on the Transmetallation Step“

119.G. Meißner, D. Dirican, C. Jäger, T. Braun, E. Kemnitz, Catal. Sci. Technol. 2017, 7, 3348-3354.
„Et3GeH versus Et3SiH: controlling reaction pathways in catalytic C-F bond activations at a nanoscopic aluminium chlorofluoride“

118.J. Berger, T. Braun, T. Ahrens, P. Kläring, R. Laubenstein, B. Braun-Cula, Chem. Eur. J. 2017, 23, 8886-8900.
„The Versatile Behavior of Platinum Alkyne Complexes towards XeF2: Formation of Fluorovinyl and Fluorido Complexes“

117.C. Berg, T. Braun, M. Ahrens, P. Wittwer, R. Herrmann, Angew. Chem. 2017, 129, 4364-4368; Angew. Chem. Int. Ed. 2017, 56, 4300-4304.
„Activation of SF6 at Platinum Complexes: Formation of SF3 Derivatives and Their Application in Deoxyfluorination Reactions“

116.A. K. Siwek, M. Ahrens, M. Feist, T. Braun, E. Kemnitz, ChemCatChem 2017, 9, 839-845.
„Activation of Chlorinated Methanes at the Surface of Nanoscopic Lewis Acidic Aluminum Fluorides“

115.T. Ahrens, B. Schmiedecke, T. Braun, R. Herrmann, R. Laubenstein, Eur. J. Inorg. Chem. 2017, 3, 713-722.
„Activation of CS2 and COS at a Rhodium(I) Germyl Complex: Generation of CS and Carbido Complexes“

114.T. Ahrens, M. Teltewskoi, M. Ahrens, T. Braun, R. Laubenstein, Dalton Trans. 2016, 45, 17495-17507.
„Competing reaction pathways of 3,3,3-trifluoropropene at rhodium hydrido, silyl and germyl complexes: C-F bond activation versus hydrogermylation“

113.R. Herrmann, P. Wittwer, T. Braun, Eur. J. Inorg. Chem. 2016, 4898-4905.
„Platinum Complexes Bearing a tripodal Germyl Ligand“

112.H. Baumgarth, G. Meier, T. Braun, B. Braun-Cula, Eur. J. Inorg. Chem. 2016, 4565-4572.
„Rhodium and Iridium Fluorido and Bifluorido Complexes Derived from Peroxido Precursors“

111.L. Zámostná, T. Braun, Nachrichten aus der Chemie 2016, 64, 829-835.
„Inertes Schwefelhexafluorid aktivieren“

110.B. Calvo, J. Wuttke, T. Braun, E. Kemnitz, ChemCatChem. 2016, 8, 1945-1950.
„Heterogeneous Catalytic Hydroarylation of Olefins at a Nanoscopic Aluminium Chlorofluoride“

109.A. C. Stelzer, P. Hrobárik, T. Braun, M. Kaupp, B. Braun-Cula, Inorg. Chem. 2016, 55, 4915-4923.
„Completing the Heterocubane Family [Cp*AlE]4 (E = O, S, Se, and Te) by Selective Oxygenation and Sulfuration of [Cp*Al]4: Density Functional Theory Calculations of [Cp*AlE]4 and Reactivity of [Cp*AlO]4 toward Hydrolysis“

108.C. Mitzenheim, T. Braun, R. Laubenstein, B. Braun, R. Herrmann, Datlton Trans. 2016, 45, 6394-6404.
„Hydrodealkoxylation reactions of silyl ligands at platinum: reactivity of SIH3 and SiH2Me complexes“

107.C. Berg, R. Laubenstein, T. Braun, B. Braun, Chem. Commun. 2016, 52, 3931-3934.
„Palladium-mediated borylation of pentafluorosulfanyl functionalized compounds: the crucial role of metal fluorido complexes“

106.T. Ahrens, T. Braun, B. Braun, R. Herrmann, Dalton Trans. 2016, 45, 4716-4728.
„Synthesis of a rhodium(I) germyl complex: a useful tool for C-H and C-F bond activation reactions“

105.S. I. Kalläne, R. Laubenstein, T. Braun, M. Dietrich, Eur. J. Inorg. Chem. 2016, 530-537.
„Activation of Si-Si and Si-H Bonds at a Platinum Bis(diphenylphosphanyl)ferrocene (dppf) Complex: Key Steps for the Catalytic Hydrogenolysis of Disilanes“

104.R. Laubenstein, M.-D. Serb, U. Englert, G. Raabe, T. Braun, B. Braun, Chem. Commun. 2016, 52, 1214-1217.
„Is it all in the hinge? A kryptoracemate and three of its alternative racemic polymorphs of an aminonitrile“

103.F. Liebau, T. Braun, B. Braun, J. Fluorine Chem. 2015, 180, 192-200.
„Dehydrogenation of cycloalkanes at rhodium complexes bearing fluorinated cyclopentadienyl ligands“

102.J. Berger, T. Braun, R. Herrmann, B. Braun, Dalton Trans. 2015, 44, 19553-19565.
„Reactivity of platinum alkyne complexes towards N-fluorobenzenesulfonimide: formaiton of platinum compounds bearing a β-fluorovinyl ligand“

101.S. I. Kalläne, T. Braun, M. Teltewskoi, B. Braun, R. Herrmann, R. Laubenstein, Chem. Commun. 2015, 51, 14613-14616.
„Remarkable reactivity of a rhodium(I) boryl complex towards CO2 and CS2: isolation of a carbido complex“

100.L. Zámostná, T. Braun, Angew. Chem. 2015, 127, 10798-10802; Angew. Chem. Int. Ed. 2015, 54, 10652-10656.
„Catalytic Degradation of Sulfur Hexafluoride by Rhodium Complexes“

99.A. Bittner, T. Braun, R. Herrmann, S. Mebs, Chem. Eur. J. 2015, 21, 12299-12302.
„Rhodium-Mediated Oxygenation of Nitriles with Dioxygen: Isolation of Rhodium Derivatives of Peroxyimidic Acids“

98.H. Baumgarth, T. Braun, B. Braun, R. Laubenstein, R. Herrmann, Eur. J. Inorg. Chem. 2015, 2015, 3157-3168.
„Synthesis of an iridium Peroxido Complex and its Reactivity Towards Brønsted Acids“

97.M. Feist, M. Ahrens, A. Siwek, T. Braun, E. Kemnitz, J. Therm. Anal. Calorim. 2015, 121, 929-935.
„Triethylsilane-loaded aluminium chlorofluoride“

96.A. L. Raza, T. Braun, Chem. Sci. 2015, 6, 4255-4260.
„Consecutive C-F bond activation and C-F bond formation of heteroaromatics at rhodium: the peculiar role of FSi(OEt)3

95.L. Zámostná, S. Sander, T. Braun, R. Laubenstein, B. Braun, R. Herrmann, P. Kläring, Dalton Trans. 2015, 44, 9450-9469.
„Synthesis and structure of rhodium(I) silyl carbonyl complexes: photochemical C-F and C-H bond activation of fluorinated aromatic compounds“

94.S. I. Kalläne, M. Teltewskoi, T. Braun, B. Braun, Organometallics 2015, 34, 1156-1169.
„C-H and C-F Bond Activations at a Rhodium(I) Boryl Complex: Reaction Steps for the Catalytic Borylation of Fluorinated Aromatics“

93.M. A. Chilleck, L. Hartenstein, T. Braun, P. W. Roesky, B. Braun, Chem. Eur. J. 2015, 21, 2594-2602.
„Cationic Zinc Organyls as Precatalysts for Hydroamination Reactions“

92.T. Ahrens, J. Kohlmann, M. Ahrens, T. Braun, Chem. Rev. 2015, 115, 931-972.
„Functionalization of Fluorinated Molecules by Transition-Metal-Mediated C-F Bond Activation to Access Fluorinated Building Blocks“

91.R. Herrmann, T. Braun, S. Mebs, Eur. J. Inorg. Chem. 2014, 28, 4826-4835.
„[Ge(H)(2-C6H4PPh2)3] as Ligand precursor at Ruthenium: Formation and Reactivity of [Ru(Cl){Ge(2-C6H4PPh2)3)}]“

90.S. I. Kalläne, T. Braun, Angew. Chem. 2014, 126, 9465-9469; Angew. Chem. Int. Ed. 2014, 53, 9311-9315.
„Catalytic Borylation of SCF3-Functionalized Arenes by Rhodium(I) Boryl Complexes: Regioselective C-H Activation at the ortho-Position“

89.G. Meier, V. Steck, B. Braun, A. Eißler, R. Herrmann, M. Ahrens, R. Laubenstein, T. Braun, Eur. J. Inorg. Chem. 2014, 2793-2808.
„Synthesis and Structures of Fluorinated (β-Diketiminato)rhodium Complexes: Si-H Activation of Silanes at a Carbonyl Complex“

88.S. I. Kalläne, T. Braun, B. Braun, S. Mebs, Dalton Trans. 2014, 43, 6786-6801.
„Versatile reactivity of a rhodium(I) boryl complex towards ketones and imines“

87.L. Zámostná, T. Braun, B. Braun, Angew. Chem. 2014, 126, 2783-2787; Angew. Chem. Int. Ed. 2014, 53, 2745-2749.
„S-F and S-C Activation of SF6 and SF5 Derivatives at Rhodium: Conversion of SF6 into H2S“

86.M. Chilleck, T. Braun, B. Braun, S. Mebs, Organometallics 2014, 33, 551-560.
„Neutral and Cationic Zinc Complexes with N- and S-Donor-Functionalized Cyclopentadienyl Ligands“

85.T. Ahrens, T. Braun, B. Braun, Z. Anorg. Allg. Chem. 2014, 640, 93-99.
„Activation of 1,2-Dihydridodisilanes at Platinum(0) Phosphine Complexes: Syntheses and Structures of Bissilyl Platinum(II) Complexes“

84.M. Teltewskoi, S. I. Kalläne, T. Braun, R. Herrmann, Eur. J. Inorg. Chem. 2013, 33, 5762-5768.
Synthesis of Rhodium(I) Boryl Complexes: Catalytic N–H Activation of Anilines and Ammonia“

83.P. Kläring, T. Braun, Angew. Chem. 2013, 125, 11302-11307; Angew. Chem. Int. Ed. 2013, 52, 11096-11101.
„Insertion of CS2 into Iridium–Fluorine Bonds“

82.L. Zámostná, M. Ahrens, T. Braun, J. Fluorine Chem. 2013, 155, 132-142.
„Catalytic hydrodefluorination of fluoroaromatics with silanes as hydrogen source at a binuclear rhodium complex: Characterization of key intermediates“

81.A. Eißler, P. Kläring, F. Emmerling, T. Braun, Eur. J. Inorg. Chem. 2013, 27, 4775-4788.
„α-Dialdimine Complexes of Rhodium(I) and Iridium(I): Their Reactivity with Dioxygen and Dihydrogen“

80.C. Mitzenheim, T. Braun, Angew. Chem. 2013, 125, 8787-8790; Angew. Chem. Int. Ed. 2013, 52, 8625-8628.
„Si-Si and Si-O Bond Activation at Platinum: Stepwise Formation of a SiH3 Complex“

79.A. L. Raza, J. Panetier, M. Teltewskoi, S. Macgregor, T. Braun, Organometallics 2013, 32, 3795-3807.
„Rhodium(I) Silyl Complexes for C–F Bond Activation Reactions of Aromatic Compounds: Experimental and Computational Studies“

78.B. Rabay, T. Braun, J. P. Falkenhagen, Dalton Trans. 2013, 42, 8058-8065.
„Photolytic C–H activation and dehydrogenation of alkanes at cyclopentadienyl iridium complexes in a perfluorinated solvent“

77.M. Ahrens, G. Scholz, T. Braun, E. Kemnitz, Angew. Chem. 2013, 125, 5436-5440; Angew. Chem. Int. Ed. 2013, 52, 5328-5332.
„Catalytic Hydrodefluorination of Fluoromethanes at Room Temperature by Silylium-ion-like Surface Species“

76.M. Kuehnel, D. Lentz, T. Braun, Angew. Chem. 2013, 125, 3412-3433; Angew. Chem. Int. Ed. 2013, 52, 3328-3348.
„Synthesis of Fluorinated Building Blocks by Transition-Metal-Mediated Hydrodefluorination Reactions“

75.>M. Chilleck, T. Braun, R. Herrmann, B. Braun, Organometallics 2013, 32, 1067-1074.
„Zinc Complexes with the N-Donor-Functionalized Cyclopentadienyl Ligand C5Me4(CH2)2NMe2

74.J. Voigt, M. Chilleck, T. Braun, Dalton Trans. 2013, 42, 4052-4058.
„Activation of Si–Si and Si–H bonds at Pt: a catalytic hydrogenolysis of silicon–silicon bonds“

73.D. Breyer, T. Braun, Efficient Preparations of Fluorine Compounds, Vol. 1, H. W. Roesky (Hrsg.), John Wiley & Sons, Hoboken 2012, 237-239.
„Palladium-Mediated Synthesis of 4-Vinyltetrafluoropyridine and 2,3,5,6-Tetrafluoropyridine“

72.M. Teltewskoi, T. Braun, Efficient Preparations of Fluorine Compounds, Vol. 1, H. W. Roesky (Hrsg.), John Wiley & Sons, Hoboken 2012, 235-236.
„Rhodium-Mediated Synthesis of a Tetrafluoropyridyl-2-boronate Ester“

71.F. Wehmeier, T. Braun, Efficient Preparations of Fluorine Compounds, Vol. 1, H. W. Roesky (Hrsg.), John Wiley & Sons, Hoboken 2012, 232-234.
„Rhodium-Mediated Synthesis of (3,3,3-Trifluoropropyl)trimethoxysilane and (3,3,3-Trifluoropropyl)triphenylsilane“

70.G. Meier, T. Braun, Angew. Chem. 2012, 124, 12732-12737; Angew. Chem. Int. Ed. 2012, 51, 12564-12569.
„Hydrogenation of a Rhodium Peroxido Complex by Formate Derivatives: Mechanistic Studies and the Catalytic Formation of H2O2 from O2

69.D. Breyer, J. Berger, T. Braun, S. Mebs, J. Fluorine Chem. 2012, 143, 263-271.
„Nickel fluoro complexes as intermediates in catalytic cross-coupling reactions“

68.S. Mebs, M. A. Chilleck, S. Grabowsky, T. Braun, Chem. Eur. J. 2012, 18, 11647-11661.
„Hapticity Uncovered: Real-Space Bonding Indicators for Zincocene Chemistry“

67.A.-K. Jungton, C. Herwig, T. Braun, C. Limberg, Chem. Eur. J. 2012, 18, 10009-10013.
„Activation and Coordination of Ammonia at [Cp*Ir(H2)]: NMR and Matrix Isolation Studies“

66.A.-K. Jungton, P. Kläring, T. Braun, A. Eißler, Z. Anorg. Allg. Chem. 2012, 638, 505-511.
„Synthesis, Reactivity and Structure of Iridium Tetrafluoropyridyl Complexes: Ammonia Coordination and Activation“

65.P. Kläring, A.-K. Jungton, T. Braun, C. Müller, Eur. J. Inorg. Chem. 2012, 1430-1436.
„Synthesis, Structure and Reactivity of Iridium Hydrido Fluorido Complexes“

64.T. Braun, Organometallics 2012, 31, 1213-1215.
„Organometallic Chemistry Meets Fluorine“

63.D. Breyer , T. Braun, P. Kläring, Organometallics 2012, 31, 1417-1424.
„Synthesis and Reactivity of the Fluoro Complex trans-[Pd(F)(4-C5NF4)(iPr2PCH2CH2OCH3)2]: C-F Bond Formation and Catalytic C-F Bond Activation Reactions“

62.>M. Prechtl, M. Teltewskoi, A. Dimitrov, E. Kemnitz, T. Braun, Chem. Eur. J. 2011, 17, 14385-14388.
„Catalytic C-H Bond Activation at Nanoscale Lewis Acidic Aluminium Fluorides: H/D Exchange Reactions at Aromatic and Aliphatic Hydrocarbons“

61.J. Voigt, T. Braun, Dalton Trans. 2011, 40, 12699-12704.
„Si–H and Si–Si activation at Pt: synthesis and reactivity of neutral and cationic silyl complexes“

60.M. A. Chilleck, T. Braun, B. Braun, Chem. Eur. J. 2011, 17, 12902-12905.
„Cationic Cyclopentadienyl Zinc Complexes with Slipped Triple-Decker and Half-Sandwich Structures“

59.P. Kläring, S. Pahl, T. Braun, A. Penner, Dalton Trans. 2011, 6785-6791.
„Facile oxidative addition of water at iridium: reactivity of trans-[Ir(4-C5NF4)(H)(OH)(PiPr3)2] towards CO2 and NH3

58.A. Penner, T. Braun, Eur. J. Inorg. Chem. 2011, 2579-2587.
„Rhodium and Iridium Complexes with α-Diketimine Ligands: Oxidative Addition of H2 and O2

57.G. Meier, T. Braun, Angew. Chem. 2011, 123, 3338-3342; Angew. Chem. Int. Ed. 2011, 50, 3280-3284.
„A Rhodium Peroxide Complex in Mono-, Di- and Peroxygenation Reactions“

56.T. Braun, F. Wehmeier, Eur. J. Inorg. Chem. 2011, 613-625.
„C-F Bond Activation of Highly Fluorinated Molecules at Rhodium: From Model Reactions to Catalyis“

55.D. Breyer, T. Braun, A. Penner, Dalton Trans. 2010, 7513-7520.
„Isolation and reactivity of palladium hydrido complexes: intermediates in the hydrodefluorination of pentafluorpyridine“

54.A.-K. Jungton, A. Meltzer, C. Präsang, T. Braun, M. Driess, A. Penner, Dalton Trans. 2010, 5436-5438.
„Addition of [(h5-C5Me5)IrH4] to a zwitterionic silylene: stepwise formation of iridium(V) and iridium(III)-silylene complexes“

53.M. Teltewskoi, J. A. Panetier, Stuart A. Macgregor, T. Braun, Angew. Chem. 2010, 122, 4039-4043; Angew. Chem. Int. Ed. 2010, 49, 3947-3951.
„A Highly Reactive Rhodium(I)-Boryl Complex as a Useful Tool for C-H Bond Activation and Catalytic C-F Bond Borylation“

52.A. Penner, T. Schröder,T. Braun, and B. Ziemer   Eur. J. Inorg. Chem. 2009, 4464-4464.
„Synthesis, Structure, and Reactivity of Rhodium Bipyridine Compounds: Formation of a RhII Hydrido Cluster and a RhIII Peroxide Complex“

51.M. Ahijado-Salomon, Ann-Katrin Jungton, T. Braun,  Dalton Trans. 2009, 7669-7677.
„Activation of ethylene and ammonia at iridium: C-H versus N-H oxidative addition“

50.T. Braun, M. Ahijado-Salomon, K. Altenhöner, M. Teltewskoi, S. Hinze,  Angew. Chem. 2009, 121, 1850-1854; Angew. Chem. Int. Ed. 2009, 48, 1818-1822.
„C-F Activation at Rhodium Boryl Complexes: Formation of 2-Fluoroalkyl-1,3,2-Dioxoborolanes by Catalystic Functionalization of Hexafluoropropene“

49.G. Meier, T. Braun, Angew. Chem. 2009, 121, 1546-1548; Angew. Chem. Int. Ed. 2009, 48, 1575-1577.
„Catalytic C-F Activation and Hydrodefluorination of Fluoroalkyl Groups“

48.A. Roscher, T. Braun, Dalton Trans. 2009, 1378-1382.
„Towards a Catalytic Hydrogenolysis of Silicon-Silicon Bonds: Formation of Si-H Bonds from Disilanes and H2 at Platinum“

47.E. Yegen, U. Zimmermann, W. E. S. Unger, T. Braun, Plasma Processes and Polymers 2009, 6, 11-16.
„C-F bond cleavage during derivatization reaction of amino groups with TFAB and PFB at plasma processed organic surfaces“

46.M. Ahijado-Salomon, T. Braun, A. Penner, Angew. Chem. 2008, 120, 8999-9003; Angew. Chem. Int. Ed. 2008, 47, 8867-8871.
„Stepwise Oxygenation of Pinacolborane by a Rhodiumperoxo Complex: Detection of an Intermediate Metal Borate and Perborate“

45.M. Ahijado-Salomon, T. Braun, I. Krossing, Dalton Trans. 2008, 5197-5206.
„Iridium Derivates of Fluornated Aromatics by C-H Activation: Isolation of Classical and Non-classical Hydrides“

44.T. Schraub, P. Fischer, A. Steffen, T. Braun, U. Radius, A. Mix J. Am. Chem. Soc. 2008, 130, 9304-9317.
„C−F Activation of Fluorinated Arenes using NHC-Stabilized Nickel(0) Complexes: Selectivity and Mechanistic Investigations“

43.M. Ahijado, T. Braun, Angew. Chem. 2008, 120, 2996-3000; Angew. Chem. Int. Ed. 2008, 47, 2954-2958.
„Rhodium Derivatives of Peroxoboronic Acids and Peroxoboric Acid: Formation of Metallatrioxaborolanes from an h2 -Peroxo Complex“

42.A. Steffen, T. Braun, B. Neumann, H.-G. Stammler Angew. Chem. 2007, 119 ,8828-8832; Angew. Chem. Int. Ed. 2007, 46, 8674-8678.
„Palladium Fluro Complexes: Useful Tools to Access Organometallic Metallamacrocycles“

41.A. Steffen, T. Hagemeister, T. Braun, P. Jutzi, B. Neumann, H.-G. Stammler Organometallics. 2007, 26 , 3820–3825.
„Synthesis of 3,3,3- Trifluoropropyl Substituted Cyclopentadienes and Their Zirconocene Derivatites: Catalytic Applications in the Polymerization of Ethylene“

40.T. Braun, D. Noveski, M. Ahijado, F. Wehmeier, Dalton Trans. 2007, 5118-5132.
„Hydrodefluorination of Pentafluoropyridine at Rhodium using Dihydrogen: Detection of Unusual Rhodium Hydrido Complexes“

39.T. Braun, F. Wehmeier, K. Altenhöner, Angew. Chem.. 2007, 119, 5415-5418; Angew. Chem. Int. Ed. 2007, 46, 5321-5324.
„Catalytic C-F Bond Activation of Hexafluoropropene by Rhodium: Formation of (3,3,3- Trifluoropropyl)silanes“

38.L. Weber, G. Noveski, T. Braun, H.-G. Stammler, B. Neumann, Eur. J. Inorg. Chem. 2007, 562-567.
„Synthesis of the  h2-1-Phosphaallen Complexes [(h5-C5H5)(CO)(NO)W{h2-R1P=C=C(R2)H}] (R1 = tBu, Cy; R2 = Ph,H) from [(h5-C5H5)(CO)(NO)W=C=C(R2)H}(R2 = Ph,H) and Inversely Polarized Phosphaalkenes R1P=C(NMe2)2 (R1 = tBu, Cy), and Their Structure“

37.T. Braun, R. N. Perutz, Comprehensive Organometallic Chemistry III, Vol. 1, R. H. Crabtree, M. P. Mingos (Hrsg.), Elsevier, Oxford 2007, 725-758.
„Transition-Metal Mediated C-F Bond Activation“

36.T. Braun, J. Izundu, A. Steffen, B. Neumann, H.-G. Stammler, Dalton Trans. 2006, 5118-5132.
„Reactivity of a Palladium Fluoro Complex Towards Silanes and Bu3SnCH=CH2: Catalytic Derivatisation of Pentafluoropyridine Based on Carbon-Fluorine Bond Activation Reactions“

35.T. Braun, V. Schorlemer, B. Neumann, H.-G. Stammler, J. Fluorine Chem. 2006, 127, 367-372.
„Palladium mediated activation of C-F bonds in 2,4,6-trifluoropyrimidine: synthesis and structure of palladium pyrimidyloxy and pyrimidinone derivatives“

34.L. Weber, P. Bayer, T. Braun, H.-G. Stammler, B. Neumann, Organometallics 2006, 25, 1786-1794.
„Arsaalkenes RAs=C(NMe2)2 [R = PhC(O), 4-EtC6H4C(O), 2,4,6-Me3C6H2C(O), tBuC(O), Me3Si]: Versatile Reagents in the Chemistry of Heterocumulenes“

33.L. Weber, I. Domke, C. Schmitd, T. Braun, H.-G. Stammler, B. Neumann, Dalton Trans. 2006, 2127-2132.
„Syntheses, Structures, Luminescence and Electrochemistry of Benzene- and Biphenyl-centered Bis- and Tris-1,3,2-diazaboroles and -1,3,2-diazaborolodines“

32.L. Weber, P. Bayer, S. Uthmann, T. Braun, H.-G. Stammler, B. Neumann, Eur. J. Inorg. Chem. 2006, 137-143.
„Reactivity of Inversely Polarized Arsaalkenes RAs=C(NMe2)2 {R = [h5-C5Me5)(CO)2Fe], tBuC(O), 4-EtC6H4C(O)} towards Phosphavinylidene Complexes [h5-(C5H5)(CO)2M=P=C(SiMe3)2] (M = Mo, W)“

31.T. Braun, A. Steffen, V. Schorlemer, B. Neumann, H.-G. Stammler, Dalton Trans. 2005, 3331-3336.
„Routes to Unique Palladium A-Frame Complexes with a Bridging Fluoro-Ligand“

30.M. Ahijado, T. Braun, D. Noveski, N. Kocher, B. Neumann, D. Stalke, H.-G. Stammler, Angew. Chem. 2005, 117, 7107-7111; Angew. Chem. Int. Ed. 2005, 44, 6947-6951.
„Rhodium- mediated Formation of Peroxides from Dioxygen: Isolation of Hydroperoxo, Silylperoxo and Methylperoxo Intermediates“

29.T. Braun, Angew. Chem. 2005, 117, 5138-5140; Angew. Chem. Int. Ed. 2005, 44, 5012-5014.
„Oxidative Atdition of NH3 to a Transition Metal: a Key-Step for the Metal-Mediated Derivatization of Ammonia?“

28.T. Braun, A. Steffen, M. I. Sladek, B. Neumann, H.-G. Stammler, Organometallics 2005, 23, 4057-4064.
„Catalytic C-C Coupling Reactions at Ni by C-F Activation of a Pyrimidine in the Presence of a C-Cl Bond: The Crucial Role of Highly Reactive Fluoro Complexes“

27.D. Noveski, T. Braun, B. Neumann, A. Stammler, H.-G. Stammler, Dalton Trans. 2004, 4106-4119.
„C-F or C-H bond activation and C-C coupling reactions of fluorinated pyridines at rhodium: synthesis, structure and reactivity of a variety of tetrafluoropyridyl complexes“

26.N. A. Jasim, R. N. Perutz, A. C. Whitwood, T. Braun, J. Izundu, B. Neumann, S. Rothfeld, H.-G. Stammler, Organometallics 2004, 23, 6140-6149.
„Contrasting reactivity of fluoropyridines at palladium and platinum: C-F oxidative atdition at palladium, alkyl transfer from phosphorus to platinum“

25.D. Noveski, T. Braun, S. Krückemeier, J. Fluorine Chem. 2004, 125, 959-966.
„Synthesis and Reactivity of Rhodium Fluoro Complexes“

24.D. Noveski, T. Braun, M. Schulte, B. Neumann, H.-G. Stammler, Dalton Trans. 2003, 4075-4083.
„C-F activation and hydrodefluorination of fluorinated alkenes at rhodium“

23.T. Braun, S. Rothfeld, V. Schorlemer, A. Stammler, H.-G. Stammler, Inorg. Chem. Commun. 2003, 6, 752-755.
„Palladium Mediated Activation of a C-F Bond in Pentafluoropyridine: Synthesis, Structure and Reactivity of a Pyridyloxy Complex“

22.A. Bockholt, T. Braun, P. Jutzi, B. Neumann, A. Stammler, H.-G. Stammler, Organosilicon Chemistry V, (Hrsg.: N. Auner, J. Weis), Wiley-VCH 2003, S. 50-54.
„New Donor-Stabilized Organosilicon Cations: Synthesis, Structure and Reactivity“

21.T. Braun, M. I. Sladek, B. Neumann, H.-G. Stammler, New. J. Chem. 2003, 27, 313-318.
3-Fluoropyridyl Nickel Complexes as Useful Tools for the Selective Synthesis of New 2,4,5,6-Tetrafluoropyridines: A Route Complementing the Established Methods to Access Fluorinated Pyridines“

20.T. Braun, R. N. Perutz, Perspectives in Organometallic Chemistry, (Hrsg.: C. G. Screttas, B. R. Steele), RSC 2003, S. 136-151.
„Routes to Fluorinated Organic Derivatives by Nickel Mediated C-F Activation of Heteroaromatics“

19.T. Braun, G. Münch, B. Windmüller, O. Gevert, M. Laubender, H. Werner, Chem. Eur. J. 2003, 9, 2516-2530.
„Synthesis, Molecular Structure, and C-C Coupling Reactions of Carbeneruthenium(II) Complexes with C5H5Ru(=CRR‘) and C5Me5Ru(=CRR‘) as Molecular Units“

18.T. Braun, D. Noveski, B. Neumann, H.-G. Stammler, Angew. Chem. 2002, 114, 2870-2873; Angew. Chem. Int. Ed. 2002, 41, 2745-2747.
„Conversion of Hexafluoropropene into 1,1,1-Trifluoropropane by C-F Activation at Rhodium“

17.T. Braun, B. Blöcker, V. Schorlemer, B. Neumann, A. Stammler, H.-G. Stammler, J. Chem. Soc., Dalton Trans. 2002, 2213-2218.
„Synthesis, Structure and Reactivity of Fluorovinyl Nickel Complexes: Formation of a Phosphonioethenyl Complex“

16.M. I. Sladek, T. Braun, B. Neumann, H.-G-Stammler, J. Chem. Soc., Dalton Trans. 2002, 297-299.
„Aromatic C-F Activation at Ni in the Presence of a Carbon Chlorine Bond: The Nickel Mediated Synthesis of new Pyrimidines“

15.T. Braun, R. N. Perutz, Chem. Commun. 2002, 2749-2757.
„Routes to Fluorinated Organic Derivatives by Nickel Mediated C-F Activation of Heteroaromatics“

14.I. Atheaux, F. Delpech, B. Donnadieu, S. Sabo-Etienne, B. Chaudret, K. Hussein, J.-C. Barthelat, T. Braun, S. B. Duckett, R. N. Perutz, Organometallics 2002, 5347-5357.
„Exchange Processes in Complexes with Two Ruthenium (h2-silane) Linkages: Role of the Secondary Interactions between Silicon and Hydrogen Atoms“

13.T. Braun, R.N. Perutz, M. I. Sladek, Chem. Commun. 2001, 2254-2255.
„Catalytic C-F Activation of Polyfluorinated Pyridines by Nickel-Mediated Cross-Coupling Reactions“

12.T. Braun, L. Cronin, C. L. Higgitt, J. E. McGrady, R. N. Perutz, M. Reinhold, New. J. Chem. 2001, 25, 19-21.
„Coordination and oxidative atdition of octafluoronaphthalene at a nickel-centre: isolation of an intermediate in C-F bond activation“

11.T. Braun, S. J. Archibald, J. A. Gaunt, J. E. Hobson, R. N. Perutz, J. Chem. Soc., Dalton Trans. 2000, 2013-1018.
„Chemistry of Nickel Tetrafluoropyridyl Derivatives: Synthesis and Structure of a Binuclear Complex With Bridging Pyridyl Ligands“

10.T. Braun, S. P. Foxon, R. N. Perutz, P. H. Walton, Angew. Chem. 1999, 111, 3543-3545; Angew. Chem. Int. Ed. 1999, 38, 3326-3329.
„Nickel-Assisted Carbon-Fluorine Bond Activation of 2,4,6-Trifluoropyrimidine: The Synthesis of New Pyrimidine and Pyrimidinone Derivatives“

9.T. Braun, S. Parsons, R. N. Perutz, M.Voith, Organometallics 1999, 18, 1710-1716.
„Reactivity of a Nickelfluoride Complex: Preparation of new Tetrafluoropyridyl Derivatives“

8.H. Werner, T. Braun, T. Daniel, O. Gevert, M. Schulz, J. Organomet. Chem. 1997, 541, 127-141.
„Cyclopentadienyl- und Pentamethylcyclopentadienyl-Rutheniumkomplexe mit Carboxylat-, Vinylester- und Carben-Liganden“

7.T. Braun, M. Laubender, O. Gevert, H. Werner, Chem. Ber./Recl. 1997, 130, 559-564.
„Halfsandwich-Type Triisopropylstibane Ruthenium Compounds with 16-, 17- and 18-Electron Configurations and an Unsymmetrical Binuclear 18/16-Electron Ru2(SbiPr3) Species“

6.P. LeGendre, T. Braun, C. Bruneau, P. H. Dixneuf, J. Org. Chem. 1996, 61, 8453-8456.
„Preparation of Optically Active Cyclic Carbonates and 1,2-Diols via Enantioselective Hydrogenation of a-Methylenedioxolanones Catalyzed by Chiral Ruthenium (II) Complexes“

5.T. Braun, P. Meuer, H. Werner, Organometallics 1996, 15, 4075-4077.
h3-2.3.4-Butadienyl and h3-3.4.5-Pentatrienyl Ruthenium Complexes From Vinylidene and Allenylidene Precursors“

4.T. Braun, O. Gevert, H. Werner, J. Am. Chem. Soc. 1995, 117, 7291-7292.
„A Ruthenium-Mediated [C1 + C2] Coupling Reaction: Formation of π-Allyl Complexes from Carbenemetal Precursors“

3.T. Braun, P. Steinert, H. Werner, J. Organomet. Chem. 1995, 488, 169-176.
„Vinylidene transition metal complexes XXXIV: The preparation and structure of neutral vinylidene and allenylidene ruthenium(II) compounds of the half-sandwich type containing iPr2PCH2CO2Me as supporting ligand“

2.H. Werner, T. Daniel, T. Braun, O. Nürnberg, J. Organomet. Chem. 1994, 480, 145-153.
„Five-membered OsC3N heterocycles from osmium azavinylidenes as precursors“

1.T. Daniel, N. Mahr, T. Braun, H. Werner, Organometallics 1993, 12, 1475-1477.
„Insertion of a Vinylidene Unit into a Ru-O Bond: Synthesis and Molecular Structure of [C5H5(PPh3)Ru{k2(C,O)-C(=CHCO2Me)OC(CH3)=O}]“